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Physical Sciences and Mathematics Commons

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Earth Science Faculty Scholarship

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Climate change

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Full-Text Articles in Physical Sciences and Mathematics

Long-Term And Seasonal Variations In Co2: Linkages To Catchment Alkalinity Generation, Stephen A. Norton, B. J. Cosby, I. J. Fernandez, J. S. Kahl, M. Robbins Church Mar 2001

Long-Term And Seasonal Variations In Co2: Linkages To Catchment Alkalinity Generation, Stephen A. Norton, B. J. Cosby, I. J. Fernandez, J. S. Kahl, M. Robbins Church

Earth Science Faculty Scholarship

As atmospheric emissions of S have declined in the Northern Hemisphere, there has been an expectation of increased pH and alkalinity in streams believed to have been acidified by excess S and N. Many streams and lakes have not recovered. Evidence from East Bear Brook in Maine, USA and modelling with the groundwater acid-base model MAGIC (Cosby et al. 1985a,b) indicate that seasonal and yearly variations in soil PCO2 are adequate to enhance or even reverse acid-base (alkalinity) changes anticipated from modest decreases of SO4 in surface waters. Alkalinity is generated in the soil by exchange of H+ from dissociation …


Glaciochemical Investigations As A Tool In The Historical Delineation Of The Acid Precipitation Problem, William B. Lyons, Paul Andrew Mayewski Jul 1984

Glaciochemical Investigations As A Tool In The Historical Delineation Of The Acid Precipitation Problem, William B. Lyons, Paul Andrew Mayewski

Earth Science Faculty Scholarship

Precipitation in the Northern Hemisphere has been recently recognized to have hydrogen ion concentrations 10 to 100 times higher than expected for natural precipitation (Likens and Bormann 1974, Cogbill and Likens 1974, Lewis and Grant 1980). However, controversy has arisen regarding the nature of the acidity of the precipitation sampled and whether, indeed, the pH of North American precipitation has increased over time (Miller and Everett 1979, Lerman 1979, Stensland 1980, Sequeria 1981, Carlson and Rodhe 1982). In most locations pH records have been constructed rather imperfectly due to differences in sampling, handling, and analytical procedures used (Galloway and Likens …