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Physical Sciences and Mathematics Commons

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Dissertations

Chemistry

2016

Click Reactions

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Full-Text Articles in Physical Sciences and Mathematics

Curing Of Polymer Thermosets Via Click Reactions, Mark Richard Brei May 2016

Curing Of Polymer Thermosets Via Click Reactions, Mark Richard Brei

Dissertations

In the first project, an azide functional resin and tetra propargyl aromatic diamines were fabricated for use as a composite matrix. These systems take already established epoxy/amine matrices and functionalize them with click moieties. This allows lower temperatures to be used in the production of a thermoset part. These new systems yield many better mechanical properties than their epoxy/amine derivatives, but their Tgs are low in comparison.

The second project investigates the characterization of a linear system based off of the above azide functional resin and a difunctional alkyne. Through selectively choosing catalyst the linear system can show …