Physical Sciences and Mathematics | Open Access Articles

Ordering Tendencies In The Binary Alloys Of Rh, Pd, Ir, And Pt: Density Functional Calculations, Gus L. W. Hart, Brian Kolb, Stefan Müller, David B. Botts

Faculty Publications

The binary alloys of Rh, Pd, Ir, and Pt are important because of their high catalytic potential. We report in this paper that the Rh1-xIrx and Rh1-xPtx systems, long thought to phase separate at low temperatures, actually exhibit miscibility over the entire concentration and temperature range. We find low critical ordering temperatures, indicating that long-range order is unlikely to be observed experimentally. These results are compared with previous theoretical predications for the other binary alloys of Rh, Pd, Ir, and Pt and with calculations performed here on the Pt1-xIrx and Pd1-xIrx systems. We discuss these results and investigate the mechanisms …

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Fourier Spectroscopy Of Ultrashort Laser Pulses, Scott D. Bergeson, Justin Peatross

Faculty Publications

We describe a Fourier-transform spectrometer appropriate for use in an undergraduate optics laboratory. The modular design, which uses off-the-shelf equipment, is suitable for determining the spectra of ultrashort pulsed and continuous light sources. The spectrometer does not require equal step sizes for the motion of the mirror. An algorithm interpolates the phase of both a reference and an unknown light beam at equal intervals before performing the Fourier transform. The interferometer scan and the phase and spectral analysis are performed in a few seconds, making the apparatus a useful tool for teaching concepts of temporal coherence and Fourier spectroscopy.

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Mesoscopic Domain Average Engineering Simulations Of Ferroelectric Perovskites Compared With Multidomain Group Theoretical Predictions, Brandon J. Keith, Dorian M. Hatch

Faculty Publications

Engineered, multidomain ferroelectrics are of current interest for mechatronic and optical applications. Previously [D. M. Hatch et al., J. Appl. Phys. 94, 5220 (2003)], we presented a set of tables/symmetry rules showing all possible domain average engineered multidomain structures arising from [100]-, [110]-, and [111]-ordering ferroelectric transitions from a Pm[overline 3]m perovskite structure. In this work we test those predictions against three-dimensional mesoscopic fast quench simulations under various electric/stress field combinations and find excellent agreement with multidomain group theory. These simulations use a Langevin strain-displacement/polarization evolution strategy and are important to developing processing conditions for materials with precise domain structures.

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Understanding Dc-Bias Sputtered Thorium Oxide Thin Films Useful In Euv Optics, William R. Evans, Sarah C. Barton, Michael Clemens, David D. Allred

Faculty Publications

We use spectroscopic ellipsometry to determine the optical constants of seven thin-film ThO2 samples deposited by radio-frequency sputtering, thickness ranging between 24 and 578 nm, for the spectral range of 1.2 to 6.5. We used a hollow-cathode light source and vacuum monochromator to measure constants at 10.2 eV. None of the deposition parameters studied including DC-bias voltages successfully increased the n of (that is, densify) thoria films. The value of n at 3.0 eV is 1.86 ± 0.04. We find compelling evidence to conclude that the direct bad gap is at ~5.9 eV, clarifying the results of others, some of …

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Compositional Stability Of Fept Nanoparticles On Sio2/Si During Annealing, Richard R. Vanfleet, B. Yao, R. V. Petrova, K. R. Coffey

Faculty Publications

The loss of Fe due to oxidation or diffusion into the substrate can prevent the successful preparation of well-ordered, stoichiometric, FePt nanoparticles. In this work we report the composition changes during annealing observed for small (<10 nm) FePt nanoparticles on thermally grown SiO2 layers on Si wafer substrates. Additionally, we describe the use of a controlled reducing gas mixture, Ar+H2+H2O, to reduce the loss of Fe.

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Compact Solid-State Laser Source For 1s-2s Spectroscopy In Atomic Hydrogen, Scott D. Bergeson, N. Kolachevsky, J. Alnis, T. W. Hansch

Faculty Publications

We demonstrate a compact solid-state laser source for high-resolution two-photon spectroscopy of the 1S-2S transition in atomic hydrogen. The source emits up to 20 mW at 243 nm and consists of a 972 nm diode laser, a tapered amplifier, and two doubling stages. The diode laser is actively stabilized to a high-finesse cavity. We compare the new source to the stable 486 nm dye laser used in previous experiments and record 1S-2S spectra using both systems. With the solid-state laser system, we demonstrate a resolution of the hydrogen spectrometer of 6×10^11, which is promising for a number of high-precision measurements …

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Finding The Radial Parallel Temperature Profile In A Non-Neutral Plasma Using Equilibrium Calculations On Experimental Data, Grant W. Hart, Bryan G. Peterson

Faculty Publications

In 1992, Eggleston et al. [D. L. Eggleston et al., Phys. Fluids B 4, 3432 (1992)] reported on a technique for measuring the radial temperature profile in a pure-electron plasma confined in a Malmberg-Penning trap by partially dumping the plasma onto a charge collector at the end of the trap. For short plasmas and short confining rings, the assumptions in their paper are violated and a more general calculation is needed. This paper presents a variation of the standard equilibrium calculation to find the temperature profile of a pure-electron plasma. Eggleston's shortcut "evaporation" temperature method is found to require a …

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Hydrodynamic Description Of The Adiabatic Piston, Alejandro Garcia, M. M. Mansour

Faculty Publications

A closed macroscopic equation for the motion of the two-dimensional adiabatic piston is derived from standard hydrodynamics. It predicts a damped oscillatory motion of the piston towards a final rest position, which depends on the initial state. In the limit of large piston mass, the solution of this equation is in quantitative agreement with the results obtained from both hard disk molecular dynamics and hydrodynamics. The explicit forms of the basic characteristics of the piston’s dynamics, such as the period of oscillations and the relaxation time, are derived. The limitations of the theory’s validity, in terms of the main system …

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Estimating Hydrodynamic Quantities In The Presence Of Microscopic Fluctuations, Alejandro Garcia

Faculty Publications

This paper discusses the evaluation of hydrodynamic variables in the presence of spontaneous fluctuations, such as in molecular simulations of fluid flows. The principal point is that hydrodynamic variables such as fluid velocity and temperature must be defined in terms of mechanical variables such as momentum and energy density). Because these relations are nonlinear and because fluctuations of mechanical variables are correlated, care must be taken to avoid introducing a bias when evaluating means, variances, and correlations of hydrodynamic variables. The unbiased estimates are formulated; some alternative, incorrect approaches are presented as cautionary warnings. The expressions are verified by numerical …

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A Deep Kinematic Survey Of Planetary Nebulae In The Andromeda Galaxy Using The Planetary Nebula Spectrograph, H. R. Merrett, M. R. Merrifield, N. G. Douglas, K. Kuijken, Aaron J. Romanowsky, N. R. Napolitano, M. Arnaboldi, M. Capaccioli, K. C. Freeman, O. Gerhard, L. Coccato, D. Carter, N. W. Evans, M. I. Wilkinson, C. Halliday, T. J. Bridges

Faculty Publications

We present a catalogue of positions, magnitudes and velocities for 3300 emission-line objects found by the Planetary Nebula Spectrograph in a survey of the Andromeda galaxy, M31. Of these objects, 2615 are found likely to be planetary nebulae (PNe) associated with M31. The survey area covers the whole of M31's disc out to a radius of Graphic. Beyond this radius, observations have been made along the major and minor axes, and the Northern Spur and Southern Stream regions. The calibrated data have been checked for internal consistency and compared with other catalogues. With the exception of the very central, high …

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Planetary Nebula Velocities In The Disc And Bulge Of M31, C. Halliday, D. Carter, T. J. Bridges, Z. C. Jackson, M. I. Wilkinson, D. P. Quinn, N. W. Evans, N. G. Douglas, H. R. Merrett, Aaron J. Romanowsky, K. Kuijken, M. J. Irwin

Faculty Publications

We present radial velocities for a sample of 723 planetary nebulae in the disc and bulge of M31, measured using the WYFFOS fibre spectrograph on the William Herschel Telescope. Velocities are determined using the [O III] λ5007 emission line. Rotation and velocity dispersion are measured to a radius of 50 arcmin (11.5 kpc), the first stellar rotation curve and velocity dispersion profile for M31 to such a radius. Our kinematics are consistent with rotational support at radii well beyond the bulge effective radius of 1.4 kpc, although our data beyond a radius of 5 kpc are limited. We present tentative …

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Wide-Field Kinematics Of Globular Clusters In The Leo I Group, G. Bergond, S. E. Zepf, Aaron J. Romanowsky, R. M. Sharples, K. L. Rhode

Faculty Publications

We present wide-field spectroscopy of globular clusters around the Leo I group galaxies NGC 3379 and NGC 3384 using the FLAMES multi-fibre instrument at the VLT. We obtain accurate radial velocities for 42 globular clusters (GCs) in total, 30 for GCs around the elliptical NGC 3379, eight around the lenticular NGC 3384, and four which may be associated with either galaxy. These data are notable for their large radial range extending from 0$\farcm$7 to 14$\farcm$5 (2 to 42 kpc) from the centre of NGC 3379, and small velocity uncertainties of about 10 km s-1. We combine our sample of 30 …

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The Araucaria Project. An Accurate Distance To Ngc 6822 From Near-Infrared Photometry Of Cepheid Variables, W. Gieren, G. Pietrzyński, K. Nalewajko, I. Soszyński, F. Bresolin, R.-P. Kudritzki, D. Minniti, Aaron J. Romanowsky

Faculty Publications

We have measured near-infrared magnitudes in the J and K bands for 56 Cepheid variables in the Local Group galaxy NGC 6822 with well-determined periods and optical light curves in the V and I bands. Using the template light-curve approach of Soszyński and coworkers, accurate mean magnitudes were obtained from these data, which allowed us to determine with unprecedented accuracy the distance to NGC 6822 from a multiwavelength period-luminosity solution in the VIJK bands. From our data, we obtain a distance to NGC 6822 of (m - M)0 = 23.312 ± 0.021 (random error) mag, with an additional systematic uncertainty …

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Full-Text Articles in Physical Sciences and Mathematics

Ordering Tendencies In The Binary Alloys Of Rh, Pd, Ir, And Pt: Density Functional Calculations, Gus L. W. Hart, Brian Kolb, Stefan Müller, David B. Botts

Faculty Publications

Fourier Spectroscopy Of Ultrashort Laser Pulses, Scott D. Bergeson, Justin Peatross

Faculty Publications

Mesoscopic Domain Average Engineering Simulations Of Ferroelectric Perovskites Compared With Multidomain Group Theoretical Predictions, Brandon J. Keith, Dorian M. Hatch

Faculty Publications

Understanding Dc-Bias Sputtered Thorium Oxide Thin Films Useful In Euv Optics, William R. Evans, Sarah C. Barton, Michael Clemens, David D. Allred

Faculty Publications

Compositional Stability Of Fept Nanoparticles On Sio2/Si During Annealing, Richard R. Vanfleet, B. Yao, R. V. Petrova, K. R. Coffey

Faculty Publications

Compact Solid-State Laser Source For 1s-2s Spectroscopy In Atomic Hydrogen, Scott D. Bergeson, N. Kolachevsky, J. Alnis, T. W. Hansch

Faculty Publications

Finding The Radial Parallel Temperature Profile In A Non-Neutral Plasma Using Equilibrium Calculations On Experimental Data, Grant W. Hart, Bryan G. Peterson

Faculty Publications

Hydrodynamic Description Of The Adiabatic Piston, Alejandro Garcia, M. M. Mansour

Faculty Publications

Estimating Hydrodynamic Quantities In The Presence Of Microscopic Fluctuations, Alejandro Garcia

Faculty Publications

Faculty Publications

Planetary Nebula Velocities In The Disc And Bulge Of M31, C. Halliday, D. Carter, T. J. Bridges, Z. C. Jackson, M. I. Wilkinson, D. P. Quinn, N. W. Evans, N. G. Douglas, H. R. Merrett, Aaron J. Romanowsky, K. Kuijken, M. J. Irwin

Faculty Publications

Wide-Field Kinematics Of Globular Clusters In The Leo I Group, G. Bergond, S. E. Zepf, Aaron J. Romanowsky, R. M. Sharples, K. L. Rhode

Faculty Publications

The Araucaria Project. An Accurate Distance To Ngc 6822 From Near-Infrared Photometry Of Cepheid Variables, W. Gieren, G. Pietrzyński, K. Nalewajko, I. Soszyński, F. Bresolin, R.-P. Kudritzki, D. Minniti, Aaron J. Romanowsky

Faculty Publications