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Full-Text Articles in Physical Sciences and Mathematics

Experimental Limestone Dissolution And Changes In Multiscale Structure Using Small- And Ultra Small- Angle Neutron Scattering, Chad Alan Novack Dec 2015

Experimental Limestone Dissolution And Changes In Multiscale Structure Using Small- And Ultra Small- Angle Neutron Scattering, Chad Alan Novack

Masters Theses

Small angle neutron scattering (SANS), ultra-small angle neutron scattering (USANS), and backscatter electron (BSE) imaging, along with neutron computed tomography (NCT) were used in this study to experimentally quantify pore size, distribution, and connectivity of dissolved limestone geometries. Eight samples of Indiana limestone of two different initial permeabilities (2-4 mD and 70 mD ) [millidarcy] were reacted with HCl [hydrochloric acid] solutions at differing pH (2 and 4), and flow rates (0.1 and 10 cm3/min) [cubic centimeters per minute] to describe a broad range of parameters that affect limestone dissolution. NCT was first used to image the dissolution …


Measurement Of Hysteretic Shale Capillary Pressure – Saturation Relationships Using A Water Activity Meter, Brendan Michael Donnelly Aug 2015

Measurement Of Hysteretic Shale Capillary Pressure – Saturation Relationships Using A Water Activity Meter, Brendan Michael Donnelly

Masters Theses

Capillary pressure is the pressure difference across the interface of two immiscible fluids within a porous medium due to the interfacial tension between fluids and is related to both the properties of the fluids and the porous medium. Capillary pressure within a porous medium will change depending upon its degree of saturation. Understanding the relationship between capillary pressure and saturation for a rock allows for the modeling of multi-phase flow. Many traditional methods of measuring capillary pressure are unsuitable for the characterization of shale due to their inability to measure the high capillary pressures found within the small pores. Furthermore, …


Characterizing Groundwater Ch4 And 222rn In Relation To Hydraulic Fracturing And Other Environmental Processes In Letcher County, Ky, St. Thomas Majeau Ledoux May 2015

Characterizing Groundwater Ch4 And 222rn In Relation To Hydraulic Fracturing And Other Environmental Processes In Letcher County, Ky, St. Thomas Majeau Ledoux

Masters Theses

Hydraulic fracturing of shale deposits has greatly increased the productivity of the natural gas industry by allowing it to exploit previously inaccessible reservoirs. However, previous research has demonstrated that this practice can contaminate shallow aquifers with CH4 [methane] from deeper formations. This study compares concentrations and isotope compositions of CH4 sampled from domestic groundwater wells in Letcher County, Kentucky in order to characterize its occurrence and origins in relation to neighboring hydraulically fractured natural gas wells. Additionally, this study tests the reliability of 222Rn [radon] as an alternative tracer to CH4 in identifying processes of gas …