Physical Sciences and Mathematics Commons^™

Synthesis And Characterization Of Quantum Materials, Yunsheng Qiu

Doctoral Dissertations

"In this study, attempts were made to grow quantum materials that have recently undergone a profound change of perspective. These materials are involved in intricate macroscopic properties rooted in the subtle nature of quantum physics. To explore our understanding of quantum materials, this study includes three projects: Magnetic Topological Insulators, Topological Superconductors, and high-temperature superconductors.

A Cr-doped Sb₂Te₃ is added to the category for the magnetic topological insulators project. Their transport properties are studied, and the origin of ferromagnetism is studied. Anomalous Hall effect is observed in the Hall measurements, and serval factors (cooling rate, dopant deficiency) …

Design, Synthesis, And Characterization Of Complex Chalcogenides For Energy Storage And Energy Conversion Applications, Srikanth Balijapelly

Doctoral Dissertations

"Through this investigation, complex chalcogenides with the combination of main group metals, transition metals, and rare earth metals have been synthesized using the building block approach and their structure-property relationships are evaluated. The main emphasis of research is on rationally designing new materials for applications in sodium and lithium ion conducting solid electrolytes, cathodes, thermoelectrics, and nonlinear optics. Along with the experimental studies, theoretical calculations are also employed to better understand the physicochemical properties of the synthesized compounds.

The first part of the research will discuss designing alkali ion containing complex chalcogenides using the building block approach. This investigation resulted …

Chirality Determination Using Three-Wave Mixing Microwave Spectroscopy, Nicole Taylor Moon

Doctoral Dissertations

"Rotational spectroscopy has established itself as a reliable gas-phase spectroscopic technique for the structural determination of molecules. This reliability has stemmed from both advancements in microwave technology and a willingness from the community to push the boundaries of the field. In this dissertation, the boundaries are tested in both how well the technique can determine the structure of molecules exhibiting large amplitude motion and through chirality determination. The first half of this dissertation explores the use of deep averaging to determine the structure of silicon containing molecules in collaboration with Dr. Guirgis from the College of Charleston. For each of …

Experimental Investigation Of High-Temperature Brine-Shale Interactions, Anna Atasha Hoffmann

Doctoral Dissertations

"Hydrofracturing (fracking), a common practice in the Petroleum Industry to induce or improve fluid flow in tight formations, creates chemical disequilibrium that further alters the porosity and permeability of host rocks and results in the production of saline and contaminated produced waters (PW). The PW of the Tuscaloosa Marine Shale (TMS) are Na-Ca-Mg-K-Cl brines with mean concentrations of approximately 16% Total Dissolved Solids (TDS) and circumneutral pH. Analysis of composition suggests the PW result from a 20 to 80% dilution of formation waters (relict brines of the Louann Salt) by fracking fluid. Trace element concentrations generally show moderate to strong …

The Science Of Gravitational-Wave Sources And Beyond Compact Binary Coalescences, Yanyan Zheng

Doctoral Dissertations

"This work focuses on the field of gravitational-wave astronomy by extending the scope of detectable sources beyond compact binary coalescences, All the gravitational-wave detections so far come from compact binary coalescences. Focusing on core-collapse supernovae as promising sources for short gravitational-wave transients, this work reports optically targeted searches for gravitational-wave emitted by core-collapse supernovae during the third observing run of the LIGO and Virgo detectors. It also predicts the search sensitivity for the ongoing fourth and forthcoming fifth observing runs. Moreover, the work introduces a novel computational framework for testing the spatial distribution of binary black hole sources, allowing for …

Re-Evaluating Missouri’S Strategic Element Potential: A Geochemical Study Of The Mesoproterozoic Fe-Cu-Co-Ree Deposits In Southeast Missouri, Usa, Brandon James Sullivan

Doctoral Dissertations

"Iron-oxide-copper-gold (IOCG) deposits are poorly understood mineral systems. For example, we do not know why Cu- and Co-rich IOCG deposits typically occur proximal to Fe ore deposits that are notably Cu and Co-poor, such as Iron Oxide Apatite (IOA) deposits. To better understand the formation of IOA and IOCG deposits in Missouri, USA, this PhD thesis examines the genesis of the Kratz Spring IOA and the Boss Central Dome IOCG deposits. This study presents the first constraints on formation conditions and fluid sources in the studied deposits using integrated petrographic, mineral composition, and Fe isotope analyses of oxide minerals. Observations …

Novel Quantum Materials For Spintronic And Opto-Electronic Applications, Ali Sarikhani

Doctoral Dissertations

"Multi-functional quantum materials play a crucial role in the development of spintronics and opto-electronics, as their properties can greatly influence device performance. For instance, in spintronics, materials such as ferromagnetic half-metals, Giant Magnetoresistants (GMR), and magnetic semiconductors have been extensively studied due to their ability to manipulate the spin of electrons for applications in magnetic storage. In opto-electronics, materials such as Diluted Magnetic Semiconductors (DMS) and non-oxide Transparent Conductors (TC) offer advantages such as tunable bandgap and high absorption coefficients, which enable improved device performance.

For this purpose, we have experimentally investigated the compounds that have shown theoretically interesting physical …

Advances In Differentially Methylated Region Detection And Cure Survival Models, Daniel Ahmed Alhassan

Doctoral Dissertations

"This dissertation focuses on two areas of statistics: DNA methylation and survival analysis. The first part of the dissertation pertains to the detection of differentially methylated regions in the human genome. The varying distribution of gaps between succeeding genomic locations, which are represented on the microarray used to quantify methylation, makes it challenging to identify regions that have differential methylation. This emphasizes the need to properly account for the correlation in methylation shared by nearby locations within a specific genomic distance. In this work, a normalized kernel-weighted statistic is proposed to obtain an optimal amount of "information" from neighboring locations …

Electrodeposition Of Epitaxial Wide Bandgap P-Type Semiconductors And Copper Metal For Energy Conversion And Flexible Electronics, Bin Luo

Doctoral Dissertations

"Epitaxial electrodeposition is a simple, low-cost technology to produce highly ordered materials on single-crystal surfaces. This research focuses on the epitaxial electrodeposition of wide bandgap p-type semiconductors and epitaxial Cu thin films via a self-assembled monolayer for energy conversion and flexible electronics. Paper I introduces the epitaxial electrodeposition of hole conducting CuSCN nanorods onto Au (111) surface, and lift-off to produce flexible and transparent foils. Highly ordered CuSCN could serve as an inorganic transport layer in various opto-electronic devices such as perovskite solar cells, LEDs, and transistors. An ordered and transparent CuSCN foil was also produced by epitaxial lift-off following …

Near-Ir Spectroscopic Analysis Of The Primary Volatile Composition Of Long And Short-Period Comets, Younas Khan

Doctoral Dissertations

"Comets are among the most well-preserved objects that formed in the protosolar nebula ∼4.5 Gyr ago. Hence, they are important for understanding various aspects of the formation, evolution, and habitability of the solar system. Multiple primary volatiles (molecules directly sublimating into the coma from the nucleus) emit via rovibrational transitions in the near-IR, providing opportunities to calculate their abundances. To date, only ∼50 comets have been characterized for their primary volatiles, with the short-period Jupiter-family comets (JFCs) being significantly underrepresented. In contrast, hundreds of comets have been sampled at optical/UV wavelengths, primarily for the composition of daughter species, leading to …

Recurrent Event Data Analysis With Mismeasured Covariates, Ravinath Alahakoon Mudiyanselage

Doctoral Dissertations

"Consider a study with n units wherein every unit is monitored for the occurrence of an event that can recur with random end of monitoring. At each recurrence, p concomitant variables associated to the event recurrence are recorded with q (q ≤ p) collected with errors. Of interest in this dissertation is the estimation of the regression parameters of event time regression models accounting for the covariates. To circumvent the problem of bias and consistency associated with model's parameter estimation in the presence of measurement errors, we propose inference for corrected estimating functions with well-behaved roots under additive measurement errors …

Applied Geochemistry, Geochronology And Biostratigraphy: Case Studies From The 38th Parallel Structures In Missouri And Orange Basin, Offshore Western South Africa, Marissa Kay Spencer

Doctoral Dissertations

"The unique alignment of the Decaturville, Crooked Creek, and Weaubleau geological structures in central Missouri, three of nine known such structures along the 38th parallel in Illinois, Missouri, and Kansas, has puzzled geoscientists for decades. Research using palynology (palynomorphs and particulate organic matter) and radiometric dating of impact spherules were used to constrain age and a relationship between these enigmatic structures and infer their paleoenvironmental conditions. Novel melting damages, unique to impact, were documented in the palynomorphs in all the three structures. Early Ordovician acritarchs with melted processes correlate with ⁴⁰Ar-³⁹Ar stepwise heating age of impact spherules …

Fluorination Of Rubisco-Mimetic Co2 Capture Systems. Theoretical And Experimental Studies Of Ammonium Ion Acidity Depression And Carbamylation, Brian Michael Jameson

Doctoral Dissertations

"RuBisCO-inspired CO₂ capture and release (CCR) systems featuring amines have been developed for the purpose of reversable CO₂ capture from air. The enzyme active site consists of the tetrapeptide sequence Lys-Asp-Asp-Glu. The Lys sidechain amine undergoes carbamylation and an Mg²⁺ cation stabilizes the resulting carbamate. The N^a-acyl-lysinyl-aspratyl-aspartyl-glutamide (Lys-Asp-Asp-Glu, KDDE) peptide featured maximum capture at pH ≈ 10; a pH region too high for Mg²⁺ ions to remain in solution. This work aims to achieve pKa depression by introducing fluorine in the proximity of the lysine’s sidechain amine. A comparative analysis was made of butylamine, …

Essays On Conditional Heteroscedastic Time Series Models With Asymmetry, Long Memory, And Structural Changes, K C M R Anjana Bandara Yatawara

Doctoral Dissertations

"The volatility of asset returns is usually time-varying, necessitating the introduction of models with a conditional heteroskedastic variance structure. In this dissertation, several existing formulations, motivated by the Generalized Autoregressive Conditional Heteroskedastic (GARCH) type models, are further generalized to accommodate more dynamic features of asset returns such as asymmetry, long memory, and structural breaks. First, we introduce a hybrid structure that combines short-memory asymmetric Glosten, Jagannathan, and Runkle (GJR) formulation and the long-memory fractionally integrated GARCH (FIGARCH) process for modeling financial volatility. This formulation not only can model volatility clusters and capture asymmetry but also considers the characteristic of long …

Efficient High Order Ensemble For Fluid Flow, John Carter

Doctoral Dissertations

"This thesis proposes efficient ensemble-based algorithms for solving the full and reduced Magnetohydrodynamics (MHD) equations. The proposed ensemble methods require solving only one linear system with multiple right-hand sides for different realizations, reducing computational cost and simulation time. Four algorithms utilize a Generalized Positive Auxiliary Variable (GPAV) approach and are demonstrated to be second-order accurate and unconditionally stable with respect to the system energy through comprehensive stability analyses and error tests. Two algorithms make use of Artificial Compressibility (AC) to update pressure and a solenoidal constraint for the magnetic field. Numerical simulations are provided to illustrate theoretical results and demonstrate …

Using Coherence And Interference To Study The Few Body Dynamics In Simple Atomic Collisions Systems, Sujan Bastola

Doctoral Dissertations

"Atomic Collision experiments are best suited to sensitively test the few-body dynamics of simple systems. The few-body dynamics, in turn, can be sensitively affected by interference effects. However, an important requirement to observe interference effects in atomic scattering experiments is that the incoming projectile beam must be coherent. The coherence properties of the incoming projectile can be controlled by the geometry of the collimating slit placed before the target. We performed a kinematically complete experiment where a 75 keV proton beam is crossed with a molecular hydrogen beam to study the dissociative capture process. The motivation for this project was …

Survivor Bond Models For Securitizing Longevity Risk, Priscilla Mansah Codjoe

Doctoral Dissertations

"Longevity risk is the risk that a reference population’s mortality rates deviate from what is projected from prior life tables. This is due to discoveries in biological sciences, improved public health measures, and nutrition, which have dramatically increased life expectancy. Longevity risk raises life insurers’ liability, increasing product costs and reserves. Securitization through longevity derivatives is a way of dealing with this risk.

To enhance the pricing of life contingent products, we present an additive type mortality model in the style of the Lee-Carter. This model incorporates policyholder covariates. By using counting processes and martingale machinery, we obtain close form …

Hydroclimate Variability In Central America During The Holocene Inferred From Lacustrine Sediments In Lake Izabal, Eastern Guatemala, Edward Fernando Duarte

Doctoral Dissertations

"Holocene hydroclimate reconstructions have contributed to our understanding of the mechanisms controlling precipitation in Central America. Recent hydroclimate proxy records from the region, however, have revealed considerable spatiotemporal complexity in precipitation variability. This complexity is hypothesized to result from the interaction between multiple oceanic-atmospheric processes that converge in the region. This project analyzed three sediment cores from Lake Izabal, eastern lowland Guatemala, with the goal of understanding changes in precipitation, lake productivity, and lake water chemistry during the Holocene. Our proxy results indicate that precipitation in the region increased from the early to the middle Holocene, when Lake Izabal became …

Secured Information Dissemination And Misbehavior Detection In Vanets, Ayan Roy

Doctoral Dissertations

"In a connected vehicle environment, the vehicles in a region can form a distributed network (Vehicular Ad-hoc Network or VANETs) where they can share traffic-related information such as congestion or no-congestion with other vehicles within its proximity, or with a centralized entity via. the roadside units (RSUs). However, false or fabricated information injected by an attacker (or a malicious vehicle) within the network can disrupt the decision-making process of surrounding vehicles or any traffic-monitoring system. Since in VANETs the size of the distributed network constituting the vehicles can be small, it is not difficult for an attacker to propagate an …

Social Media Analytics With Applications In Disaster Management And Covid-19 Events, Md Yasin Kabir

Doctoral Dissertations

"Social media such as Twitter offers a tremendous amount of data throughout an event or a disastrous situation. Leveraging social media data during a disaster is beneficial for effective and efficient disaster management. Information extraction, trend identification, and determining public reactions might help in the future disaster or even avert such an event. However, during a disaster situation, a robust system is required that can be deployed faster and process relevant information with satisfactory performance in real-time. This work outlines the research contributions toward developing such an effective system for disaster management, where it is paramount to develop automated machine-enabled …

Semiparametric Estimation With Clustered Right Censored Data Via Multivariate Gaussian Random Fields, Fathima Zahra Sainul Abdeen

Doctoral Dissertations

Consider a fixed number of clustered areas identified by their geographical coordinate that are monitored for the occurrences of an event such as pandemic, epidemic, migration to name a few. Data collected on units at all areas include time varying covariates and other environmental factors that may affect event occurrences. The event times in every area can be independent. They can also be correlated with correlation between two units induced by an unobservable frailty. In both cases, the collected data is considered pairwise to account for spatial correlation between all pair of areas. The pairwise right censored data is probit-transformed …

Mantle Flow And Transition Zone Discontinuities Beneath The Carribean Plate: Constraints From Shear Wave Splitting And Receiver Function Analyses, Tu Xue

Doctoral Dissertations

"Azimuthal anisotropy quantified by teleseismic SKS, SKKS, PKS (“XKS”) and local S wave splitting parameters is used to investigate lithospheric deformation and asthenospheric flow beneath the boundary zone of the North American and Caribbean plates and adjacent areas. A total of 4915 XKS and 1202 pairs of local S wave splitting parameters were obtained at 24 broad band seismic stations. The XKS observations can be divided into two groups based on the spatial distribution of the resulting fast polarization orientations. Those observed on the Caribbean Plate are mostly WNW-ESE which are roughly trench-parallel. In contrast, the fast orientations observed on …

The Kanarra Fold-Thrust System -- The Leading Edge Of The Sevier Fold-Thrust Belt, Southwest Utah, William Joseph Michael Chandonia

Doctoral Dissertations

“The Jurassic to Eocene Sevier fold-thrust belt is the subject of continued scientific curiosity in tectonics, stratigraphy, and industry. Understanding its development in southwest Utah is hindered in part due to the multiple origins proposed for the Kanarra anticline, a major leading edge structure -- a drag fold along the Hurricane fault, Laramide monocline, Sevier fault propagation fold, or a combination of these -- which have confused its tectonic significance and regional context. This confusion results from the structural complexity of its exposed eastern limb, as well as displacement and burial of its crest and western limb beneath Neogene sediments …

Representation Learning On Heterogeneous Spatiotemporal Networks, Dakshak Keerthi Chandra

Doctoral Dissertations

“The problem of learning latent representations of heterogeneous networks with spatial and temporal attributes has been gaining traction in recent years, given its myriad of real-world applications. Most systems with applications in the field of transportation, urban economics, medical information, online e-commerce, etc., handle big data that can be structured into Spatiotemporal Heterogeneous Networks (SHNs), thereby making efficient analysis of these networks extremely vital. In recent years, representation learning models have proven to be quite efficient in capturing effective lower-dimensional representations of data. But, capturing efficient representations of SHNs continues to pose a challenge for the following reasons: (i) Spatiotemporal …

Advances And Applications In High-Dimensional Heuristic Optimization, Samuel Alexander Vanfossan

Doctoral Dissertations

“Applicable to most real-world decision scenarios, multiobjective optimization is an area of multicriteria decision-making that seeks to simultaneously optimize two or more conflicting objectives. In contrast to single-objective scenarios, nontrivial multiobjective optimization problems are characterized by a set of Pareto optimal solutions wherein no solution unanimously optimizes all objectives. Evolutionary algorithms have emerged as a standard approach to determine a set of these Pareto optimal solutions, from which a decision-maker can select a vetted alternative. While easy to implement and having demonstrated great efficacy, these evolutionary approaches have been criticized for their runtime complexity when dealing with many alternatives or …

Secure And Efficient Information Management In Delay(Disruption) Tolerant Network, Shudip Datta

Doctoral Dissertations

"In environments like international military coalitions on the battlefield or multi-party relief work in a disaster zone, multiple teams are deployed to serve different mission goals by the command-and-control center (CC). They may need to survey damages and send information to the CC for situational awareness and also transfer messages to each other for mission purposes. However, due to the damaged network infrastructure in the emergency, nodes need to relay messages using the store and forward paradigm, also called Delay-tolerant Networks (DTNs). In DTN, the limited bandwidth, energy, and contacts among the nodes, and their interdependency impose several challenges such …

Persistent Stealthy Attacks And Their Detection In Large Distributed Cyber-Physical Systems, Simon Bech Thougaard

Doctoral Dissertations

"Cyber-Physical Systems (CPS) are increasingly targeted by attackers using a wide and evolving array of methods. When these systems are distributed, every node represents a potential vulnerability, and secure system design must take this into account. Distributed CPSs also have the potential to better detect and handle attacks, by leveraging redundancies of physical measurements between adjacent nodes. The main purpose of this research is to determine the conditions that render a distributed CPS more resistant to attacks, and the conditions that render it more vulnerable. The work is centered around two separate applications: The Smart Grid and Autonomous Drone Swarms. …

Design And Synthesis Of Purine Based Neuroprotectors And Novel Synthetic Methods For The Trifluoromethylation Of Aldehyde Hydrazones, Puspa Aryal

Doctoral Dissertations

"Purine-derived compounds are widely investigated as cyclin-dependent kinase inhibitors that have broad applications in the design of pharmaceuticals for treating diseases, such as diabetes, atherosclerosis, and cancers. Towards the goal of effective AGE-inhibitors, and neuroprotector compounds we have synthesized a series of novel purine-based triazoles and investigated their neuroprotective effects, using SHSY-3Y human neuroblastoma cell line. Through these studies, we have identified purine-based neuroprotector compounds that favorably modulate oxidative stress induced by the Fenton reaction-generated reactive oxygen species (ROS).

The C(sp²−H)-trifluoromethylation of hydrazones would give access to the αtrifluoromethylated hydrazones that can serve as intermediates in the synthesis …

Application Of Machine Learning In Geophysics: Ranking Teleseismic Shear Wave Splitting Measurements And Classifying Different Types Of Earthquakes, Yanwei Zhang

Doctoral Dissertations

"During the past decades, applications of Machine Learning have been explosively developed to solve various academic and industrial problems, and over-human performance has been shown in diverse areas. In geophysical research, Machine Learning, especially Convolutional Neural Network (CNN), has been applied in numerous studies and demonstrated considerable potential. In this study, we applied CNN to solve two geophysical problems, ranking teleseismic shear splitting (SWS) measurements and classifying different types of earthquakes.

For ranking teleseismic SWS measurements, we utilized a CNN-based method to automatically select reliable SWS measurements. The CNN was trained by human-verified teleseismic SWS measurements and tested using synthetic …

Depositional Conditions, Stratigraphic Evolution, And Allo- And Autogenic Controls Of Lower Permian Non-Marine Carbonate Rocks, Lucaogou Low-Order Cycle, Bogda Mountains, Nw China, Yiran Lu

Doctoral Dissertations

"The overall objective of this study is to interpret the depositional conditions of lacustrine carbonate deposits of the lower Permian Lucaogou low-order cycle in the greater Turpan-Junggar continental rift basin, NW China. The depositional environments of ten carbonate lithofacies in the Tarlong-Taodonggou half graben and the Zhaobishan section were interpreted. Allo- and autogenic factors were identified. They controlled characteristics and distribution pattern of carbonate deposits in regional and local scale, respectively. Allogenic factors include the amount and direction of regional siliciclastic input, basin geometry, cyclic humidity/aridity oscillation, temperature, and regional tectonics. Autogenic factors include local siliciclastic input, local topography, local …