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Full-Text Articles in Physical Sciences and Mathematics
Synthesis And Properties Of Novel Polymeric Metal-Free And Metallophthalocyanines Containing Peripherally Long 1,2-Bis[(3-Oxapropyl)Oxa]Benzene Derivatives, Ahmet Bi̇lgi̇n, Durmuş Yanmaz, Çi̇ğdem Yağci
Synthesis And Properties Of Novel Polymeric Metal-Free And Metallophthalocyanines Containing Peripherally Long 1,2-Bis[(3-Oxapropyl)Oxa]Benzene Derivatives, Ahmet Bi̇lgi̇n, Durmuş Yanmaz, Çi̇ğdem Yağci
Turkish Journal of Chemistry
New polymeric phthalocyanine moieties (M = 2H, Zn, Ni, Cu, and Co) were synthesized via polytetracyclomerization reaction of o-bis[3-(3,4-dicyanophenoxy)propyloxy]benzene (3), which can be obtained by the reaction of 4-nitrophthalonitrile with o-bis[(3-hydroxypropyl)oxy]benzene. Aggregation and disaggregation behavior of the polymeric phthalocyanine (5) was studied with some alkali and earth alkali metal cations. Measured intrinsic viscosities of the polymeric phthalocyanines exhibited a substantial decreasing tendency with dilution of the solution. Thermogravimetric analysis was performed under air by using DSC and DTG/TGA techniques and indicated that these polymers have good thermal stability. AC and DC electrical conductivities of the polymeric phthalocyanines were investigated in …
Microwave-Assisted Synthesis Of Novel Nonperipherally Substituted Metallophthalocyanines Bearing (7-(Trifluoromethyl)Quinolin-4-Yl)Oxy Groups, Di̇dem Evren, Hacer Yasemi̇n Yeni̇lmez, Ayfer Kalkan Burat
Microwave-Assisted Synthesis Of Novel Nonperipherally Substituted Metallophthalocyanines Bearing (7-(Trifluoromethyl)Quinolin-4-Yl)Oxy Groups, Di̇dem Evren, Hacer Yasemi̇n Yeni̇lmez, Ayfer Kalkan Burat
Turkish Journal of Chemistry
The synthesis, characterization, and spectroscopic properties of novel nonperipherally tetrasubstituted metallophthalocyanines (zinc, cobalt, copper, manganese, and indium) bearing 4 (7-(trifluoromethyl)quinolin-4-yl)oxy units has been reported. The new compounds have been characterized using UV-Vis, IR, ^1H NMR, ^{13}C NMR, ^{19}F NMR, and mass spectroscopic data. The absorption properties of these new complexes were compared to those of peripherally substituted phthalocyanine derivatives. Based on the structural, spectroscopic, and absorption studies, it was found that the substitution effect altered the electronic structures significantly. The results provide useful information to understand the effect of peripheral or nonperipheral substitution on the properties of this macrocyclic ring. …