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Physics and Astronomy Faculty Publications and Presentations

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Nanoparticles

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Full-Text Articles in Physical Sciences and Mathematics

A Review On Antibacterial Activity Of Nanoparticles, Badr-Edine Sadoq, Mohammed Reda Britel, Adel Bouajaj, Ramzi Maâlej, Ahmed Touhami, Marwa Abid, Hanen Douiri, Fakhita Touhami, Amal Maurady Oct 2023

A Review On Antibacterial Activity Of Nanoparticles, Badr-Edine Sadoq, Mohammed Reda Britel, Adel Bouajaj, Ramzi Maâlej, Ahmed Touhami, Marwa Abid, Hanen Douiri, Fakhita Touhami, Amal Maurady

Physics and Astronomy Faculty Publications and Presentations

The increasing resistance of bacteria to antibiotic agents is a main global public health problem. The use of nanoparticles is one of the promising ways to overcome microbial resistance to antimicrobial agents. Metal nanoparticles are increasingly used to target bacterial strains. Advances in nanotechnology, in particular the ability to synthesize nanoparticles of specific size and shape, are likely to lead to the development of new antibacterial agents. The antibacterial activities of nanoparticles are largely influenced by their sizes and large surface area/mass ratio. The antibacterial mechanisms of nanoparticles are poorly understood, but the currently accepted mechanisms include oxidative stress induction, …


Magnetic Sensing Potential Of Fe3o4 Nanocubes Exceeds That Of Fe3o4 Nanospheres, Arati G. Kolhatkar, Yi-Ting Chen, Pawilai Chinwangso, Ivan Nekrashevich, Gamage C. Dannangoda, Ankit Singh, Andrew C. Jamison, Oussama Zenasni, Irene A. Rusakova, Karen S. Martirosyan Nov 2017

Magnetic Sensing Potential Of Fe3o4 Nanocubes Exceeds That Of Fe3o4 Nanospheres, Arati G. Kolhatkar, Yi-Ting Chen, Pawilai Chinwangso, Ivan Nekrashevich, Gamage C. Dannangoda, Ankit Singh, Andrew C. Jamison, Oussama Zenasni, Irene A. Rusakova, Karen S. Martirosyan

Physics and Astronomy Faculty Publications and Presentations

This paper highlights the relation between the shape of iron oxide (Fe3O4) particles and their magnetic sensing ability. We synthesized Fe3O4 nanocubes and nanospheres having tunable sizes via solvothermal and thermal decomposition synthesis reactions, respectively, to obtain samples in which the volumes and body diagonals/diameters were equivalent. Vibrating sample magnetometry (VSM) data showed that the saturation magnetization (Ms) and coercivity of 100–225 nm cubic magnetic nanoparticles (MNPs) were, respectively, 1.4–3.0 and 1.1–8.4 times those of spherical MNPs on a same-volume and same-body diagonal/diameter basis. The Curie temperature for the cubic Fe3O4 MNPs for each size was also higher …


Slip-Jump Model For Carbon Combustion Synthesis Of Complex Oxide Nanoparticles, A. A. Markov, Mkhitar A. Hobosyan, Karen S. Martirosyan Jan 2016

Slip-Jump Model For Carbon Combustion Synthesis Of Complex Oxide Nanoparticles, A. A. Markov, Mkhitar A. Hobosyan, Karen S. Martirosyan

Physics and Astronomy Faculty Publications and Presentations

Carbon Combustion Synthesis of Oxides (CCSO) is a promising method to produce submicron- and nano- sized complex oxides. The CCSO was successfully utilized for producing several complex oxides, a complete theoretical model including the sample porosity, fl ow parameters and reaction energetics is needed to predict the combustion parameters for CCSO. In this work, we studied the ignition temperature and combustion wave axial temperature distribution, activation energy, combustion heat and thermal losses for a typical CCSO synthesis for cylindrical samples of Ni-Zn ferrites with high (>85%) porosity. We developed a two level combustion model of chemically active nano-dispersed mixture, …


Fabrication Of Yttrium Ferrite Nanoparticles By Solution Combustion Synthesis, A. A. Saukhimov, Mkhitar A. Hobosyan, Gamage C. Dannangoda, N. N. Zhumabekova, S. E. Kumekov Jan 2014

Fabrication Of Yttrium Ferrite Nanoparticles By Solution Combustion Synthesis, A. A. Saukhimov, Mkhitar A. Hobosyan, Gamage C. Dannangoda, N. N. Zhumabekova, S. E. Kumekov

Physics and Astronomy Faculty Publications and Presentations

The ternary oxide system Y-Fe-O presents fascinating magnetic properties that are sensitive to the crystalline size of particles. There is a major challenge to fabricate these materials in nano-crystalline forms due to particle conglomeration during nucleation and synthesis. In this paper we report the fabrication of nano sized crystalline yttrium ferrite by solution combustion synthesis (SCS) where yttrium and iron nitrates were used as metal precursors with glycine as a fuel. The magnetic properties of the product can be selectively controlled by adjusting the ratio of glycine to metal nitrates. Yttrium ferrite nano-powder was obtained by using three concentration of …


Reactive Self-Heating Model Of Aluminum Spherical Nanoparticles, Karen S. Martirosyan, Maxim Zyskin Jan 2013

Reactive Self-Heating Model Of Aluminum Spherical Nanoparticles, Karen S. Martirosyan, Maxim Zyskin

Physics and Astronomy Faculty Publications and Presentations

Aluminum-oxygen reaction is important in highly energetic and high pressure generating systems. Recent experiments with nanostructured thermites suggest that oxidation of aluminum nanoparticles occurs in a few microseconds. Such rapid reaction cannot be explained by a conventional diffusion-based mechanism. We present a rapid oxidation model of a spherical aluminum nanoparticle, using Cabrera-Mott moving boundary mechanism, and taking self-heating into account. In our model, electric potential solves the nonlinear Poisson equation. In contrast with the Coulomb potential, a “double-layer” type solution for the potential and self-heating leads to enhanced oxidation rates. At maximal reaction temperature of 2000 C, our model predicts …


Carbon Monoxide Adsorption On Platinum-Osmium And Platinum-Ruthenium-Osmium Mixed Nanoparticles, N. Dimakis, Nestor E. Navarro, Eugene S. Smotkin Jan 2013

Carbon Monoxide Adsorption On Platinum-Osmium And Platinum-Ruthenium-Osmium Mixed Nanoparticles, N. Dimakis, Nestor E. Navarro, Eugene S. Smotkin

Physics and Astronomy Faculty Publications and Presentations

Density functional calculations (DFT) on carbon monoxide (CO) adsorbed on platinum, platinum-osmium, and platinum-ruthenium-osmium nanoclusters are used to elucidate changes on the adsorbate internal bond and the carbon-metal bond, as platinum is alloyed with osmium and ruthenium atoms. The relative strengths of the adsorbate internal bond and the carbon-metal bond upon alloying, which are related to the DFT calculated C–O and C–Pt stretching frequencies, respectively, cannot be explained by the traditional 5σ-donation/2π*-back-donation theoretical model. Using a modified π-attraction σ-repulsion mechanism, we ascribe the strength of the CO adsorbate internal bond to changes in the polarization of the adsorbate-substrate hybrid orbitals …