Physical Sciences and Mathematics Commons^™

Stable Isotope Analysis Of Japan Sea And East China Sea Sediments: Late Pleistocene Paleoceanographic Reconstructions, Heather Dawn Black

FIU Electronic Theses and Dissertations

The East Asian Monsoon system is an important dynamic of East Asian climates, affecting over one-third of the world’s population. Marginal seas within East Asia are ideal environments to study past fluctuations of monsoon intensities and durations as they are sensitive to climatic and glacio-eustatic sea level changes. This study focuses on continuous sedimentary sequences collected from three Integrated Oceanic Drilling Program Expedition 346 sites; Sites U1426 and U1427 in the Japan Sea and Site U1429 in the East China Sea. Elemental concentration (%TOC, %TN, and %CaCO₃) and stable isotope ratios (δ¹³C and δ¹⁵N) …

Investigation Of The Lead Isotope Signatures Of Marine Sediments In Relation To The Lead Isotope Signatures Of Northern Andean Ores, Kimberly D. Beck

FIU Electronic Theses and Dissertations

Lead isotope ratios of ores and igneous rocks in the Central and Southern Andes show a large-scale geographic pattern related to magmatic source processes. This pattern changes in the Northern Andes for reasons that are not well understood; this study is an investigation of potential causes of this change. Deep ocean sediment samples from the Nazca Plate were analyzed for ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb, and the data were compared with published data on central Andean ores and ores and igneous rocks from Ecuador. Lead isotopic compositions of the Nazca Plate sediments …

Elemental Analysis And Forensic Comparison Of Soils By Laser-Induced Breakdown Spectroscopy (Libs) And Laser Ablation Inductively Coupled Plasma Mass Spectrometry (La-Icp-Ms), Sarah C. Jantzi

FIU Electronic Theses and Dissertations

The elemental analysis of soil is useful in forensic and environmental sciences. Methods were developed and optimized for two laser-based multi-element analysis techniques: laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and laser-induced breakdown spectroscopy (LIBS). This work represents the first use of a 266 nm laser for forensic soil analysis by LIBS.

Sample preparation methods were developed and optimized for a variety of sample types, including pellets for large bulk soil specimens (470 mg) and sediment-laden filters (47 mg), and tape-mounting for small transfer evidence specimens (10 mg). Analytical performance for sediment filter pellets and tape-mounted soils was similar …