Physical Sciences and Mathematics Commons^™

Manganese Oxide Mineral Phases Produced At Room Temperature Under Acidic Conditions Investigated With Xrd, Tem, Sem, Eds, And Bet, Nancy R. Birkner

UNLV Theses, Dissertations, Professional Papers, and Capstones

This thesis concerns characterization of synthetic manganese oxides belonging to mineral phases known as Birnessite and Cryptomelane. Presented here are the results of an experiment designed to examine the influence of sodium, potassium, chloride, and sulfate ions on the reduction of potassium permanganate under acidic conditions at room temperature to produce Birnessite and Cryptomelane. The experiments used KMnO4 as the source of Mn and the resulting Birnessite and Cryptomelane precipitates were washed with 18 Mn/cm NANOpure water at the end of syntheses. Several state-of-the-art solid state techniques were used to characterize the Mn-based oxide mineral phases. Based on the literature …

Democracy And The Environment In Latin America, Javier Albert Escamilla

UNLV Theses, Dissertations, Professional Papers, and Capstones

This study examines the ability of democratic and non-democratic states alike to protect the environment. Democracy has long been an important concept in the study of politics and environmental protection is an increasingly important issue in world politics. Advocates of democracy claim democratic states are better able to protect the environment than non-democracies. In contrast there are those that argue democracy's emphasis on individual rights leads to excessive resource consumption. This thesis employs a mixed methods approach to determine if democratic countries protect the environment more than their non-democratic counterparts. In short democracies do protect the environment better than non-democracies …

Evaluation Of Low-Temperature Fluoride Routes To Synthesize Actinide Nitrides And Oxide Solid Solutions, Gunanda Waduge Chinthaka Silva

UNLV Theses, Dissertations, Professional Papers, and Capstones

Actinide mononitrides have been considered as a possible nuclear fuel for the Generation-IV nuclear reactor systems. In the process of evaluating these actinide mononitrides as nuclear fuel, it is important to study different chemical and physical characteristics of these compounds. Synthesis of the materials is thus important. Carbothermic reduction is one of the techniques that have been used to synthesize actinide mononitrides. In this method, a mixture of actinide oxide such as UO ₂ and excess carbon is heat treated at temperatures greater than 1700 °C under a nitrogen atmosphere. The technique is however not promising in synthesizing the actinide …

Identifying Biomarkers For Resistance To Novel Cisplatin Analogues In Human Lung, Breast And Prostate Cancers, Becky Michelle Hess

UNLV Theses, Dissertations, Professional Papers, and Capstones

Cisplatin is a common therapeutic agent used in cancer treatment. Unfortunately, resistance to cisplatin in addition to severe side effects limits its use in cancer treatment. Two novel cisplatin analogues, 4DB and 4TB were shown to have varying cytotoxicity in lung, breast and prostate cancer cells. The hypothesis for this study states that the differences in 4DB and 4TB cytotoxicity among different tissue types is due to the type and efficiency of DNA repair mechanisms involved in response to these drugs.

To test the hypothesis, proteins involved in the rate limiting step of nucleotide excision repair (NER) and mismatch repair …

Uncertainty, Sensitivity And Geostatistical Studies Of Flow And Contaminant Transport In Heterogeneous Unsaturated Zone, Feng Pan

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objectives of this study are: (1) to develop a methodology of estimating probability density functions (PDFs) of unsaturated hydraulic parameters when field samples are sparse, (2) to evaluate the predictive uncertainties in flow and contaminant transport due to parameter uncertainties in the layer- and local-scale heterogeneities of hydraulic parameters in unsaturated zone (UZ), (3) to investigate the contributions of the parameter uncertainties to the flow and transport uncertainties, and (4) to estimate the spatial correlation structures of hydraulic parameters by incorporating prior information and site measurements.

At layer scale, the uncertainty assessment of flow and contaminant transport in UZ …

Case Study: Feasibility Analysis Of Renewable Energy Supply Systems In A Small Grid Connected Resort, Jody Robins

UNLV Theses, Dissertations, Professional Papers, and Capstones

This paper presents a case study on the feasibility of a small grid connected resort in the marine west coast climate of Canada to implement a renewable energy supply system. The current industry conditions of three renewable energy systems are explored including small and large wind energy conversion systems, solar photovoltaic cell systems, and energy cell systems. Furthermore, these three systems are evaluated using the power load, wind, and solar radiation information from a specific resort. The renewable energy source assessment and optimization software HOMER (National Renewable Energy Laboratory, US) is used to evaluate the costs and benefits of each …

The Influence Of Carbon Source Types And Nitrate On The Performance Of The Enhanced Biological Phosphorus Removal Systems, Shamim Ara Begum

UNLV Theses, Dissertations, Professional Papers, and Capstones

This research focuses on two issues in enhanced biological phosphorus removal (EBPR). The first issue encompasses the effect of the type of carbon sources (i.e. volatile fatty acids and non volatile fatty acids) on the microbiology of EBPR. The second issue deals with the influence of denitrification on EBPR. Few studies have been performed to investigate these two issues. The recent findings on these areas are summarized below to establish the knowledge gaps this dissertation attempted to address. Details on the specific findings can be found in the literature review portion of this proposal.

Going Green In The Hospitality Industry, Christina Wilson Micioni

UNLV Theses, Dissertations, Professional Papers, and Capstones

The purpose of this research is to examine whether a hotel’s greening efforts are a reason why everyday guests or hospitality professionals choose a hotel. Do meeting planners and business travelers expect certain things while staying at a hotel? Do the personal greening activities of a guest affect their hotel stay? This will also include the housekeeping needs of the guests and why they choose the hotel. The objective of the research will be to discover whether there is guest data to support the need for hotels to become green establishments.

A Study Of Relevance Feedback In Vector Space Model, Deepthi Katta

UNLV Theses, Dissertations, Professional Papers, and Capstones

Information Retrieval is the science of searching for information or documents based on information need from a huge set of documents. It has been an active field of research since early 19^th century and different models of retrieval came in to existence to cater the information need.

This thesis starts with understanding some of the basic information retrieval models, followed by implementation of one of the most popular statistical retrieval model known as Vector Space Model. This model ranks the documents in the collection based on the similarity measure calculated between the query and the respective document. The user …

The Sheep Pass Formation, A Record Of Late Cretaceous And Paleogene Extension Within The Sevier Hinterland, East-Central Nevada, Peter Alexander Druschke

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Sevier hinterland of western North America is considered by many to be an ancient proxy for the modern Andean Puna-Altiplano or Tibetan Plateau. However, controversies exist as tectonic setting and overall paleogeography of the Sevier hinterland during the Late Cretaceous and Paleogene. The Sheep Pass Formation type section within the southern Egan Range of east-central Nevada comprises a > 1 km thick sedimentary succession spanning the latest Cretaceous to Eocene, and provides a rare opportunity to test prevailing tectonic and paleogeographic models for the Sevier hinterland. New 1:12,000 scale field mapping inthe southern Egan Range indicates that up to three …

Magnetic Sensors For Biodetection, Pranjali Vineet Sneha Deshpande

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objective of thesis is to design magnetic sensor for detection of nanoparticles. Recently integrating the standard laboratory techniques into integrated system on chip is growing attention. Recent development is to combine magnetic markers and magnetoresistive sensors together in magnetic chip. In this thesis two magnetoresistive sensors were studied and designed.

By applying magnetic fields, magnetic nanoparticles can be manipulated on-chip, which can be utilized to pull the molecules to specific binding sites or to test the binding strength and distinguish between specifically and non-specifically bound molecules

Magnetoresistive sensors are compatible with the semiconductor industry which provides electronic signal directly …

A Survey Of Monge Properties, Swetha Sethumadhavan

UNLV Theses, Dissertations, Professional Papers, and Capstones

Monge properties play an important role in theoretical computer science. Many greedy algorithms are based on such properties, as is speedup in dynamic programming. Monge properties are simple monotonicity properties which are observed and used in various settings such as resource optimization, computational geometry, statistical sampling, computational biology and coding.

Turn Constrained Path Planning Problems, Victor M. Roman

UNLV Theses, Dissertations, Professional Papers, and Capstones

We consider the problem of constructing multiple disjoint paths connecting a source point s to a target point t in a geometric graph. We require that the paths do not have any sharp turn angles. We present a review of turn constrained path planning algorithms and also algorithms for constructing disjoint paths. We then combine these techniques and present an O(nlogn) time algorithm for constructing a pair of edge disjoint turn constrained paths connecting two nodes in a planar geometric graph. We also consider the development of a turn constrained shortest path map in the presence of …

The Synthesis And Systematic Evaluation Of Modified Polymeric Foams And Electrically Conductive Polyimide/Carbon/Metal Films, John Macharia Kinyanjui

UNLV Theses, Dissertations, Professional Papers, and Capstones

Thermally processed PU foams are examined as a function of processing temperatures (25, 45, 65, and 85°C) at the side, middle, and center of a simple cylindrical mold. The PU foams show both chemical and morphological differences as a function of the processing temperature and radial position within the mold. Thermal degradation of uretoneimine structures, the emergence of carbodiimide structures, and extent of reaction of isocyanate groups are measured using photoacoustic FTIR spectroscopy. Chemical gradients and morphology differences between the side, middle, and center of the molded foam are observed for all processing temperatures. The data indicate that thermal activation …

Substrate Monitoring, Contaminant Monitoring, And Educational Outreach On Quagga Mussels (Dreissena Bugensis) In Lake Mead, Nevada, Sara Ann Mueting

UNLV Theses, Dissertations, Professional Papers, and Capstones

The invasive species, the quagga mussel, Dreissena bugensis, was found in Lake Mead, Nevada-Arizona, USA on January 6, 2007. Since then, researchers have been attempting to quantify the amount of damage these mussels will cause to the lower Colorado River basin. Three projects were implemented in this thesis to research the quagga mussel in Lake Mead. First, a study to determine which types of substrates quagga mussels will grow on preferentially was conducted. Six different substrates, Acrylonitrile Butadiene Styrene (ABS) plastic, High Density Polyethylene (HDPE) plastic, Concrete Underlayment Board (CUB), aluminum, stainless steel and fiberglass, were placed in the Boulder …

Flowing Toward Sustainability: Two Stream Adjudications Analyzed Under The Iad Framework, Nancye Lou Bethurem

UNLV Theses, Dissertations, Professional Papers, and Capstones

One of the most significant problems impacting the western United States today is the lack of naturally occurring water resources, especially during this period of drought and explosive population growth. This has led to intense competition over water use and ownership in the arid and semi-arid regions of the United States. During this period of water resource scarcity, it is extremely important to determine the ownership of water rights in order to implement optimal management systems. Most western states use a system of "general stream adjudications" to make water rights ownership determinations.

General stream adjudications are legal proceedings used to …

Trophic Interactions Associated With Indroduction Of The Invasive Quagga Mussel In Lake Mead, Nevada, Eric Michael Loomis

UNLV Theses, Dissertations, Professional Papers, and Capstones

The ecology of Lake Mead is experiencing an uncertain future since the documented arrival of the invasive quagga mussel. Interactions among constituents of the food web will undoubtedly be altered over time, adversely affecting the popular sport fishery. This study is the first in Lake Mead to present historic trends in lower trophic interactions among threadfin shad and zooplankton before, and shortly after, the arrival of quagga mussels. Shad stomach content analysis revealed cladocerans and copepods were the dominant identifiable food items in Las Vegas Bay and Overton Arm of Lake Mead. Baseline energetics data through the use of stable …

Water Quality Changes In A Constructed Wetland At The Springs Preserve In Las Vegas, Nevada, Aaron Mathis Miller

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Springs Preserve near downtown Las Vegas, Nevada contains a seven-acre constructed wetland. Springs Preserve managers are planning to use water from the constructed wetland to irrigate creeks immediately north of the wetland. These creeks will be used by a variety ofaquatic wildlife, including endangered amphibians sensitive to harmful metalloids, such as selenium, lead, and arsenic.

In an attempt to answer toxicological questions about contaminant concentrations in the constructed wetland, three metals and metalloids (selenium, arsenic, and lead), two nutrients (nitrogen and phosphorus), and the major ionic species were analyzed at four sampling locations for aqueous concentrations, in two separate …

High Pressure Phase Transistions In The Lanthanide Sesquioxides, Jason Patrick Mcclure

UNLV Theses, Dissertations, Professional Papers, and Capstones

Crystallizing into 5 known polymorphic forms, the rare-Earth sesquioxides RE 2 O 3 represent a family of 4-f electron compounds that have been the subject of study for many years. Aspects of the systematics in the structural phase transitions for RE 2 O 3 (RE=La, Sm, Eu, Gd, Y, Er, Yb, Lu) under pressure were studied using diamond anvil cells (DACs). As a part of this study, detailed equation of state (EOS) data for all these compounds were obtained through the use of angle-dispersive x-ray diffraction (XRD) where anomalies in compression data led to the detailed investigation into one particular …

Characterization Of Iron Oxide Thin Films For Photoelectrochemical Hydrogen Production, Kyle Eustace Nelson George

UNLV Theses, Dissertations, Professional Papers, and Capstones

Solar energy is the most sustainable source of energy available. However, solar applications such as photovoltaic cells represent only a partial solution to weaning our dependence upon fossil fuels. Several methods of storing solar energy are currently being pursued, and chemical storage stands out as a promising option - combining design simplicity with high energy density, with hydrogen being particularly attractive because of its abundance and inherently clean nature. A monolithic Photoelectrochemical (PEC) device that produces hydrogen by electrolyzing water directly from sunlight has the benefit of utilizing "free" solar energy to drive the reaction.

Although α-Fe 2 O 3 …

Parametric Study Of Efficiency Measures For Home Energy Conservation In Las Vegas, Nevada, Todd M. France

UNLV Theses, Dissertations, Professional Papers, and Capstones

Pulte Homes, a production home builder and community developer partnering with the U.S. Department of Energy's Building America program, has collaborated with the Center for Energy Research at the University of Nevada, Las Vegas and NV Energy, the local electric utility, on an energy conservation project in the Las Vegas Valley.

This study entails four model homes at a new development in the Summerlin community of Las Vegas, Nevada, named Villa Trieste. The home models, ranging in floor plan area from 1,487 to 1,777 square feet, have been constructed under the Environments for Living program and are LEED (Leadership in …

An Evaluation Of Lead Hazards In Pre-1978 Residental Housing Within Clark County, Nevada, Usa, Erika Raquel Torres

UNLV Theses, Dissertations, Professional Papers, and Capstones

Lead poisoning remains a public health concern due to leads persistence in the environment from anthropogenic uses. Initial efforts to address the impacts of lead on vulnerable communities have included secondary prevention measures which typically occur after a child has been poisoned. However, in recent years there has been a pragmatic shift toward primary prevention efforts.

This study evaluates lead hazards identified through primary prevention activities in residential housing within Clark County, Nevada, USA. It is the first study to systematically address and evaluate pre-1978 housing in Southern Nevada. Risk assessments were conducted in 81 dwellings built prior to 1979 …

Controlled Functionalization Of Crystalline Polyolefins And Their Application In Soluble Polymer Support, Jihoon Shin

UNLV Theses, Dissertations, Professional Papers, and Capstones

Functionalization of polyolefins has been recognized as a useful methodology for the generation of new materials with a wide range of applications. Recently, crystalline or semi-crystalline polyolefins have drawn increasing attention in both industrial and academic fields as one of the most interesting engineering plastics, due to their remarkable physical and mechanical properties. This dissertation describes: (1) novel methods for the direct postfunctionalization of crystalline polyolefins to introduce functionality, (2) characterizations for the functionalized polymers to analyze their structures, molecular-weight properties, thermal properties, and hydrophilicity, and (3) an application of the modified crystalline polystyrene as a soluble polymer support for …

Effects Of Similarity Metrics On Document Clustering, Rushikesh Veni

UNLV Theses, Dissertations, Professional Papers, and Capstones

Document clustering or unsupervised document classification is an automated process of grouping documents with similar content. A typical technique uses a similarity function to compare documents. In the literature, many similarity functions such as dot product or cosine measures are proposed for the comparison operator.

For the thesis, we evaluate the effects a similarity function may have on clustering. We start by representing a document and a query, both as a vector of high-dimensional space corresponding to the keywords followed by using an appropriate distance measure in k-means to compute similarity between the document vector and the query vector to …

Evaluation Of Extraction Chromatography Resins For Rapid Actinide Analysis, Julie Marisa Gostic

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this work, physical and chemical parameters associated with extraction chromatography separation procedures were investigated for rapid actinide analysis. A vacuum box system was designed in-house and was characterized in terms of flow rate reproducibility, matrix effects on flow rate for sequential elution, and actinide separation efficiency using different types of resin (TEVA, DGA and TRU). Results indicated that the columnar kinetics of the resins were sufficiently rapid to run high purity samples through the unit over a wide range of flow rates for all resin types. Single matrix interferences at a metal ion ratio of 1:10 6 relative to …

Hierarchical Routing In Manets Using Simple Clustering, Adam Carnine

UNLV Theses, Dissertations, Professional Papers, and Capstones

This thesis presents both a review of current MANET routing protocols and a new MANET routing algorithm. The routing protocols reviewed include representative samples from the three primary forms of routing found in MANETS: proactive routing, reactive routing and hybrid routing. Secure algorithms are given special treatment in the review. In addition several protocol enhancements are discussed.

The proposed routing protocol is designed to support networks of a medium size, containing over 200 nodes but less than 3,000 nodes. The design is intentionally simple to allow ease of implementation in comparison with other MANET protocols that provide similar functionality.

Geoelectrical Response Of Surfactant Solutions In A Quartzitic Sand Analog Aquifer, Meghan Therese Magill

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this project, the resistivity and phase shift of ten surfactant aqueous solutions in a sand matrix were measured using spectral induced polarization (SIP). In addition, specific conductivity, pH, dissolved oxygen, and dielectric constant measurements of the solutions were also evaluated. The frequency range assessed was 0.091-12000Hz. The surfactants, which are typically used in the remediation of tetrachloroethylene, were Aerosol MA 80-I, Dowfax 8390, and Steol CS-330. The surfactants were mixed into solutions of both deionized and tap water at varying concentrations and injected into a closed system of silica sand. The surfactant treatments altered resistivity, specific conductivity, and pH …

Ac Susceptibility And Heat Capacity Studies Of The Geometrically Frustrated Pyrochlores Terbium Titanium Tin Oxides And Holmium Titanates, Daniel Antonio

UNLV Theses, Dissertations, Professional Papers, and Capstones

Materials with a geometrically frustrated magnetic pyrochlore lattice have been of interest due to their unusual ground states. Tb 2 Ti 2 O 7 is known for having a spin liquid ground state which does not transition to a long-range ordered state down to at least 50 mK. Ho 2 Ti 2 O 7 has a macroscopically degenerate spin ice ground state which resembles that of the proton ordering in water ice. Heat Capacity measurements of Tb 2 Ti 2- x Sn x O 7 were done down to 0.36 K and AC magnetic susceptibility measurements of Ho 2- x …

Soil Moisture And Water Stage Estimation Using Precipitation Radar, Sumit Puri

UNLV Theses, Dissertations, Professional Papers, and Capstones

In south-western United States, soil moisture data is important for drought studies in the region which is experiencing a drought for many years, whereas in South Florida, water stage data is required by hydrologists to monitor the hydrological flow in wetlands. Soil moisture data and water stage data are not sufficiently available due to sparse monitoring stations. Installation of dense measuring stations over an extended area is costly and labor intensive. Therefore, there is a need to develop an alternative method of measuring soil moisture and water stage. Microwave remote sensing has proven to be a useful tool in the …

Spectroscopic Investigation Of Palladium-Copper Bimetallic Systems For Pem Fuel Cell Catalysts, Timo Hofmann

UNLV Theses, Dissertations, Professional Papers, and Capstones

One of the main barriers to commercialization of polymer electrolyte membrane fuel cells systems is cost, which is largely due to the need of platinum (Pt)-containing catalysts. In this thesis we investigate bimetallic systems consisting of a base metal (copper) and a noble metal (palladium) that, as an alloy on the nanoscale, mimic the electronic properties that make Pt desirable as a catalyst.

We present a detailed investigation of the electronic structure of carbon-supported Pd/Cu nanoparticle catalysts, model bilayer thin film systems, alloys, and various metal reference samples. We have investigated the valence band structure of the catalysts using a …