Physical Sciences and Mathematics Commons^™

Routes To N-Heterocycle Functionalized Poly(Arylene Ether Sulfone)S, Jesse L. Picker

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The synthesis of poly(arylene ether sulfone)s, with a pendant aryl iodide, was achieved via nucleophilic aromatic substitution (NAS) polycondensation of 3-iodo-3',5'-difluoro-diphenylsulfone. The polymer series was subjected to amino acid promoted, copper catalyzed coupling reactions with various N-heterocycles. The resulting polymers became crosslinked and insoluble in any organic solvents. The iodo monomer was then subjected to an amino acid promoted, copper catalyzed coupling reaction with carbazole. The successful synthesis of 3'-(9-carbazole) 3,5-difluorodiphenylsulfone is reported. A series of PAES containing a carbazole substituent were synthesized and characterized. The polymers were characterized by a combination of NMR spectroscopy, SEC, TGA, DSC, UV-Vis spectroscopy. …

Processing And Interpretation Of Illinois Basin Seismic Reflection Data, Katherine M. Gigandet

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An anonymous oil company released 2D dynamite reflection data from the Illinois basin to be reprocessed and interpreted by Wright State University. The aim of the project is to exhaustively apply different seismic processing methods to the data to determine if any improvement in the imaging and interpretation may be accomplished. The data interpretation procedure convolved extracted wavelets from the final migrated section with reflectivity calculated from well log data provided. Once major formation tops were identified attribute analysis was applied to locate potential oil volumes of interest.

The raw shot records from this impulse data are dominated by guided …

Effect Of Rivers On Groundwater Temperature In Heterogeneous Buried-Valley Aquifers: Extent, Attenuation, And Phase Lag Of Seasonal Variation, Nathan Lee Young

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The temperature of groundwater in aquifers is relatively stable when compared to the water temperature in surface-water bodies. However, in aquifers that are hydraulically connected to rivers that have water flux into the aquifer, the local aquifer temperature can show seasonal variation. This project focused on the thermally-altered, near-river zone of such an aquifer, and used numerical methods to examine the extent of seasonal variation in temperature into the aquifer, and the attenuation and phase shift of the signal with distance from the river. The results show that the extent of alteration by diffusive heat flow is negligible compared to …

Characterization Of A Utica Shale Reflector Package Using Well Log Data And Amplitude Variation With Offset Analysis, Andrei Butterfield

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Using well logs and AVO gradient analysis, I identify and characterize a package of reflectors associated with the Utica Shale from vibroseis data collected by Wright State University at the Gabor Gas Storage field near Canton, Ohio. I also correlate TOC measurements from wells to densities and velocities at the same depths. On the seismic data, I interpret prominent reflections from the top and bottom of the Utica Shale and an intra-Utica reflector of varying frequency content associated with a velocity/density low in well log data. I investigate the possibility that the lateral variation in frequency content and change in …

Seismic Interpretation And Well Log Analysis Of Jay County, Indiana, Focused On Lithologic Units Below The Mt. Simon Formation, Jennifer Welder

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Cuttings recovered from two Benegar wells in Jay County, Indiana, have led to the recognition of a lithic arenite and limestone layer beneath the Mt. Simon Sandstone, the regional basal sandstone of the Paleozoic platform sequence. This lithic arenite is interpreted as the Middle Run Formation which has been observed in numerous wells within the Western Ohio, Northern Kentucky, and Indiana region. However, the limestone layer in these Benegar wells is unique, with only one other instance of limestone beneath the Mt. Simon being in the Mattison #1 well in southeast Clark County, Ohio. During the summer of 2013 students …

Distributed Local Trust Propagation Model And Its Cloud-Based Implementation, Dharan Kumar Reddy Althuru

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World Wide Web has grown rapidly in the last two decades with user generated content and interactions. Trust plays an important role in providing personalized content recommendations and in improving our confidence in various online interactions. We review trust propagation models in the context of social networks, semantic web, and recommender systems. With an objective to make trust propagation models more flexible, we propose several extensions to the trust propagation models that can be implemented as configurable parameters in the system. We implement Local Partial Order Trust (LPOT) model that considers trust as well as distrust ratings and perform evaluation …

Functionalized Sulfone And Sulfonamide Based Poly(Arylene Ether)S, Marina Andrejevic

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A series of fluorinated poly(arylene ether)s, PAE, bearing sulfonated pendent sulfonyl groups, was prepared. A range of Ion Exchange Capacity (IEC) values were achieved by varying the ratios of sulfonated and non sulfonated monomers. Incorporation of both of the monomers was confirmed by NMR spectroscopy and characterization of the thermal properties was done using thermogravimetric analysis (TGA) and differential scanning (DSC). Polymers with these IEC values were synthesized in order to explore their use as a potential alternatives to the widely studied proton exchange membrane, Nafion, with an IEC of 0.91 meq/g.

Using N-phenyl-3,5-difluorobenzene sulfonamide as the starting material a …

The Synthesis Of Polyimides Containing Oxyalkylene Units, Kristy Wickman

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A series of oxyalkylene containing diamines, 1,4-bis(2-(4-aminophenoxy)-ethoxy)benzene, 2,2-bis[4-(2-(4-nitrophenoxy)ethoxy)phenyl]hexafluoropropane, 9,9-bis(4-(2-(4-nitrophenoxy)ethoxy)phenyl)fluorene, and bis(4-(2-(4-nitrophenoxy)ethoxy)-phenyl)diphenylmethane, has been synthesized from the reduction of 1,4-bis(2-(4-nitrophenoxy)ethoxy)benzene, 2,2-bis[4-(2-(4-nitrophenoxy)ethoxy)phenyl]-hexafluoropropane, 9,9-bis(4-(2-(4-nitrophenoxy)ethoxy)phenyl)fluorene, bis(4-(2-(4-nitrophenoxy)ethoxy)phenyl)diphenylmethane, respectively. The diamine compounds were reacted reacted with 6FDA to obtain the corresponding polyimide. The polymerization was done in a one-pot reaction with m-cresol and isoquinoline. The polyimides displayed glass transition temperatures ranging from 186-231°C and thermal stability <400°C.

Surface Effects On Critical Dimensions Of Ferromagnetic Nanoparticles, Vartika Chaudhary

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This work studies surface effects on the critical dimensions of ferromagnetic nanoparticles. Iron nanoparticles with different mean diameters from 5.9 nm to 21.4 nm used in this research were prepared by thermal decomposition of iron pentacarbonyl in the presence of oleic acid/octyl ether at Cambridge University, United Kingdom. Heating response of these ferromagnetic nanoparticles suspended in water were measured experimentally during which same amount of iron nanoparticles and di-ionized water were irradiated by an alternating magnetic field and the increase in temperature of these samples was measured. Heating performance of nanoparticles was described in terms of Specific Absorption Rate (SAR) …

Reactivity Ratio Controlled Polycondensation As A Route To Synthesize Functional Poly(Arylene Ether)S, Godfred Boakye

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Two monomers, 4',3,5-trifluorodiphenylsulfone, 1, and 4',3,5-trifluorobenzophenone, 2, have been investigated for their potential use as special BB'B''type monomers to synthesize functionalized, linear PAEs via a process called reactivity ratio controlled polycondensation (RRCP). A model study with monomer 1 resulted in a mixture of unreacted starting material, two mono-substitution products (para-and meta-F substitution) and a significant amount of di-substitution products as evidenced by the GC/MS and 13C DEPT-90 NMR spectroscopy. Conversely, subjecting monomer 2 to similar conditions, using 3-aminophenol (3f) as the nucleophile, afforded mono-substitution exclusively. A series of functionalized, linear PAEs polymers were prepared by reaction of compound 2 with …

Phylogenetics, Population Genetics, And Evolution Of The Mallard Complex, Philip Lavretsky

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Speciation is primarily regarded as an ancestral split that results in two distinct taxonomic units, and proceeds in stages along a continuum from initiation (i.e., population divergence) to completion (i.e., reproductively isolated species). Establishing how and why populations diverge, including the primary mechanisms influencing these events is a major objective for evolutionary scientists. Focusing on incipient forms, researchers attempt to disentangle the antagonistic nature of selection, genetic drift, and gene flow in the speciation process.

In chapter 1, I investigate the phylogenetic relationships of 14 closely related taxa within the mallard complex (Anas spp.) that underwent a radiation within the …

Mining Privacy Settings To Find Optimal Privacy-Utility Tradeoffs For Social Network Services, Shumin Guo

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Privacy has been a big concern for users of social network services (SNS). On recent criticism about privacy protection, most SNS now provide fine privacy controls, allowing users to set visibility levels for almost every profile item. However, this also creates a number of difficulties for users. First, SNS providers often set most items by default to the highest visibility to improve the utility of social network, which may conflict with users' intention. It is often formidable for a user to fine-tune tens of privacy settings towards the user desired settings. Second, tuning privacy settings involves an intricate tradeoff between …

Automatic Identification Of Interestingness In Biomedical Literature, Gaurish Anand

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This thesis presents research on automatically identifying interestingness in a graph of semantic predications. Interestingness represents a subjective quality of information that represents its value in meeting a user's known or unknown retrieval needs. The perception of information as interesting requires a level of utility for the user as well as a balance between significant novelty and sufficient familiarity. It can also be influenced by additional factors such as unexpectedness or serendipity with recent experiences. The ability to identify interesting information facilitates the development of user-centered retrieval, especially in information semantic summarization and iterative, step-wise searching such as in discovery …

Synthesis And Biological Activity Of Indolinones, Kaleb Woodrow Cox

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Indolinones of the type known as Arylidene oxindoles have been demonstrated to possess a broad range of activity ranging from proten kinase inhibtors, cell-death inhibitors and tau protein binding agents. Small libraries of such molecules were designed and synthesized herein in modifications involving variously substituted halogen derivatives, N-alkylation of the indolinone nitrogen, and finally a new class of molecules, namely arylidene oxindoles possessing extended conjugation. The biological activities of such molecules were examined and the results disclosed herein.

The Properties Of Property Alignment On The Semantic Web, Michelle Andreen Cheatham

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Ontology alignment is an important step in enabling computers to query and reason across the many linked datasets on the semantic web. This is a difficult challenge because the ontologies underlying different linked datasets can vary in terms of subject area coverage, level of abstraction, ontology modeling philosophy, and even language. The alignment approach presented here centers on string similarity metrics. Nearly all ontology alignment systems use a string similarity metric in one form or another, but it seems that the choice of a particular metric is often arbitrary. We begin this dissertation with the most comprehensive survey to date …

Chemical Analysis Of Exhaled Breath By Means Of Terahertz Rotational Spectroscopy, Tianle Guo

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Terahertz spectroscopy, due to the high sensitivity and specificity that it affords, has been incorporated in many fields to aid in the chemical analysis of gases. One potential application is to detect bio-markers in human breath for early diagnosis. Our current aim of our research is to establish a relationship between several chemicals and the glucose levels from human exhaled breath. 20 chemical including Acetone, Carbon monoxide (CO), Methanol were studied. Volunteers' breath samples were processed through a pre-concentration system before being injected into the spectrometer. Initially, a commercial preconcentration system, Entech 7100A, was used. However, due to the limitations …

An Evolutionary Approximation To Contrastive Divergence In Convolutional Restricted Boltzmann Machines, Ryan R. Mccoppin

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Deep learning is an emerging area in machine learning that exploits multi-layered neural networks to extract invariant relationships from large data sets. Deep learning uses layers of non-linear transformations to represent data in abstract and discrete forms. Several different architectures have been developed over the past few years specifically to process images including the Convolutional Restricted Boltzmann Machine. The Boltzmann Machine is trained using contrastive divergence, a depth-first gradient based training algorithm. Gradient based training methods have no guarantee of reaching an optimal solution and tend to search a limited region of the solution space. In this thesis, we present …

What Machines Understand About Personality Words After Reading The News, Eric David Moyer

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Vector-based lexical semantics is a powerful technique that still has many undiscovered applications. In this thesis I apply a vector-space lexical-semantic model newly developed by Mikolov et. al. trained on skip-grams to the lexical hypothesis in personality psychology. The method produces interpretable dimensions that are consistent across several sets of descriptive personality words. The dimensions include ones for conflict and positive and negative evaluation. However they are more descriptive of word usage semantics than of the characteristics of the thing described and thus do not include a recognizable component of the 5 factor model in their first 14 dimensions. They …

Destruction Of Chlorinated Hydrocarbons By Zero-Valent Zinc And Bimetallic Zinc Reductants In Bench-Scale Investigations, Christopher Scott Cushman

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Many remediation technologies have been developed to treat extensive subsurface contamination by chlorinated hydrocarbons (CHCs). One such technology is a permeable reactive barrier (PRB), which contains reactive media that acts as an electron donor in order to reduce CHCs. Extensive effort has been placed on finding the most suitable reactive media in PRBs, with zero-valent iron (ZVI) being the most commonly utilized media. However, zero-valent zinc (ZVZ) is a promising replacement for ZVI in PRBs as it will more readily donate electrons, resulting in more rapid degradation of CHCs. In addition, amending a secondary/catalytic metal to primary metal surface can …

A New Proof For A Result Of Kingan And Lemos, Jesse Williams

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The prism graph is the planar dual of K5\e. Kingan and Lemos proved a decomposition theorem for the class of binary matroids with no prism minor. In this paper, we present a different proof using fundamental graphs and blocking sequences.

On The Spectra Of Momentum Operators, Cody Edward Watson

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The selfadjoint momentum operators acting in two intervals are parametrized by the unitary two-by-two matrices. Fixing a parametrization of the unitary two- by-two matrices we study how the spectra of the selfadjoint momentum operators depends on these parameters as well as on the lengths of the two intervals.

Tcdd Represses 3'IghRr Activation Through An Ahr-Dependent Shift In The Nf-Κb/Rel Protein Complexes Binding To Κb Motifs Within The Hs1,2 And Hs4 Enhancers, Richard L. Salisbury Jr.

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Transcriptional regulation of the murine immunoglobulin heavy chain gene involves several regulatory elements including the 3'Igh regulatory region (3'IghRR) composed of at least four enhancers (hs3A; hs1,2; hs3B; hs4). Enhancers hs1,2 and hs4 contain binding sites for several transcription factors including NF-κB/Rel proteins and the AhR. Interestingly, 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) profoundly inhibits 3'IghRR and hs1,2 activation induced by the B-cell activator lipopolysaccharide (LPS), but enhances the activation of the hs4. Within the hs4, the AhR binding site overlaps an NF-κB/Rel binding site suggesting that both the AhR and the NF-κB together may modulate of the 3' …

A Chemical Free Approach For Increasing The Biochemical Surface-Enhanced Raman Spectroscopy (Sers)-Based Sensing Capabilities Of Colloidal Silver Nanoparticles, Kevin Michael Dorney

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The unique optoelectronic properties of silver nanoparticles (AgNPs) have led to their explosive use in a multitude of both research and industrial settings in recent years. Localized surface plasmon resonance (LSPR) exhibited by AgNPs has been exploited extensively as a nano-scale probe in a variety of spectroscopic detection modalities, particularly in surface-enhanced Raman spectroscopy (SERS). The SERS effect is highly dependent upon the LSPR interaction with optical laser frequencies, thus optimization of LSPR via specific control of AgNP dimensionality and composition of the surrounding medium is vital for increasing the efficacy of SERS-based nano-sensing. This work aimed to augment LSPR …

Thermal Properties Of Magnetic Nanoparticles In External Ac Magnetic Field, Anna Beata Lukawska

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This work studies thermal properties of magnetic nanoparticles in an external ac magnetic field. Dried iron and cobalt nanoparticles were prepared by thermal decomposition of iron pentacarbonyl (Fe(CO)5) and dicobalt octacarbonyl (Co2(CO)8), triscobalt nona(carbonyl)chloride (Co3(CO)9Cl), or tetracaobalt dodecacarbonyl (Co4(CO)12) [1]. The samples had different mean diameters: 5.6 - 21.4 nm for iron and 6.5 - 19.4 nm for cobalt. Each sample was exposed to ac magnetic field and the increase in temperature of the sample was measured. Results were analyzed to find the critical diameters for the transitions from multi-domain to single-domain and from single-domain to superparamagnetic regime. The nanoparticles …

The Synthesis Of 1,4-Bis(2-(4-(4-Fluorobenzoyl)Phenoxyethoxy)Benzene And Poly(Aralkyl Ether)S Derived From 1,4-Bis(2-Tosyloxyethoxy)Benzene, Juraj Drzic

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The reaction of 1,4-bis(2-tosyloxyethoxy)benzene or 1,4-bis(bromoethoxy)-benzene with 4-fluoro-4'-hydroxybenzophenone was carried out under a variety of conditions. Changes were made in solvent, reaction time, work-up and base. All attempts to generate a bis(fluorobenzophenone) monomer were unsuccessful. In some cases the presence of the half-product could be determined. In other cases, an elimination product was indicated. The ditosylate, 1,4-bis(2-tosyloxyethoxy)benzene was reacted with bisphenol-A, bisphenol-AF, bis(4-hydroxyphenyl)diphenylmethane and 9,9-bis(4-hydroxyphenyl)fluorene in a dioxane - water solution in the presence of sodium hydroxide to produce four polymers. The polymers were characterized by thermal analysis (TGA) to reveal 5% weight loss temperatures of 338°, 350°, 365° and …

The Synthesis Of Benzyloxy Substituted Dp-Ppv And Examination Of The Horner-Wadsworth-Emmons Reaction In The Synthesis Of Dp-Ppv, Jeremy M. Lear

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In the interest of the synthesis of polymers that have the potential to possess inherent light-emitting properties (LEDs) the synthesis of a novel 1,4-bis(chloromethyl)-benzene monomer, 5-benzyloxy-1,4-dichloromethyl-2,3-diphenyl benzene 78 was carried out. Monomer 78 was polymerized via the Gilch polymerization method to yield, poly(5-benzyloxy-2,3-diphenyl phenylene vinylene) 80. Polymer 80 was characterized by TGA (5% weight loss at 267°, GPC (weight average molecular weight of 7136 Da, number average molecular weight of 6603 Da) , UV-Vis and fluorescence studies (absorbance maximum at 406 nm, emission maximum at 510 nm).

The Horner-Wadsworth-Emmons variant of the Wittig was applied in the synthesis of poly(2,3-diphenyl-1,4-phenylenevinylene) …

Effect Of Land Use On Mercury In Soils Of Southwest Ohio, Rebecca L. Gamby

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Terrestrial biomass and soils are a primary reservoir of mercury (Hg) derived from natural and anthropogenic sources; however, the fate and stability of Hg in the surface soil reservoir and its susceptibility to change as a result of human activities is relatively unknown. In this study, soil concentrations of Hg and lead (Pb) were compared between old- and new-growth forest soils as well as fallow grassland and agricultural soils in southwest Ohio. Old- and new-growth forest soils had significantly greater concentrations of soil Hg, Pb, and organic matter than fallow and cultivated soils in the O/A horizon. Mercury:organic matter ratios …

Modeling Physical And Hydraulic Properties Of Disordered Porous Media: Applications From Percolation Theory And Fractal Geometry, Behzad Ghanbarian-Alavijeh

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A fundamental component of the hydrologic cycle is the movement of fluids in the pore space of geological formations and soils. Prediction of the motion of fluids in such porous materials requires first modeling the physical properties of the medium itself, and second, invoking a capable theory to describe fluid transport in tortuous interconnected pathways. In this dissertation, for the former we use fractal geometry since most phenomena in nature are fractal, and for the latter percolation theory is applied because it has successfully described flow and transport in disordered networks and media. We propose models for the soil water …

Thin Film Growth Of Dielectric Materials By Pulsed Laser Deposition, Jason Christopher Anders

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Thin films of Sr_yCa_1-yZr_1-xTi_xO₃ (SCZT) with x = 0.8, y = 0.01, CaHf_1-xTi_xO₃ (CHT) with x = 0.8, and _xBiScO₃ - (1-x) BaTiO₃ with x = 0.36 (BSBT(36/64)) showing a high permittivity are useful both in capacitor applications. These dielectric thin films with a SrRuO₃ (SRO) conductive bottom electrodes were prepared by using pulsed laser deposition on <100< La_0.3Sr_0.7Al_0.65Ta_0.35O₃ (LSAT) single crystal substrates. In a search of optimal conditions to achieve epitaxially grown SCZT, CHT, …

Ultraviolet Rayleigh Scatter Imaging For Spatial Temperature Profiles In Atmospheric Microdischarges, James E. Caplinger

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Spatially resolved temperature measurements within a microdischarge in atmospheric pressure air have been conducted using Rayleigh scattering of a pulsed ultraviolet laser. Scattering intensity images were used to generate a radial profile of translational temperature, with the analysis based on the ideal gas inverse relationship of temperature and gas density. Rayleigh scattering results were compared to standard optical emission spectral analyses of N2(C3Πu - B3Πg) bands, where the calculated rotational temperatures from emission were in reasonable agreement with the Rayleigh translational temperature profiles.