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Australian Institute for Innovative Materials - Papers

2014

Thin

Articles 1 - 6 of 6

Full-Text Articles in Physical Sciences and Mathematics

Microscopic Model For Exchange Bias From Grain-Boundary Disorder In A Ferromagnet/Antiferromagnet Thin Film With A Nanocrystalline Microstructure, David L. Cortie, A G. Biternas, R W. Chantrell, Xiaolin Wang, Frank Klose Jan 2014

Microscopic Model For Exchange Bias From Grain-Boundary Disorder In A Ferromagnet/Antiferromagnet Thin Film With A Nanocrystalline Microstructure, David L. Cortie, A G. Biternas, R W. Chantrell, Xiaolin Wang, Frank Klose

Australian Institute for Innovative Materials - Papers

Monte Carlo spin simulations were coupled to a Voronoi microstructure-generator to predict the magnitude and behavior of exchange bias in a ferromagnet/antiferromagnet (AF) thin film bilayer with a nanocrystalline microstructure. Our model accounts for the effects of irregular grain-shapes, finite-sized particles, and the possible presence of local random-fields originating from the antiferromagnet's grain-boundary regions. As the grain-boundary represents a crystal-structure distortion, we model the local effect on the exchange constants in the Gaussian approximation which can cause regions resembling a spin glass confined to an unusual 2D topology. Although an ensemble of completely disconnected AF grains isolated by non-magnetic barriers …


Thin, Tough, Ph-Sensitive Hydrogel Films With Rapid Load Recovery, Sina Naficy, Geoffrey M. Spinks, Gordon G. Wallace Jan 2014

Thin, Tough, Ph-Sensitive Hydrogel Films With Rapid Load Recovery, Sina Naficy, Geoffrey M. Spinks, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

Stimuli-responsive hydrogels are used as the building blocks of actuators and sensors. Their application has been limited, however, by their lack of mechanical strength and recovery from loading. Here, we report the preparation of pH-sensitive hydrogels as thin as 20 μm. The hydrogels are made of a polyether-based polyurethane and poly(acrylic acid). A simple method was employed to create hydrogels with thicknesses in the range of 20-570 μm. The hydrogel films volume changed by a factor of ∼2 when the pH was switched around the transition point (pH 4). Tensile extensibilities of up to ∼350% were maintained at each pH, …


Highly Oriented Lifepo4 Thin Film Electrodes Via Chemical Solution Deposition, Qi Li, Shulei Chou, Jiazhao Wang, Dongqi Shi, Hua-Kun Liu Jan 2014

Highly Oriented Lifepo4 Thin Film Electrodes Via Chemical Solution Deposition, Qi Li, Shulei Chou, Jiazhao Wang, Dongqi Shi, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

Highly oriented LiFePO4 thin-film electrodes were fabricated via chemical solution deposition combined with spin coating. The effects of the precursor concentrations and types of substrates on microstructures and electrochemical performances were studied. Single-phase LiFePO4 with orientations perpendicular to the (211)/(020) and (311) planes prepared using stainless steel as substrate presents the capacity of 4.9 μAh•cm-2 and the apparent activation energy of 59.2 kJ•mol-1, indicating its great potential to be used as cathode material for lithium thin film batteries.


Pb Thin Films On Si(111): Local Density Of States And Defects, Stefan Eilers, Yi Du, S X. Dou Jan 2014

Pb Thin Films On Si(111): Local Density Of States And Defects, Stefan Eilers, Yi Du, S X. Dou

Australian Institute for Innovative Materials - Papers

Local density of states and atomic structure of the stripped incommensurate phase, the √3 x√7 phase and the 1 x 1 phase of a monolayer of Pb on Si(111) are characterized by scanning tunneling microscopy and spectroscopy. The dI/dV-images reveal congruent local density of states structures for the stripped incommensurate and the √3 x√ phase but suggest a hexagonal lattice of the local density of states for the 1x1 phase while the atomic structure consists of one more atom in the center of each hexagon. Vacancy defects and impurities show a depletion of local density of states for the stripped …


Biocompatible Ionic Liquid-Biopolymer Electrolyte Enabled Thin And Compact Magnesium Air Batteries, Xiaoteng Jia, Yang Yang, Caiyun Wang, Chen Zhao, R Vijayaraghavan, Douglas R. Macfarlane, Maria Forsyth, Gordon G. Wallace Jan 2014

Biocompatible Ionic Liquid-Biopolymer Electrolyte Enabled Thin And Compact Magnesium Air Batteries, Xiaoteng Jia, Yang Yang, Caiyun Wang, Chen Zhao, R Vijayaraghavan, Douglas R. Macfarlane, Maria Forsyth, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

With the surge of interest in miniaturized implanted medical devices (IMDs), implantable power sources with small dimensions and biocompatibility are in high demand. Implanted battery/supercapacitor devices are commonly packaged within a case that occupies a large volume, making miniaturization difficult. In this study, we demonstrate a polymer electrolyte-enabled biocompatible magnesium-air battery device with a total thickness of approximately 300 μm. It consists of a biocompatible polypyrrole-para(toluene sulfonic acid) cathode and a bioresorbable magnesium alloy anode. The biocompatible electrolyte used is made of choline nitrate (ionic liquid) embedded in a biopolymer, chitosan. This polymer electrolyte is mechanically robust and offers a …


Significant Tunability Of Thin Film Functionalities Enabled By Manipulating Magnetic And Structural Nano-Domains, Igor A. Golovchanskiy, Alexey V. Pan, Sergey A. Fedoseev, Michael Higgins Jan 2014

Significant Tunability Of Thin Film Functionalities Enabled By Manipulating Magnetic And Structural Nano-Domains, Igor A. Golovchanskiy, Alexey V. Pan, Sergey A. Fedoseev, Michael Higgins

Australian Institute for Innovative Materials - Papers

The influence of laser frequency on the structure and physical properties of thin films grown by pulsed laser deposition has been studied. Different types of thin films, hard ferromagnetic FePt L10 and quasi-single crystal superconducting YBa2Cu3O7 (YBCO), have been used for demonstration of the effect. Significant structural modifications have been obtained for the films with similar thicknesses. These modifications are shown to dramatically control their corresponding properties, providing an instrumental ability for tuning the practical characteristics of the films by changing the laser frequency of their deposition. In particular, 20-fold increase of coercive field and modification of demagnetization mechanism are …