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Full-Text Articles in Physical Sciences and Mathematics
Photocatalytic Activity Of Core/Shell Semiconductor Nanocrystals Featuring Spatial Separation Of Charges, Dimuthu Perera, Ryan Lorek, Rony S. Khnayzer, Pavel Moroz, Timothy O’Connor, Dmitry Khon, Geoffrey Diederich, Erich Kinder, Scott Lambright, Felix N. Castellano, Mikhail Zamkov
Photocatalytic Activity Of Core/Shell Semiconductor Nanocrystals Featuring Spatial Separation Of Charges, Dimuthu Perera, Ryan Lorek, Rony S. Khnayzer, Pavel Moroz, Timothy O’Connor, Dmitry Khon, Geoffrey Diederich, Erich Kinder, Scott Lambright, Felix N. Castellano, Mikhail Zamkov
Physics and Astronomy Faculty Publications
The present study investigates the photocatalytic activity of ZnSe/CdS core/shell semiconductor nanocrystals. These nanoparticles exhibit a spatial separation of photoinduced charges between the core and the shell domains, which makes them potentially viable for photocatalytic applications. Unfortunately, one of the excited charges remains inside the core semiconductor and thus cannot efficiently react with the external environment. Here, we explore this issue by investigating the mechanisms of hole extraction from the ZnSe core to the surface of the CdS shell. In particular, the effect of shell thickness in ZnSe/CdS core/shell nanocrystals on the ability of core-localized charges to perform oxidative reactions …
Photocatalytic Hydrogen Production At Titania-Supported Pt Nanoclusters That Are Derived From Surface-Anchored Molecular Precursors, Rony S. Khnayzer, Lucas B. Thompson, Mikhail Zamkov, Shane Ardo, Gerald J. Meyer, Catherine J. Murphy, Felix N. Castellano
Photocatalytic Hydrogen Production At Titania-Supported Pt Nanoclusters That Are Derived From Surface-Anchored Molecular Precursors, Rony S. Khnayzer, Lucas B. Thompson, Mikhail Zamkov, Shane Ardo, Gerald J. Meyer, Catherine J. Murphy, Felix N. Castellano
Physics and Astronomy Faculty Publications
Degussa P-25 TiO2 bearing surface-anchored Pt(dcbpy)Cl-2 [dcbpy = 4,4'-dicarboxylic acid-2,2'-bipyridine] prepared with systematically varied surface coverage produced Pt-0 nanoparticles under bandgap illumination in the presence of methanol hole scavengers. Energy-dispersive X-ray spectroscopy confirmed the presence of elemental platinum in the newly formed nanoparticles during scanning transmission electron microscopy (STEM) eleriments. According to the statistical analysis of numerous STEM images, the Pt-0 nanoclusters were distributed in a segregated manner throughout the titania surface, ranging in size from 1 to 3 nm in diameter. The final achieved nanoparticle size and net hydrogen production were determined as a function of the Pt(dcbpy)Cl-2 surface …