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Dissertations

2009

Block copolymer/magnetic metal oxide nanocomposites

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Full-Text Articles in Physical Sciences and Mathematics

Magnetic And Dielectric Properties Of Sulfonated (S) Poly[(Styrene)-(Ethylene-Co-Butylene)-(Styrene)] (Sebs) Block Copolymer/Magnetic Metal Oxide Nanocomposites Synthesized Via An In-Situ Precipitation Method, Sateesh Kumar Peddini May 2009

Magnetic And Dielectric Properties Of Sulfonated (S) Poly[(Styrene)-(Ethylene-Co-Butylene)-(Styrene)] (Sebs) Block Copolymer/Magnetic Metal Oxide Nanocomposites Synthesized Via An In-Situ Precipitation Method, Sateesh Kumar Peddini

Dissertations

Block copolymer/magnetic metal oxide nanocomposites were synthesized by growing metal oxide nanoparticles (cobalt ferrite, CoFe204 and iron oxide, a-Fe203) in sulfonated (s) poly (styrene) (PS) block domains of sulfonated poly [(styrene)-(ethyleneco- butylene)-(styrene)] (SEBS) BCP preformed films via an in-situ precipitation method by dissolving the salts of respective metal chloride (s) in a suitable solvent that selectively swells the sPS regions. Inorganic uptake was determined using thermogravimetric analysis (TGA), and it was observed that none of the samples incorporated more than 5 wt % of the inorganic component. Dynamical mechanical analysis was used to observe the changes in the glass transition …