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Full-Text Articles in Physical Sciences and Mathematics
Electrochemical Studies Of Metal Complexes In Solution, Yexiang Tong, Beisheng Kang, Qiqin Yang
Electrochemical Studies Of Metal Complexes In Solution, Yexiang Tong, Beisheng Kang, Qiqin Yang
Journal of Electrochemistry
The prospectus of electrochemical studies of metal complexes in solution have been introduced as a background of our research work. The electrochemical behaviors of the metal complexes and clusters have been investigated by many kinds of electrochemical methods.The content includes the standard electrode potential and the related equilibrium constant, electrochemical kinetics and the related behavior of structure, electrocatalysis and electrosynthesis of metal complexes. The electrode reaction mechanisms of the complexes have been approached. The methods for measuring some thermodynamic and kinetic parameters of the complexes are also given. Electrochemical studies would provid many kinds of important information for studying the …
The Role Of Electrolytically Co-Deposited Platinum-Palladium Electrodes On The Electrooxidation Of D. Glucose In Alkaline Medium: A Synergistic Effect, İpek Beceri̇k
Turkish Journal of Chemistry
The electrooxidation of D. glucose was investigated on platinum-palladium alloy electrodes of different compositions in alkaline aqueous solutions. The surface characteristics of the alloys in contact with electrolytic solution were studied using cyclic voltammetry. In particular, a surface enrichment in platinum due to a preferential dissolution of palladium was shown. Enhanced electrocatalytic activity at about 37 at. % in Pd was obtained when compared to pure metals, thus leading to a synergistic effect. The electrocatalytic activity of different alloys for D. glucose oxidation has been chacterized by exchange current densities obtained from extrapolation of Tafel lines to calculated equilibrium potential. …