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Reactions Of N-Aminopyrimidine Derivatives With 1,3-Dicarbonyl Compounds, Zülbi̇ye Önal, Behzat Altural

Turkish Journal of Chemistry

The reactions of 1-Amino-pyrimidine derivatives (1) and some 1,3-dicarbonyl compounds (2) were realized in the presence of p-toluensulfonic acid catalyst to give convenient enamine (3) and/or imine derivatives (4). In the same way, the enamine (5) and/or imine derivatives (6) were synthesized using (1) and 1,3-indanedione which is one of the different 1,3-dicarbonyl compounds. The molecular structures of all the prepared compounds were determined by ^1H-nmr, ^{13}C-nmr, i.r. spectra and elemental analyses, and were drawn by taking imine-enamine tautomerism into account.