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Full-Text Articles in Physical Sciences and Mathematics

Electrochemical Behavior Of Riboflavin On Glassy Carbon Electrode, Hong Li, Lincai Jiang May 1999

Electrochemical Behavior Of Riboflavin On Glassy Carbon Electrode, Hong Li, Lincai Jiang

Journal of Electrochemistry

The electrochemical behavior of riboflavin(RF) on glassy carbon has been investigated by using potential sweep,rotating ring_disc electrode and the measurement of differential capacitance. It is shown that a single well_behaved oxidation_reduction wave corresponding to a reversible two_electrons reaction apears in medium of pH<6,and the adsorption of RFH2 formed by electro_reduction is weak and hence its solubility is good.In medium of pH>6,there are two separating but overlapping partly oxidation_reduction waves corresponding to two_step one_electron reaction.The adsorptions of RFH and RFH2 produced by reduction reactions in medium of 610,the solubilities of the adsorbed species produced by electro_reduction are good.


Investigation Of Adsorption Isotherms Of Myristic, Palmitic And Stearic Acids On Rice Hull Ash, Hüseyi̇n Topallar, Yüksel Bayrak Jan 1999

Investigation Of Adsorption Isotherms Of Myristic, Palmitic And Stearic Acids On Rice Hull Ash, Hüseyi̇n Topallar, Yüksel Bayrak

Turkish Journal of Chemistry

The adsorption of myristic, palmitic and stearic acids on rice hull ash from isooctane as solvent was studied and conformed to a Langmuir isotherm. Monolayer coverage was determined to be 40.08, 38.43 and 37.27 mg/g, respectively. The free energy of adsorption, \Delta G°_{ads}, for the adsorption was determined to be -6,25, -6.32 and -6.39 kcal mol^{-1} for the adsorbates, respectively. The equilibrium parameter indicated that rice hull ash is a good adsorbent for myristic, palmitic and stearic acids examined.


Adsorption Of Copper And Cadmium Lons By Activated Carbon From Rice Hulls, Murat Teker, Mustafa İmamoğlu, Ömer Saltabaş Jan 1999

Adsorption Of Copper And Cadmium Lons By Activated Carbon From Rice Hulls, Murat Teker, Mustafa İmamoğlu, Ömer Saltabaş

Turkish Journal of Chemistry

The removal of copper (II) and cadmium (II) ions from aqueous solutions, by adsorption on activated carbon prepared from rice hulls (ACRH), was investigated depending on pH, activated carbon dosage, contact time, initial metal concentration and solution temperature. The optimum values of pH, ACRH dosage and contact time were determined to be 5-8, 0.5 g ACRH/25 mL solution an 60 minutes respctively for the adsorption of Cu (II) ions and 5-8, 1.5 g ACRH/25 mL solution and 60 minutes for the adsorption of Cd (II) ions. From the initial concentrations, the constants for the Freundlich and Langmuir isotherm were calculated …