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Hans Conrad zur Loye

2011

Centrosymmetric Title Complex

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Tetraquabis(5-Fluorosaccharinato)Nickel(Ii), Larnelle Peterson, Jennifer Kelley, Leroy Peterson, Mark Smith, Hans Conrad Zur Loye Nov 2011

Tetraquabis(5-Fluorosaccharinato)Nickel(Ii), Larnelle Peterson, Jennifer Kelley, Leroy Peterson, Mark Smith, Hans Conrad Zur Loye

Hans Conrad zur Loye

In the centrosymmetric title complex, [Ni(C7H3FNO3S)2(H2O)4], the NiII atom exhibits a slightly distorted trans-NiN2O4 octahedral coordination. The nitrogen donors are provided by two 5-fluorosaccharinate ligands and the oxygen donors are provided by four water molecules. The crystal structure features O-HO and bifurcated O-H(F,O) hydrogen bonds, the latter involving the F atom of the 5-fluorosaccharinate ligand.