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Articles 1 - 6 of 6
Full-Text Articles in Physical Sciences and Mathematics
Enrichments Of Heavy Sulfur (34s) In Sulfide Minerals: Gas Hydrates, Methane Delivery, And Anaerobic Methane Oxidation, Walter S. Borowski, Namcy M. Rodriguez, Charles K. Paull, William Ussler Iii
Enrichments Of Heavy Sulfur (34s) In Sulfide Minerals: Gas Hydrates, Methane Delivery, And Anaerobic Methane Oxidation, Walter S. Borowski, Namcy M. Rodriguez, Charles K. Paull, William Ussler Iii
EKU Faculty and Staff Scholarship
The sulfur isotopic composition of authigenic, sedimentary sulfide minerals is largely controlled by sulfate reduction and related processes within sedimentary environments. Histograms show that that d34S values of sulfide minerals forming in depositional and diagenetic environments are most often negative (d34S < 0o/oo CDT) reflecting the original isotopic composition of seawater sulfate (now ~21o/oo), microbially-mediated fractionations of ~-8 to -40o/oo (a = 1.029-1.059) during sulfate reduction, and more extreme fractionations caused by sulfur disproportionation. Enrichments of heavy sulfur (d34S > 0o/oo) in sulfide …
The Meeting Of Two Microbial Worlds: Geochemistry Of The Sulfate-Methane Interface, Walter S. Borowski, Charles K. Paull, William Ussler Iii
The Meeting Of Two Microbial Worlds: Geochemistry Of The Sulfate-Methane Interface, Walter S. Borowski, Charles K. Paull, William Ussler Iii
EKU Faculty and Staff Scholarship
No abstract provided.
Data Report: Carbon Isotopic Composition Of Dissolved Co2, Co2 Gas, And Methane, Blake-Bahama Ridge And Northeast Bermuda Rise, Odp Leg 172, Walter S. Borowski, Namik Cagatay, Y Tournois, Charles K. Paull
Data Report: Carbon Isotopic Composition Of Dissolved Co2, Co2 Gas, And Methane, Blake-Bahama Ridge And Northeast Bermuda Rise, Odp Leg 172, Walter S. Borowski, Namik Cagatay, Y Tournois, Charles K. Paull
EKU Faculty and Staff Scholarship
Carbon isotopic data of interstitial dissolved CO2 (ΣCO2), CO2 gas, and methane show that a variety of microbial diagenetic processes produce the observed isotopic trends. Anaerobic methane oxidation (AMO) is an important process near the sulfate-methane interface (SMI) that strongly influences the isotopic composition of ΣCO2 in the sulfate reduction and upper methanogenic zones, which in turn impacts methane isotopic composition. Dissolved CO2 and methane are maximally depleted in 3C near the SMI, where C values are as light as –31.8‰ and –101‰ PDB for ΣCO2 and methane, respectively. CO2 reduction links the CO2 and methane pools in the methanogenic …
Significance Of Anaerobic Methane Oxidation In Methane-Rich Sediments Overlying The Blake Ridge Gas Hydrates, Walter S. Borowski, Tori M. Hoehler, Mark J. Alperin, Namcy M. Rodriguez, Charles K. Paull
Significance Of Anaerobic Methane Oxidation In Methane-Rich Sediments Overlying The Blake Ridge Gas Hydrates, Walter S. Borowski, Tori M. Hoehler, Mark J. Alperin, Namcy M. Rodriguez, Charles K. Paull
EKU Faculty and Staff Scholarship
A unique set of geochemical pore-water data, characterizing the sulfate reduction and uppermost methanogenic zones, has been collected at the Blake Ridge (offshore southeastern North America) from Ocean Drilling Program (ODP) Leg 164 cores and piston cores. The δ13 C values of dissolved CO2(Σ CO2) are as 13 C-depleted as –37.7‰ PDB (Site 995) at the sulfate-methane interface, reflecting a substantial contribution of isotopically light carbon from methane. Although the geochemical system is complex and difficult to fully quantify, we use two methods to constrain and illustrate the intensity of anaerobic methane oxidation in Blake Ridge sediments. An estimate using …
New Technique Detects Gas Hydrates, Walter S. Borowski, Charles K. Paull, William Ussler Iii
New Technique Detects Gas Hydrates, Walter S. Borowski, Charles K. Paull, William Ussler Iii
EKU Faculty and Staff Scholarship
As exploration and development moves into deep waters, the possibility of encountering gas hydrates within seafloor sediments becomes increasingly likely. The ability to accurately detect gas hydrates is key to producing deepwater fields, allowing operators to safely design and place offshore drilling and production platforms, subsea production equipment and flow lines, as well as pipelines.
Marine Pore-Water Sulfate Profiles Indicate In Situ Methane Flux From Underlying Gas Hydrate, Walter S. Borowski, Charles K. Paull, William Ussler Iii
Marine Pore-Water Sulfate Profiles Indicate In Situ Methane Flux From Underlying Gas Hydrate, Walter S. Borowski, Charles K. Paull, William Ussler Iii
EKU Faculty and Staff Scholarship
Marine pore-water sulfate profiles measured in piston cores are used to estimate methane flux toward the sea floor and to detect anomalous methane gradients within sediments overlying a major gas hydrate deposit at the Carolina Rise and Blake Ridge (U.S. Atlantic continental margin). Here, sulfate gradients are linear, implying that sulfate depletion is driven by methane flux from below, rather than by the flux of sedimentary organic matter from above. Thus, these linear sulfate gradients can be used to quantify and assess in situ methane flux, which is a function of the methane inventory below.