Physical Sciences and Mathematics Commons^™

Lithium Tetraborate As A Neutron Scintillation Detector: A Review, Elena Echeverria, John W. Mcclory, Lauren Samson, Katherine Shene, Juan A. Colon Santana, Yaroslav V. Burak, Volodymyr T. Adamiv, Ihor M. Teslyuk, Lu Wang, Wai-Ning Mei, Kyle A. Nelson, Douglas S. Mcgregor, Peter A. Dowben, Carolina C. Ilie, James C. Petrosky, Archit Dhingra

Faculty Publications

The electronic structure and translucent nature of lithium tetraborate (Li₂B₄O₇) render it promising as a scintillator medium for neutron detection applications. The inherently large neutron capture cross-section due to ¹⁰B and ⁶Li isotopes and the ease with which Li₂B₄O₇ can be enriched with these isotopes, combined with the facile inclusion of rare earth dopants (occupying the Li⁺ sites), are expected to improve the luminescent properties, as well as the neutron detection efficiency, of Li₂B₄O₇. The electronic structure of both doped …

Development Of A Methodology For The Quantification Of Reaerosolization Of A Biological Contaminate Surrogate Particle From A Military Uniform Fabric, George Cooksey, Jeremy M. Slagley, Casey W. Cooper, Douglas Lewis, Alisha Helm

Faculty Publications

In a mass casualty medical evacuation after a bioaerosol (BA) dispersal event, a decontamination (DC) method is needed that can both decontaminate and prevent biological particle (BP) re-aerosolization (RA) of contaminated clothes. However, neither the efficacy of current DC methods nor the risk of BP RA is greatly explored in the existing literature. The goals of this study were to develop a repeatable method to quantify the RA of a biological contaminant off military uniform fabric swatches and to test the efficacy of one DC protocol (high-volume, low-pressure water) using 1 µm polystyrene latex (PSL) spheres as a surrogate. A …

Directional Microwave Emission From Femtosecond-Laser Illuminated Linear Arrays Of Superconducting Rings, Thomas J. Bullard, Kyle Frische, Charlie Ebbing, Stephen J. Hageman, John Morrison, John Bulmer, Enam A. Chowdury, Michael L. Dexter, Timothy J. Haugan, Anil K. Patniak

Faculty Publications

We examine the electromagnetic emission from two photo-illuminated linear arrays composed of inductively charged superconducting ring elements. The arrays are illuminated by an ultrafast infrared laser that triggers microwave broadband emission detected in the 1–26 GHz range. Based on constructive interference from the arrays a narrowing of the forward radiation lobe is observed with increasing element count and frequency demonstrating directed GHz emission. Results suggest that higher frequencies and a larger number of elements are achievable leading to a unique pulsed array emitter concept that can span frequencies from the microwave to the terahertz (THz) regime.

Analysis And Requirement Generation For Defense Intelligence Search: Addressing Data Overload Through Human–Ai Agent System Design For Ambient Awareness, Mark C. Duncan, Michael E. Miller, Brett J. Borghetti

Faculty Publications

This research addresses the data overload faced by intelligence searchers in government and defense agencies. The study leverages methods from the Cognitive Systems Engineering (CSE) literature to generate insights into the intelligence search work domain. These insights are applied to a supporting concept and requirements for designing and evaluating a human-AI agent team specifically for intelligence search tasks. Domain analysis reveals the dynamic nature of the ‘value structure’, a term that describes the evolving set of criteria governing the intelligence search process. Additionally, domain insight provides details for search aggregation and conceptual spaces from which the value structure could be …

Search For Evidence Of Baryogenesis And Dark Matter In B+→Ψd+P Decays At Babar, J. P. Lees, V. Poireau, E. Grauges, A. Palano, G. Eigen, D. N. Brown, Yu. G. Kolomensky, M. Fritsch, H. Koch, R. Cheaib, C. Hearty, T. S. Mattison, J. A. Mckenna, R. Y. So, V. E. Blinov, A. R. Buzykaev, V. P. Druzhinin, E. A. Kravchenko, Milind Purohit, Et. Al.

Faculty Publications

A new dark sector antibaryon, denoted ψD, could be produced in decays of B mesons. This Letter presents a search for B⁺→ψ_D+p (and the charge conjugate) decays in e⁺e⁻ annihilations at 10.58 GeV, using data collected in the BABAR experiment. Data corresponding to an integrated luminosity of 398 fb⁻¹ are analyzed. No evidence for a signal is observed. Branching fraction upper limits in the range from 10⁻⁷–10⁻⁵ are obtained at 90% confidence level for masses of 1.0<mψ_D< 4.3 GeV/c². The result is also reinterpreted to provide …

Detailed Characterization Of A Khz-Rate Laser-Driven Fusion At A Thin Liquid Sheet With A Neutron Detection Suite, Benjamin M. Knight, Connor Gautam, Colton R. Stoner, Bryan V. Egner, Joseph R. Smith, Christopher M. Orban, Juan J. Manfredi, Kyle Frische, Michael L. Dexter, Enam A. Chowdury, Anil K. Patniak

Faculty Publications

We present detailed characterization of laser driven fusion and neutron production (∼10⁵/second) employing 8 mJ, 40fs laser pulses on a thin (< 1 µm) D₂O liquid sheet employing a measurement suite. At relativistic intensity (∼5×10¹⁸W/cm²) and high repetition-rate (1 kHz), the system produces consistent D-D fusion, allowing for consistent neutron generation. Evidence of D-D fusion neutron production is verified b y a measurement suite with three independent detection systems: an EJ-309 organic scintillator with pulse-shape discrimination, a ³He proportional counter, and a set of 36 bubble detectors. Time-of-flight analysis of the scintillator data shows …

Measurement Of Additional Radiation In The Initial-State-Radiation Processes E+E- →Μ+Μ- Y And E+E- → ℼ+ℼ- Y At Babar, J. P. Lees, V. Poireau, V. Tisserand, E. Grauges, A. Palano, G. Eigen, D. N. Brown, Yu. G. Kolomensky, M. Fritsch, H. Koch, R. Cheaib, C. Hearty, T. S. Mattison, J. A. Mckenna, R. Y. So, V. E. Blinov, A. R. Buzykaev, V. P. Druzhinin, E. A. Kozyrev, Milind Purohit, Et. Al.

Faculty Publications

A dedicated measurement of additional radiation in e⁺e⁻ → µ⁺µ⁻γ and e⁺e⁻ → π⁺π⁻γ initial-state-radiation events is presented using the full BABAR data sample. For the first time results are presented at next-to- and next-to-next-to-leading order, with one and two additional photons, respectively, for radiation from the initial and final states. Comparison with predictions from PHOKHARA and AFKQED Monte Carlo generators is performed, revealing discrepancies in the one-photon rates and angular distributions for the former. This disagreement has a negligible effect on the BABAR measurement of …

A Computational Approach For Mapping Electrochemical Activity Of Multi-Principal Element Alloys, Jodie A. Yuwono, Xinyu Li, Tyler D. Dolezal, Adib J. Samin, Javen Qinfeng Shi, Zhipeng Li, Nick Birbilis

Faculty Publications

Multi principal element alloys (MPEAs) comprise an atypical class of metal alloys. MPEAs have been demonstrated to possess several exceptional properties, including, as most relevant to the present study a high corrosion resistance. In the context of MPEA design, the vast number of potential alloying elements and the staggering number of elemental combinations favours a computational alloy design approach. In order to computationally assess the prospective corrosion performance of MPEA, an approach was developed in this study. A density functional theory (DFT) – based Monte Carlo method was used for the development of MPEA ‘structure’; with the AlCrTiV alloy used …

Legendre Pairs Of Lengths ℓ ≡ 0 (Mod 5), Ilias S. Kotsireas, Christopher Koutschan, Dursun Bulutoglu, David M. Arquette, Jonathan S. Turner, Kenneth J. Ryan

Faculty Publications

By assuming a type of balance for length ℓ = 87 and nontrivial subgroups of multiplier groups of Legendre pairs (LPs) for length ℓ = 85 , we find LPs of these lengths. We then study the power spectral density (PSD) values of m compressions of LPs of length 5 m . We also formulate a conjecture for LPs of lengths ℓ ≡ 0 (mod 5) and demonstrate how it can be used to decrease the search space and storage requirements for finding such LPs. The newly found LPs decrease the number of integers in the range ≤ 200 for …

System-Level Noise Performance Of Coherent Imaging Systems, Derek J. Burrell, Joshua H. Follansbee, Mark F. Spencer, Ronald G. Driggers

Faculty Publications

We provide an in-depth analysis of noise considerations in coherent imaging, accounting for speckle and scintillation in addition to “conventional” image noise. Specifically, we formulate closed-form expressions for total effective noise in the presence of speckle only, scintillation only, and speckle combined with scintillation. We find analytically that photon shot noise is uncorrelated with both speckle and weak-to-moderate scintillation, despite their shared dependence on the mean signal. Furthermore, unmitigated speckle and scintillation noise tends to dominate coherent-imaging performance due to a squared mean-signal dependence. Strong coupling occurs between speckle and scintillation when both are present, and we characterize this behavior …

Impact Of Silicon Ion Irradiation On Aluminum Nitride-Transduced Microelectromechanical Resonators, David D. Lynes, Joshua Young, Eric Lang, Hengky Chandrahalim

Faculty Publications

Microelectromechanical systems (MEMS) resonators use is widespread, from electronic filters and oscillators to physical sensors such as accelerometers and gyroscopes. These devices' ubiquity, small size, and low power consumption make them ideal for use in systems such as CubeSats, micro aerial vehicles, autonomous underwater vehicles, and micro-robots operating in radiation environments. Radiation's interaction with materials manifests as atomic displacement and ionization, resulting in mechanical and electronic property changes, photocurrents, and charge buildup. This study examines silicon (Si) ion irradiation's interaction with piezoelectrically transduced MEMS resonators. Furthermore, the effect of adding a dielectric silicon oxide (SiO₂) thin film is …

Active-Illumination Extension To The Priest And Meier Pbrdf, Mark F. Spencer, Milo W. Hyde Iv, Santasri R. Bose-Pillai, Michael A. Marciniak

Faculty Publications

This paper develops a 3D vector solution for the scattering of partially coherent laser-beam illumination from statistically rough surfaces. Such a solution enables a rigorous comparison to the well-known Priest and Meier polarimetric bidirectional reflectance distribution function (pBRDF) [Opt Eng 41(5),988 (2002).]. Overall, the comparison shows excellent agreement for the normalized spectral density and the degree of polarization. Based on this agreement, the 3D vector solution also enables an extension to the Priest and Meier pBRDF that accounts for the effects of active illumination. In particular, the 3D vector solution enables the development of a closed-form expression for the spectral …

Reply To: Beyond Microbial Carbon Use Efficiency, Feng Tao, Johannes Lehmann, Ying-Ping Wang, Lifen Jiang, Bernhard Ahrens, Kostiantyn Viatkin, Stefano Manzoni, Benjamin Z. Houlton, Yuanyuan Huang, Bruce A. Hungate, Serita D. Frey, Michael W. I. Schmidt, Markus Reichstein, Nuno Carvalhais, Philippe Ciais, Umakant Mishra, Gustaf Hugelius, Toby D. Hocking, Xingjie Lu, Zheng Shi, Ronald Vargas, Yusuf Yigini, Christian Omuto, Ashish A. Malik, Guillermo Peralta, Rosa Cuevas-Corona, Luciano E. Di Paolo, Isabel Luotto, Cuijuan Liao, Yi-Shuang Liang, Vinisa S. Saynes, Xiaomeng Huang

Faculty Publications

In their commentary, Xiao et al. cautioned that the conclusions on the critical role of microbial carbon use efficiency (CUE) in global soil organic carbon (SOC) storage in a paper by Tao et al. (2023) might be too simplistic. They claimed that Tao et al.’s study lacked mechanistic consideration of SOC formation and excluded important datasets. Xiao et al. brought up important points, which can be largely reconciled with our findings by understanding the differences in expressing processes in empirical studies and in models.

Lightning Forecast From Chaotic And Incomplete Time Series Using Wavelet De-Noising And Spatiotemporal Kriging, Jared K. Nystrom, Raymond Hill, Andrew J. Geyer, Joseph J. Pignatiello Jr., Eric Chicken

Faculty Publications

Purpose: Present a method to impute missing data from a chaotic time series, in this case lightning prediction data, and then use that completed dataset to create lightning prediction forecasts.

Design/Methodology/Approach: Using the technique of spatiotemporal kriging to estimate data that is autocorrelated but in space and time. Using the estimated data in an imputation methodology completes a dataset used in lighting prediction.

Findings: The techniques provided prove robust to the chaotic nature of the data, and the resulting time series displays evidence of smoothing while also preserving the signal of interest for lightning prediction.

Abstract © Emerald Publishing …

Precision E- Beam Polarimetry At An E-E+ B Factory Using Tau-Pair Events, J. P. Lees, V. Poireau, V, Tisserand, E. Grauges, A. Palano, G. Eigen, D. N. Brown, Yu. G. Kolomensky, M. Fritsch, H. Koch, R. Cheaib, C. Hearty, T. S. Mattison, J. A. Mckenna, R. Y. So, V. E. Blinov, A. R. Buzykaev, V. P. Druzhinin, Milind Purohit, Et. Al.

Faculty Publications

We present a new technique, “tau polarimetry,” for measuring the longitudinal beam polarization present in an e⁺e⁻ collider through the analysis of e⁺e⁻ → τ⁺τ⁻ events. By exploiting the sensitivity of τ decay kinematics to the longitudinal polarization of the beams, we demonstrate that the longitudinal polarization can be measured with a 3 per mil systematic uncertainty at the interaction point using a technique that is independent of spin and beam transport modeling. Using 424.2 ± 1.8 fb⁻¹ of BABAR data at √ s = 10.58 GeV, the average longitudinal …

What Is Microbial Dormancy, Mark D. Mcdonald, Carlos Owusu-Ansah, Jared B. Ellenbogen, Zachary D. Malone, Michael P. Ricketts, Steve E. Frolking, Jessica G. Ernakovich, Michael Ibba, Sarah C. Bagby, J. L. Weissman

Faculty Publications

Life can be stressful. One way to deal with stress is to simply wait it out. Microbes do this by entering a state of reduced activity and increased resistance commonly called ‘dormancy’. But what is dormancy? Different scientific disciplines emphasize distinct traits and phenotypic ranges in defining dormancy for their microbial species and system-specific questions of interest. Here, we propose a unified definition of microbial dormancy, using a broad framework to place earlier discipline-specific definitions in a new context. We then discuss how this new definition and framework may improve our ability to investigate dormancy using multi-omics tools. Finally, we …

Ironnetinjector: Weaponizing .Net Dynamic Language Runtime Engines, Anthony J. Rose, Scott R. Graham, Jacob Krasnov

Faculty Publications

As adversaries evolve their Tactics, Techniques, and Procedures (TTPs) to stay ahead of defenders, Microsoft’s .NET Framework emerges as a common component found in the tradecraft of many contemporary Advanced Persistent Threats (APTs), whether through PowerShell or C#. Because of .NET’s ease of use and availability on every recent Windows system, it is at the forefront of modern TTPs and is a primary means of exploitation. This article considers the .NET Dynamic Language Runtime as an attack vector, and how APTs have utilized it for offensive purposes. The technique under scrutiny is Bring Your Own Interpreter (BYOI), which is the …

Speciation Of Elements Via A Sequential Extraction Procedure In Municipal Wastewater Biosolids From Three Rural Wwtp In East Texas (Usa), Kefa K. Onchoke

Faculty Publications

In this data article, the bioavailability of elements in municipal wastewater sludge (also known as biosolids) in samples collected from three treatment plants in East Texas, USA was evaluated. Although detailed speciation of the metals were assessed by using inductively coupled plasma optical spectroscopy (ICP-OES), and were discussed in the research article titled “Evaluating bioavailability of elements in municipal wastewater sludge (Biosolids) from three rural wastewater treatment plants in East Texas (USA) by a sequential extraction procedure” [1], this report presents the absolute raw concentrations and fractionations of the 26 metals from the biosolids (Nacogdoches Wastewater Sludge, Lufkin Wastewater Sludge, …

Reply To: Contribution Of Carbon Inputs To Soil Carbon Accumulation Cannot Be Neglected, Feng Tao, Benjamin Z. Houlton, Serita D. Frey, Johannes Lehmann, Stefano Manzoni, Yuanyuan Huang, Lifen Jiang, Umakant Mishra, Bruce A. Hungate, Michael W. I. Schmidt, Markus Reichstein, Nuno Carvalhais, Philippe Ciais, Ying-Ping Wang, Bernhard Ahrens, Gustaf Hugelius, Toby D. Hocking, Xingjie Lu, Zheng Shi, Kostiantyn Viatkin, Ronald Vargas, Yusuf Yigini, Christian Omuto, Ashish A. Malik, Guillermo Peralta, Rosa Cuevas-Corona, Luciano E. Di Paolo, Isabel Luotto, Cuijuan Liao, Yi-Shuang Liang, Vinisa S. Saynes, Xiaomeng Huang, Yiqi Luo

Faculty Publications

In the accompanying Comment1, He et al. argue that the determinant role of microbial carbon use efficiency in global soil organic carbon (SOC) storage shown in Tao et al. (2023)2 was overestimated because carbon inputs were neglected in our data analysis while they suggest that our model-based analysis could be biased and model-dependent. Their argument is based on a different choice of independent variables in the data analysis and a sensitivity analysis of two process-based models other than that used in our study. We agree that both carbon inputs and outputs (as mediated by microbial processes) matter when predicting SOC …

Season, Not Long-Term Warming, Affects The Relationship Between Ecosystem Function And Microbial Diversity, Melissa S. Shinfuku, Luiz A. Domeignoz-Horta, Mallory J. Choudoir, Serita D. Frey, Kristen M. Deangelis

Faculty Publications

Across biomes, soil biodiversity promotes ecosystem functions. However, whether this relationship will be maintained under climate change is uncertain. Here, using two long-term warming experiments, we investigated how warming affects the relationship between ecosystem functions and microbial diversity across seasons, soil horizons, and warming duration. The soils in these warming experiments were heated +5 °C above ambient for 13 or 28 years. We measured seven different ecosystem functions representative of soil carbon cycling, soil nitrogen cycling, or nutrient pools. We also surveyed bacterial and fungal community diversity. We found that the relationship between ecosystem function and bacterial diversity and the …

Anomaly Detection In The Molecular Structure Of Gallium Arsenide Using Convolutional Neural Networks, Timothy Roche *, Aihua W. Wood, Philip Cho *, Chancellor Johnstone

Faculty Publications

This paper concerns the development of a machine learning tool to detect anomalies in the molecular structure of Gallium Arsenide. We employ a combination of a CNN and a PCA reconstruction to create the model, using real images taken with an electron microscope in training and testing. The methodology developed allows for the creation of a defect detection model, without any labeled images of defects being required for training. The model performed well on all tests under the established assumptions, allowing for reliable anomaly detection. To the best of our knowledge, such methods are not currently available in the open …

Spectral Broadening Effects On Pulsed-Source Digital Holography, Steven A. Owens, Mark F. Spencer, Glen P. Perram

Faculty Publications

Using a pulsed configuration, a digital-holographic system is setup in the off-axis image plane recording geometry, and spectral broadening via pseudo-random bit sequence is used to degrade the temporal coherence of the master-oscillator laser. The associated effects on the signal-to-noise ratio are then measured in terms of the ambiguity and coherence efficiencies. It is found that the ambiguity efficiency, which is a function of signal-reference pulse overlap, is not affected by the effects of spectral broadening. The coherence efficiency, on the other hand, is affected. As a result, the coherence efficiency, which is a function of effective fringe visibility, is …

Propagation Of Spatiotemporal Optical Vortex Beams In Linear, Second-Order Dispersive Media, Milo W. Hyde Iv, Miguel A. Porras

Faculty Publications

In this paper, we study the behaviors of spatiotemporal optical vortex (STOV) beams propagating in linear dispersive media. Starting with the Fresnel diffraction integral, we derive a closed-form expression for the STOV field at any propagation distance z in a general second-order dispersive medium. We compare our general result to special cases published in the literature and examine the characteristics of higher-order STOV beams propagating in dispersive materials by varying parameters of the medium and source-plane STOV field. We validate our analysis by comparing theoretical predictions to numerical computations of a higher-order STOV beam propagating through fused silica, where we …

The Emergence Of Convergence, Shana M. Sundstrom, David G. Angeler, Jessica G. Ernakovich, Jorge H. Garcia, Joseph A. Hamm, Orville Huntington, Craig R. Allen

Faculty Publications

Science is increasingly a collaborative pursuit. Although the modern scientific enterprise owes much to individuals working at the core of their field, humanity is increasingly confronted by highly complex problems that require the integration of a variety of disciplinary and methodological expertise. In 2016, the U.S. National Science Foundation launched an initiative prioritizing support for convergence research as a means of “solving vexing research problems, in particular, complex problems focusing on societal needs.” We discuss our understanding of the objectives of convergence research and describe in detail the conditions and processes likely to generate successful convergence research. We use our …

Wave Optics Approach To Solar Cell Brdf Modeling With Experimental Results, Madilynn Compean, Todd V. Small, Milo W. Hyde Iv, Michael Marciniak

Faculty Publications

Light curve analysis is often used to discern information about satellites in geosynchronous orbits. Solar panels, comprising a large part of the satellite’s body, contribute significantly to these light curves. Historically, theoretical bidirectional reflectance distribution functions (BRDFs) have failed to capture key features in the scattered light from solar panels. In recently published work, a new solar cell BRDF was developed by combining specular microfacet and “two-slit” diffraction terms to capture specular and periodic/array scattering, respectively. This BRDF was experimentally motivated and predicted many features of the solar cell scattered irradiance. However, the experiments that informed the BRDF were limited …

Hyperspectral Point Cloud Projection For The Semantic Segmentation Of Multimodal Hyperspectral And Lidar Data With Point Convolution-Based Deep Fusion Neural Networks, Kevin T. Decker, Brett J. Borghetti

Faculty Publications

The fusion of dissimilar data modalities in neural networks presents a significant challenge, particularly in the case of multimodal hyperspectral and lidar data. Hyperspectral data, typically represented as images with potentially hundreds of bands, provide a wealth of spectral information, while lidar data, commonly represented as point clouds with millions of unordered points in 3D space, offer structural information. The complementary nature of these data types presents a unique challenge due to their fundamentally different representations requiring distinct processing methods. In this work, we introduce an alternative hyperspectral data representation in the form of a hyperspectral point cloud (HSPC), which …

The Characteristics Of Successful Military It Projects: A Cross-Country Empirical Study, Helene Berg, Jonathan D. Ritschel

Faculty Publications

No abstract provided.

Short-Term Responses Of Soil Carbon, Nitrogen, And Microbial Biomass To Cover Crop Mixtures And Monocultures, Igor Alexandre De Souza, Amanda B. Daly, Jorg Schnecker, Nicholas D. Warren, Adalfredo Rocha Lobo Jr., Richard G. Smith, Andre Fonseca Brito, A. Stuart Grandy

Faculty Publications

Increasingly, cover crops are being adopted for the purpose of improving soil health, yet the timescale and magnitude by which living annual cover crops might modify soil chemical and biological aspects of soil health is not well understood. At the same time, there is growing interest among farmers in cover crop mixtures due to perceptions that species-rich cover crop communities will enhance soil health relative to monocultures. In a field experiment in southeast New Hampshire, we investigated how groups of cover crops grown as monocultures and mixtures for specific seasonal niches (winter/spring, summer, and fall) influenced levels of soil nitrogen …

Accurate Covariance Estimation For Pose Data From Iterative Closest Point Algorithm, Rick H. Yuan, Clark N. Taylor, Scott L. Nykl

Faculty Publications

One of the fundamental problems of robotics and navigation is the estimation of the relative pose of an external object with respect to the observer. A common method for computing the relative pose is the iterative closest point (ICP) algorithm, where a reference point cloud of a known object is registered against a sensed point cloud to determine relative pose. To use this computed pose information in downstream processing algorithms, it is necessary to estimate the uncertainty of the ICP output, typically represented as a covariance matrix. In this paper, a novel method for estimating uncertainty from sensed data is …

Scalable Preparation Of The Masked Acyl Cyanide Tbs-Mac, Haley Hinton, Jack Patterson, Jared Hume, Krunal Patel, Julie Pigza

Faculty Publications

This paper describes the three-step synthesis of TBS-MAC, a masked acyl cyanide (MAC) and a versatile one-carbon oxidation state three synthon. We have developed a scalable and detailed synthesis that involves: (1) acetylation of malononitrile to form the sodium enolate, (2) protonation of the enolate to form acetylmalononitrile, and (3) epoxidation of the enol, rearrangement to an unstable alcohol, and TBS-protection to form the title compound. Both the sodium enolate and acetylmalononitrile are bench-stable precursors to the intermediate hydroxymalononitrile, which can be converted to other MAC reagents beyond TBS by varying the protecting group (Ac, MOM, EE, etc.).