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Articles 1 - 30 of 57
Full-Text Articles in Physical Sciences and Mathematics
Stability In Dynamical Polysystems, George Cazacu
Stability In Dynamical Polysystems, George Cazacu
LSU Doctoral Dissertations
A dynamical polysystem consists of a family of continuous dynamical systems, all acting on a given metric space. The first chapter of the present thesis shows a generalization of control systems via dynamical polysystems and establishes the equivalence of the two notions under certain lipschitz condition on the function defining the dynamics. The remaining chapters are focused on a basic theory of dynamical polysystems. Some topological properties of limit sets are described in Chapter 2. Chapters 3 and 4 provide characterizations for various notions of strong stability. Chapter 5 makes use of the theory of closed relations to study Lyapunov …
Multiscale Strain Analysis, Timothy Donald Breitzman
Multiscale Strain Analysis, Timothy Donald Breitzman
LSU Doctoral Dissertations
The mathematical homogenization and corrector theory relevant to prestressed heterogeneous materials in the linear-elastic regime is discussed. A suitable corrector theory is derived to reconstruct the local strain field inside the composite. Based on this theory, we develop an inexpensive numerical method for multi scale strain analysis within a prestressed heterogeneous material. The theory also provides a characterization of the macroscopic strength domain. The strength domain places constraints on the homogenized strain field which guarantee that the actual strain in the heterogeneous material lies inside the strength domain of each material participating in the structure.
An Empirical Study Of Imputation Techniques For Software Data Sets, Sumanth Yenduri
An Empirical Study Of Imputation Techniques For Software Data Sets, Sumanth Yenduri
LSU Doctoral Dissertations
Software Project Effort/Cost/Time Estimation has been one of the hot topics of research in the current software engineering industry. Solutions for effort/cost/time estimation are in great demand. Knowledge of accurate effort/cost/time estimates early in the software project life cycle enables project managers manage and exploit resources efficiently. The constraints of cost and time can also be met. To this day, most companies rely on their historical database of past project data sets to predict estimates for future projects. Like other data sets, software project data sets also suffer from numerous problems. The most important problem is they contain missing/incomplete data. …
Comparative Studies Of Sperm Cryopreservation Of Diploid And Tetraploid Pacific Oysters, Qiaoxiang Dong
Comparative Studies Of Sperm Cryopreservation Of Diploid And Tetraploid Pacific Oysters, Qiaoxiang Dong
LSU Doctoral Dissertations
This dissertation addressed comparative studies of sperm cryopreservation of diploid and tetraploid Pacific oysters, Crassostrea gigas, with an emphasis on the development of standardized and optimized protocols. This includes comparative ultrastructural differences between sperm from diploid and tetraploid oysters, methods for the rapid estimation of sperm concentration, optimization of cryopreservation, and evaluation of the mechanisms for sperm agglutination (formation of clumps or elongated "noodles") in thawed samples. Currently, cryopreserved sperm has not been commercialized in any aquatic species, and standardization and optimization could greatly benefit the potential commercialization of its use. In oysters specifically, cryopreserved sperm from tetraploids would facilitate …
Nitrate Reduction And Methane Formation As Influenced By Iron-Centered Intermediate Redox Processes In Rice Soils, Bin Huang
LSU Doctoral Dissertations
Rice fields are a major source of the greenhouse gases methane (CH4) and nitrous oxide (N2O) and contribute to nitrate (NO3-) pollution in waters. Ferric iron (Fe3+) and manganic manganese (Mn4+) are two intermediate alternative electron acceptors (AEAs) capable of regeneration in freshwater soils. In this investigation, the influences of iron-centered intermediate redox processes on NO3- reduction and CH4 formation in rice soils were studied using soil slurries, soil columns, and potted rice. Reduction of Fe3+-centered intermediate AEAs was mainly mediated by obligate anaerobes …
Quasicontinuous Derivatives And Viscosity Functions, Rodica Cazacu
Quasicontinuous Derivatives And Viscosity Functions, Rodica Cazacu
LSU Doctoral Dissertations
In this work we demonstrate how the continuous domain theory can be applied to the theory of nonlinear optimization, particularly to the theory of viscosity solutions. We consider finding the viscosity solution for the Hamilton-Jacobi equation H(x, y) = g(x), with continuous hamiltonian, but with possibly discontinuous right-hand side. We begin by finding a new function space Q(X,L), the space of equivalence classes of quasicontinuous functions from a locally compact set X to a bicontinuous lattice L and we will define on Q(X,L) the qo-topology, which is a variant of classical order topology defined on complete lattices. On this …
Analytical Separations Using Polymetric Surfactants, Mary Waithira Kamande
Analytical Separations Using Polymetric Surfactants, Mary Waithira Kamande
LSU Doctoral Dissertations
The goal of the research presented in this dissertation is to develop effective analytical methods for the separation of both achiral and chiral analytes using polymeric surfactants. Three analytical techniques are employed to accomplish this objective: open-tubular capillary electrochromatography (OT-CEC), open-tubular capillary electrochromatography coupled to mass spectrometry (OT-CEC/MS), and micellar affinity gradient focusing (MAGF). This research work presents novel application of polymeric surfactants that contributes to improved separations of difficult to separate analytes. The first part focuses on the application of an achiral polyelectrolyte multilayer (PEM) coating using OT-CEC. The PEM coating consisting of the cationic polymer poly (diallyldimethylammonium chloride), …
Economic Valuation Of Natural Resource Management: A Case Study Of The Benuaq Dayak Tribe In Kalimantan, Indonesia, Indah D. Kusuma
Economic Valuation Of Natural Resource Management: A Case Study Of The Benuaq Dayak Tribe In Kalimantan, Indonesia, Indah D. Kusuma
LSU Doctoral Dissertations
The unavailability of total economic values of indigenous people in Indonesia, both in the short and long term, has created the rejection of their existences in the forest area. The purpose of this study is to estimate the total economic value of sustainable forest management conducted by indigenous tribes in Indonesia using total economic value concepts. The tribe’s total economic value is expressed by estimating the use value, indirect use value and non-use value. The study used benefit transfer and survey methods using questionnaires to estimate the tribe’s total economic value. The estimated total economic value of the Benuaq Dayak …
Learning Discrete Hidden Markov Models From State Distribution Vectors, Luis G. Moscovich
Learning Discrete Hidden Markov Models From State Distribution Vectors, Luis G. Moscovich
LSU Doctoral Dissertations
Hidden Markov Models (HMMs) are probabilistic models that have been widely applied to a number of fields since their inception in the late 1960’s. Computational Biology, Image Processing, and Signal Processing, are but a few of the application areas of HMMs. In this dissertation, we develop several new efficient learning algorithms for learning HMM parameters. First, we propose a new polynomial-time algorithm for supervised learning of the parameters of a first order HMM from a state probability distribution (SD) oracle. The SD oracle provides the learner with the state distribution vector corresponding to a query string. We prove the correctness …
The Establishment, Expansion And Ecosystem Effects Of Phragmites Australis, An Invasive Species In Coastal Louisiana, Lee Ellis Stanton
The Establishment, Expansion And Ecosystem Effects Of Phragmites Australis, An Invasive Species In Coastal Louisiana, Lee Ellis Stanton
LSU Doctoral Dissertations
As biological invasions have become a common phenomenon throughout the world, ecologists have intensified efforts to understand why natural communities are susceptible to invasion. Invading species can cause shifts in community structure that result in irreversible changes to ecosystem function. Phragmites australis has rapidly spread in North American coastal wetlands during the past 50 years and has become a dominant feature in Northern Gulf of Mexico brackish marshes. The rate at which Phragmites is spreading or the mechanisms controlling its establishment in these marshes is unknown. My research objectives were to: (1) determine the spatial and temporal patterns of Phragmites …
Molecular Recognition And Its Underlying Mechanisms In Molecularly Imprinted Polymers, Ryan Simon
Molecular Recognition And Its Underlying Mechanisms In Molecularly Imprinted Polymers, Ryan Simon
LSU Doctoral Dissertations
Molecular recognition in molecularly imprinting polymers (MIPs) is governed by two mechanisms: pre-organization of functional groups and shape specificity of the binding site. While pre-organization of functional groups has been studied extensively, shape specificity of the binding site has not been rigorously explored. The goal of this research is to determine the influence of shape specificity on molecular recognition in MIPs (Chapter 2). Once shape selectivity was proven to play a vital role in molecular recognition, it was important to determine if pre-organization of functional groups or shape specificity was the dominating factor in determining molecular recognition in the binding …
Komatiites Of The Weltevreden Formation, Barberton Greenstone Belt, South Africa: Implications For The Chemistry And Temperature Of The Archean Mantle, Keena Kareem
LSU Doctoral Dissertations
The komatiites of the 3.29 Ga Weltevreden Formation, Barberton Greenstone Belt, South Africa represent extremely magnesian lavas derived from the Archean mantle. Three related papers are presented on aspects of the temperature and composition of the Archean mantle, and surface alteration processes. Petrographical and geochemical analyses confirm that olivines from the komatiites retain much of their original igneous character, containing fresh olivines, pyroxenes, and chromites. The olivines from the Weltevreden Formation are extremely magnesian, with Fo contents up to 95.6. Primitive mantle normalized Gd/Yb values near 1, and Al2O3/TiO3 values of 26-33 for these rocks …
An Evaluation Of The Enantiomeric Recognition Of Amino Acid Based Polymeric Surfactants And Cyclodextrins Using Spectroscopic And Chromatographic Methods, Bertha Cedillo Valle
An Evaluation Of The Enantiomeric Recognition Of Amino Acid Based Polymeric Surfactants And Cyclodextrins Using Spectroscopic And Chromatographic Methods, Bertha Cedillo Valle
LSU Doctoral Dissertations
The scope of this dissertation is to explore the enantiomeric recognition properties of amino acid based polymeric surfactants using a combination of analytical techniques including chromatographic and spectroscopic methods. Chapter 1 includes an introduction to chirality and chiral separations using capillary electrophoresis. Using cyclodextrin modified micellar electrokinetic chromatography (CD-MEKC), the enantioseparation of three binaphthyl derivatives using native alpha- and beta-cyclodextrins in combination with various diastereomers of chiral polymeric surfactants (PS) was examined. A reversal of enantiomeric order was observed with the enantiomers of (1,1 S-binaphthyl-2,2 S-diamine (BNA) and (1,1 S-binaphthol (BOH) due to a competition between the two chiral selectors …
Adaptive Remote Visualization System With Optimized Network Performance For Large Scale Scientific Data, Mengxia Zhu
Adaptive Remote Visualization System With Optimized Network Performance For Large Scale Scientific Data, Mengxia Zhu
LSU Doctoral Dissertations
This dissertation discusses algorithmic and implementation aspects of an automatically configurable remote visualization system, which optimally decomposes and adaptively maps the visualization pipeline to a wide-area network. The first node typically serves as a data server that generates or stores raw data sets and a remote client resides on the last node equipped with a display device ranging from a personal desktop to a powerwall. Intermediate nodes can be located anywhere on the network and often include workstations, clusters, or custom rendering engines. We employ a regression model-based network daemon to estimate the effective bandwidth and minimal delay of a …
Hydrophobic Guar Gum Derivatives Prepared By Controlled Grafting Processes For Hydraulic Facturing Applications, Ahmad Bahamdan
Hydrophobic Guar Gum Derivatives Prepared By Controlled Grafting Processes For Hydraulic Facturing Applications, Ahmad Bahamdan
LSU Doctoral Dissertations
The synthesis of new water soluble guar gum derivatives is described. Introduction of polyalkoxyalkyleneamide grafts to guar gum or hydroxyopropyl guar was achieved in a three step process: carboxymethylation with sodium chloroacetate, esterification with dimethyl sulfate and amidation with a series of polyalkoxyalkylene-amines. The process steps were followed using infrared spectroscopy; the grafted guar derivatives were characterized using FT-IR and 1H NMR. A series of hydroxypropyl guar derivatives with degrees of carboxymethylations ranging from 0.15-0.25 were modified with polyalkoxyalkyleneamines with molecular weights ranging from 300-3000. The ratio of oxypropylene to oxoethylene units in the polyalkoxyalkyleneamines was varied from 9/1 …
The Stereoselective Synthesis Of The Butyrolactone-Bridged [8-5-5] Tricyclic Ring Systems Of (+/-)-Asteriscanolide Via The Titanium-Mediated Hetero-Pauson-Khand Reaction, Mohamed G. Sherriff
The Stereoselective Synthesis Of The Butyrolactone-Bridged [8-5-5] Tricyclic Ring Systems Of (+/-)-Asteriscanolide Via The Titanium-Mediated Hetero-Pauson-Khand Reaction, Mohamed G. Sherriff
LSU Doctoral Dissertations
The stereoselective construction of the tricyclic ring system of asteriscanolide from cyclooctadiene has been achieved. The synthesis involves two main steps; the synthesis of the aldehyde precursor(5)and the titanium-mediated cabocyclization of 5 to make the three rings of 43 stereoselectively.
Dissipative Lipschitz Dynamics, Vinicio Rafael Rios
Dissipative Lipschitz Dynamics, Vinicio Rafael Rios
LSU Doctoral Dissertations
In this dissertation we study two related important issues in control theory: invariance of dynamical systems and Hamilton-Jacobi theory associated with optimal control theory. Given a control system modelled as a differential inclusion, we provide necessary and sufficient conditions for the strong invariance property of the system when the dynamic satisfies a dissipative Lipschitz condition. We show that when the dynamic is almost upper semicontinuous and satisfies the dissipative Lipschitz property, these conditions can be expressed in terms of approximate Hamilton-Jacobi inequalities, which subsumes the classic infinitesimal characterization of strongly invariant systems given under the Lipschitz assumtion. In the important …
Radiative Transfer Modeling Of Thermal Infrared Emissivity Spectra: Applications To Martian Regolith Observations, Karly Mariah Pitman
Radiative Transfer Modeling Of Thermal Infrared Emissivity Spectra: Applications To Martian Regolith Observations, Karly Mariah Pitman
LSU Doctoral Dissertations
Satellite and rover remote sensing of planetary regolith surfaces, in the form of thermal infrared emissivity spectra taken at nadir and off-nadir angles of emergence from the surface, requires use of theoretical models for interpretation of constituent grain physical properties. However, such models have remained in stasis in recent years, with nearly a ten-year gap in significant advances. To date, no radiative transfer model (semiempirical, exact, or hybrid solution) has been able to adequately predict the nadir emissivity behavior of simple mineral assemblages. Few measurements have been attempted in the laboratory or field regarding directional emissivity effects of planetary regoliths; …
Capillary And Microchip Gel Electrophoresis Using Multiplexed Fluorescence Detection With Both Time-Resolved And Spectral-Discrimination Capabilities: Applications In Dna Sequencing Using Near-Infrared Fluorescence, Li Zhu
LSU Doctoral Dissertations
Increasing the information content obtainable from a single assay and system miniaturization has continued to be important research areas in analytical chemistry. The research presented in this dissertation involves the development of a two-color, time-resolved fluorescence microscope for the acquisition of both steady-state and time-resolved data during capillary and microchip electrophoresis. The utility of this hybrid fluorescence detector has been demonstrated by applying it to DNA sequencing applications. Coupling color discrimination with time-resolved fluorescence offers increased multiplexing capabilities because the lifetime data adds another layer of information. An optical fiber-based fluorescence microscope was constructed, which utilized fluorescence in near-IR region, …
Automatic Segmentation Of Magnetic Resonance Images Of The Brain, Kirk V. N. Spence
Automatic Segmentation Of Magnetic Resonance Images Of The Brain, Kirk V. N. Spence
LSU Doctoral Dissertations
Magnetic resonance imaging (MRI) is a technique used primarily in medical settings to produce high quality images of the human body’s internal anatomy. Each image is of a thin slice through the body, with the typical distance between slices being a few millimeters. Brain segmentation is the delineation of one or more anatomical structures within images of the brain. It promotes greater understanding of spatial relationships to aid in such tasks as surgical planning and clinical diagnoses, particularly when the segmented outlines from each image slice are displayed together as a surface in three-dimensions. A review of the literature indicates …
Synthesis Of Symmetric And Asymmetric Water-Soluble Porphyrin Derivatives, Caroline Owendi Ongayi
Synthesis Of Symmetric And Asymmetric Water-Soluble Porphyrin Derivatives, Caroline Owendi Ongayi
LSU Doctoral Dissertations
Novel symmetric and asymmetric water-soluble tetrabenzoporphyrin are synthesized in relatively good yields. These compounds are synthesized by the condensation of butanopyrrole with several aldehydes that contain masked water solubilizing groups followed by metal insertion, oxidation and demetallation and deprotection of the masked solubilizing groups. The biological evaluation (in vitro and in vivo) studies are described in addition to the photophysical evaluations of the corresponding compounds. A novel versatile route to the syntheses of novel free-bases and metallo-benzoylbiliverdin is discussed. The treatment of metal free-dodecasubstituted porphyrin with sodium nitrite and trifluoroacetic acid at room temperature in the presence of oxygen affords …
Effects Of Body Size On Goose Behavior: Lesser Snow Goose And Ross's Goose, Jon Einar Jonsson
Effects Of Body Size On Goose Behavior: Lesser Snow Goose And Ross's Goose, Jon Einar Jonsson
LSU Doctoral Dissertations
Body size is highly variable among geese, both at intra- and interspecific levels. Interspecific variation in several behaviors has been attributed to differences in body size in geese: incubation constancy, tendency to maintain family units, and time spent foraging. Body size has important physiological implications for birds, mostly because mass-specific metabolic rate is greater for birds of smaller mass. The Body-size Hypothesis predicts that smaller species deplete their energy reserves at relatively faster rates than do larger species. Hypotheses and conclusions concerning effects of body size on waterfowl behavior often are based on comparisons of species that confront different climates, …
Characterization Of Aged Polymer Modified Asphalt Cements For Recycling Purposes, Codrin Daranga
Characterization Of Aged Polymer Modified Asphalt Cements For Recycling Purposes, Codrin Daranga
LSU Doctoral Dissertations
Since polymer modified asphalt cement (PMAC) has been employed for a decade, the lifetime and wear on some of these pavements is reaching a stage where resurfacing is necessary. This research focuses on the characterization of aged polymer modified asphalt cements (PMAC) to evaluate their potential for recycling. A styrene-butadiene-styrene tri-block (SBS) polymer modified asphalt cement was selected and characterized using standard asphalt binder qualification techniques, i.e., the Superpave PG protocol. We developed a procedure to characterize the relative concentration of polymer in asphalt cements by gel permeation chromatography (GPC). Infrared spectrographic, thermogravimetric and rheological techniques were used to identify …
Medical Image Enhancement, Alina Monica Trifas
Medical Image Enhancement, Alina Monica Trifas
LSU Doctoral Dissertations
Each image acquired from a medical imaging system is often part of a two-dimensional (2-D) image set whose total presents a three-dimensional (3-D) object for diagnosis. Unfortunately, sometimes these images are of poor quality. These distortions cause an inadequate object-of-interest presentation, which can result in inaccurate image analysis. Blurring is considered a serious problem. Therefore, “deblurring” an image to obtain better quality is an important issue in medical image processing. In our research, the image is initially decomposed. Contrast improvement is achieved by modifying the coefficients obtained from the decomposed image. Small coefficient values represent subtle details and are amplified …
Enantioselective Syntheses And Chemical Investigations Of Plant-Derived Bioactive Volatile Compounds, Anne Marie Sauer
Enantioselective Syntheses And Chemical Investigations Of Plant-Derived Bioactive Volatile Compounds, Anne Marie Sauer
LSU Doctoral Dissertations
Research, inspired by nature, provides ample opportunity for discovery, ingenuity, and creative endeavor. For these reasons, the work and accomplishments presented herein focus on the total syntheses and related investigations of a variety of natural product derivatives, specifically (+)-nootkatone and jasmone. While the former consists of several independent projects: (a) an enantioselective synthetic route to (+)-nootkatone and derivatives, (b) examination of the valencane ring system, (c) determination of the absolute configuration of (+)-nootkatone, and (d) rearrangements of various sesquiterpenoid derivatives; the latter focuses on the construction ofƒndelta, epsilon-unsaturated carbonyl compounds, hetero Pauson-Khand substrates, via [3,3]-sigmatropic rearrangements.
Virtual Strings For Closed Curves With Multiple Components And Filamentations For Virtual Links, William Schellhorn
Virtual Strings For Closed Curves With Multiple Components And Filamentations For Virtual Links, William Schellhorn
LSU Doctoral Dissertations
The theory of filaments on oriented chord diagrams can be used to detect some non-classical virtual knots. We extend existing filament techniques to virtual links with more than one component and give examples of virtual links that these techniques can detect as non-classical. Given a signed Gauss word underlying an oriented chord diagram, we describe how to construct a finite sequence of integers that encodes all of the filament information for the diagram. We also introduce a square array of integers called a MIN-square that summarizes the filament information about all of the signed Gauss words having a given Gauss …
Infrared And X-Ray Spectroscopic Studies Of The Copper(Ii) Oxide Mediated Reactions Of Chlorinated Aromatic Precursors To Pcdd/F, Steven L. Alderman
Infrared And X-Ray Spectroscopic Studies Of The Copper(Ii) Oxide Mediated Reactions Of Chlorinated Aromatic Precursors To Pcdd/F, Steven L. Alderman
LSU Doctoral Dissertations
Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) are toxic compounds produced in combustion systems such as incinerators, and their emissions are an important environmental issue. Chlorinated phenols and benzenes form PCDD/F through heterogeneous reactions following adsorption onto fly-ash surfaces. Current research implicates transition metals in promoting formation of phenoxyl radicals that react to form PCDD/F, although this has not been studied extensively. This objective of this work is to better understand PCDD/F formation from chlorinated aromatic precursors. Using 2 chlorophenol as a model PCDD/F precursor and silica as a fly-ash surrogate, time-dependent chemisorption of 2 chlorophenol onto silica was studied in situ …
Detection Of Biologically Important Molecules, Kyukwang Kim
Detection Of Biologically Important Molecules, Kyukwang Kim
LSU Doctoral Dissertations
Anions play important roles in biological systems. The design of anion sensors has been of great interest. The selective detection of a specific anion is particularly challenging. In the first chapter, I describe the synthesis of a TBS-protected fluorescein dye (1.1) and its use for the selective detection of fluoride. Solutions of 1.1 either in DCM or in aqueous media at physiological pH show the excellent selectivity towards fluoride to afford color formation while solutions of other interfering anions remain colorless. The monitoring of homocysteine (Hcy) and cysteine (Cys) levels is important since they are biomarkers associated with Alzheimer’s and …
Denitrification And Greenhouse Gas Emissions From Cultivated And Wetland Alluvial Soils, Sami Ullah
Denitrification And Greenhouse Gas Emissions From Cultivated And Wetland Alluvial Soils, Sami Ullah
LSU Doctoral Dissertations
Agricultural development in the Mississippi River Basin has contributed to an 3-fold increase in NO3 loading of the river. Increased NO3 loading is a primary cause of eutrophication in the northern Gulf of Mexico. Identification of best management practices (BMPs) to reduce NO3 loss and wetlands restoration to remove NO3 through denitrification are critically needed. The objectives of this research were to determine factors controlling denitrification potential of different landscape units in an agricultural watershed and quantify the effects of BMPs and organic C amendments on denitrification rates of cultivated lands and restored forested wetlands. N2O, CH4 and CO2 emissions …
Macroinvertebrate Community Of Ecology Of Lowland, Subtropical Streams In Louisiana, Michael Douglas Kaller
Macroinvertebrate Community Of Ecology Of Lowland, Subtropical Streams In Louisiana, Michael Douglas Kaller
LSU Doctoral Dissertations
Freshwater ecosystems, particularly streams and rivers, have been the subject of prodigious research. Unfortunately, in comparison to neighboring regions, the Gulf of Mexico coastal plain has not received as much attention. Therefore, I collected data on the macroinvertebrates of these streams to begin the understanding of the relationships between community structure and environmental characteristics. In contrast to the hypothesized ancestral streams of these macroinvertebrates, coastal plain streams are commonly devoid of rocks leaving only woody debris as usable hard substrates and are typically lower in dissolved oxygen. I examined habitat selection by colonization of woody debris with large and small …