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The Effect Of Depositional Environment And Early Marine Diagenesis On Carbonate-Associated Sulfate, Jocelyn Ann Richardson
The Effect Of Depositional Environment And Early Marine Diagenesis On Carbonate-Associated Sulfate, Jocelyn Ann Richardson
Arts & Sciences Electronic Theses and Dissertations
The long-term redox state of Earth’s surface environments is governed by the relative burial proportions of redox-sensitive carbon and sulfur species throughout geologic time. The sulfur isotopic signature of seawater sulfate (δ34SSO4) traces the relative proportions of sulfur buried as sulfide (commonly pyrite) and sulfate (as evaporites, barite or carbonate-associated sulfate) and weathering source to the ocean. Thus, δ34SSO4 is a powerful tool to understand the evolution of redox conditions and the marine biogeochemical sulfur cycle. Due to the spatial and temporal extent of carbonates in the rock record, carbonate-associated sulfate (δ34SCAS) is a common proxy for the isotopic composition …
The Late Ordovician Biogeochemical Carbon Cycle, John Garrecht Metzger
The Late Ordovician Biogeochemical Carbon Cycle, John Garrecht Metzger
Arts & Sciences Electronic Theses and Dissertations
The isotopic composition of the carbonate carbon (δ13Ccarb) is one of the best tools for understanding the biogeochemical carbon cycle through Earth history. δ13Ccarb is also used to chemostratigraphically correlate coeval strata. This dissertation has three main foci that all utilize δ13Ccarb as the common data type. The geologic interval investigated was the Late Ordovician (458-444 Ma) with emphasis on the Guttenberg δ13C excursion, a globally correlated, positive ~3 / event that is ~400 kyr in duration. In the first topic we evaluate post-depositional alteration (i.e., diagenesis) of δ13Ccarb signals. In the second topic, we make reconstructions of sea level …