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Transition Metal Complexes Of Pyridyltriazole And Bipyridine Ligands, Sen Gao
Transition Metal Complexes Of Pyridyltriazole And Bipyridine Ligands, Sen Gao
LSU Doctoral Dissertations
Four Ni(II) complexes have been obtained with the pyridyltriazole ligand, bpt, or the bis(pyridyltriazole) ligand, m-xpt, in chapter 2. This work was carried out as a comparison with the previously established coordination chemistry of copper(II) with bpt and m-xpt. Initially, the reaction between Ni(II) and bpt only produced one mononuclear compound, [Ni(bpt)2(H2O)2](NO3)2 (1). In order to study the formation of Ni-bpt and Ni-m-xpt complexes in solution, mixtures of Ni(NO3)2 and ligand (m-xpt or bpt) were prepared in different ratios and …