Physical Sciences and Mathematics Commons^™

An Experimental Investigation Of Coloring Matter In Canna Indica Flowers, James Clinton Vogt

University of the Pacific Theses and Dissertations

The research was carried out for the purpose of isolating and identifying the coloring matter in flowers of the canna indica (canna lily) variety. It was done by extracting the pigment from flower petals with methanol, amyl alcohol, and other solvents, and crystallizing the pigment as a salt. Physical properties such as solubility, color reactions, spectra and others were examined for this pigment. Chemical properties and degradation products were also examined in order to identify the chemical structure of the pigment.

M-Aminocyclohexanol, Leroy Mancel Law

University of the Pacific Theses and Dissertations

There has developed in recent years an interest in chemical materials that may have the ability to concentrate in and about carcinomic tissue.

Synthesis Of Acetyl Acetophenone, Hampton D. Proett

University of the Pacific Theses and Dissertations

The keytones are representative of one of the large groups of compounds of Organic Chemistry. Phenyl-methyl-ketone is the simplest representative of the mixed aliphatic-aromatic ketones. It is a member of a group of compounds which are soporific and hypnotic and are used in medicine as sleep producers and sedatives. It is found to a small extent in coal tar. It has basic properties and is extracted from the heavy oil of coal tar with sulfuric acid.

The purpose of this research is to synthesize one of the compounds which is not present in the compilation of the natural lists and …

The Carbon Compounds Of The Primeval Atmosphere, James Sherman Rogers

University of the Pacific Theses and Dissertations

The question of how and when life originated on t his planet has always been an intriguing one, exceeded perhaps in fascination only by that area of speculation which concerns itself with death and the afterlife . The latter problem has generally been approached along theological lines; the former problem , that of the origin of life, has been widely investigated along scientific lines as well . Indeed, the origin of life has always been one of the fundamental problems of science, and the increasingly sophisticated answers to the problem reflect the increasing potence and applicability of the methods of …

Construction And Calibration Of Equipment For Obtaining Heat Capacity Data At High Temperatures, David Wells Wood

University of the Pacific Theses and Dissertations

This is a study of the heat capacity substances at high temperatures at determined by means of drop-calorimetry. The heat capacity may be defined as the quantity of heat required to raise the temperature of a substance by 1^o C. This can be expressed as [see PDF file for formula]. The concept of heat capacity is used in connection with a certain defined path such as those of constant volume or constant pressure. The following definitions apply: [see PDF file for formula] = heat capacity at constant volume and [see PDF file for formula] = heat capacity at constant …

A Kinetic Study Of The Base Catalyzed Esterification Of Propionic Anhydride With Isopropyl And N-Propyl Alcohols Using A High Frequency Oscillometer, Carl Joel Abraham

University of the Pacific Theses and Dissertations

The purpose of this research project is to investigate the base catalyzed reaction of propionic anhydride with n-propyl and isopropyl alcohols using a high frequency (120 megacycles) oscillometer to follow the course of the reaction as it proceeds.

The high frequency oscillometer has been used for many types of analytical determinations, and a review of the work up to 1957 is available in a publication by E. H. Sargent Company. The oscillometer has found application in titrations (Hall 1952), analysis of binary systems (Thomas, Faegin, and Wilson 1951) , static ternary systems (West, Robickaus, and Burkhalter 1951) , the study …

Identification Of The Products And Mechanism Of The Disproportionation Of Di(P-Sulfonic Acid)Phenylthiocarbazide, Ralph Lee Riggs

University of the Pacific Theses and Dissertations

It is the purpose of this paper to separate and identify the products resulting from treatment of this compound with strong base. This will be done using both column and paper chromatography, and through interpretation of infrared spectra. In addition, a discussion of the structure of the complexes of heavy metals with di(p-sulfonic acid) phenylthiocarbazide in basic solution will be presented.

The Determination Of Ethanol In Aqueous Solution By Gas-Liquid Partition Chromatography, Robert L. Morrison

University of the Pacific Theses and Dissertations

The present chemical and physical methods for the determination of ethyl alcohol are all subject to systematic errors derived from any of a number of interfacing substances usually present in solution with the ethanol. Some of the most popular methods are slow and tedious and require a good deal of skill and technique to perform. The dichromate (2), pycnometer and refractometer methods are three such methods. The interfering substances most often present in industrial and food products are fusel oils and acetaldehyde. These substances interfere in the three methods just mentioned. It is of course possible to analyze for these …

Identification Of The Products And Mechanism Of Decomposition Of Thiazate, Paul Edward Williams

University of the Pacific Theses and Dissertations

This work is an additional facet of the research undertaken by Dr. Herschel Frye of the Department of Chemistry of the University of the Pacific while he was a graduate student at the University of Oregon. Frye succeeded in making an analytical reagent for zinc and other transition metals similar to dithiszone but water soluble. His approach was to to sulfonate the benzene rings thus giving water solubility because of the ionic nature of the sulfonic acid. The new reagent-tensed thiazate--was quite successful in its purpose, but the sections of the compound were somewhat different than dithizone. The purpose of …

Cosmology And Galactic Angular Momenta, Marmion Michael Richard Hays

University of the Pacific Theses and Dissertations

The plan of this paper is to present some observations and then in subsequent chapters to examine the two basic cosmological ideas in the light of these observations.

The first of the observations involves an estimate of the angular momentum in a given volume of space and the ratio of this momentum to the mass or number of nucleons in the given volume. We therefore wish to obtain a rough estimate of the angular momentum in that part of the universe which man may call his immediate surroundings, i.e., the solar system and galaxy.