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Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

Wright State University

2017

Geochemistry

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Full-Text Articles in Physical Sciences and Mathematics

Removal Of Select Chlorinated Hydrocarbons By Nanoscale Zero-Valent Iron Supported On Powdered Activated Charcoal, Md Abu Raihan Chowdhury Jan 2017

Removal Of Select Chlorinated Hydrocarbons By Nanoscale Zero-Valent Iron Supported On Powdered Activated Charcoal, Md Abu Raihan Chowdhury

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Nanoscale Zero Valent Iron (NZVI) has shown limited effectiveness in degrading chlorinated hydrocarbons (CHCs), like 1,1,1-Trichloroethane (1,1,1-TCA) and Trichloroethene (TCE), in aqueous solution. A rapid agglomeration behavior of NZVI particles due to van der waals and magnetic forces can negatively impact its overall effectiveness due to increase in particle size, and decline in CHC degradation kinetics. Different support materials, such as clays and activated carbon, have been used to stabilize NZVI particle and reduce agglomeration in aqueous solution. In this bench-scale study, NZVI supported on Powdered Activated Charcoal (PAC) was selected to prepare a composite, called PAC/NZVI, for a more …


Hydrothermal Atomic Force Microscopy Investigation Of Barite Growth: The Role Of Spectator Ions In Elementary Step Edge Growth Kinetics And Hillock Morphology, Sarah A. Jindra Jan 2017

Hydrothermal Atomic Force Microscopy Investigation Of Barite Growth: The Role Of Spectator Ions In Elementary Step Edge Growth Kinetics And Hillock Morphology, Sarah A. Jindra

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To better understand the role of spectator ions in barite growth, the kinetics of step edge growth on barite (001) surfaces were studied under various salt solutions. Hydrothermal Atomic Force Microscopy (HAFM) was used to investigate the effect of background electrolytes (NaCl, NaBr and NaNO3) as a function of saturation index and ionic strength (I) on barite growth sourced at dislocations at 108 oC. Results show that hillock morphology is affected by I, as well as type of anion, where the prevalence of steps aligned on the [010] direction is highest under Cl- …


Hydrothermal Atomic Force Microscopy Investigation Of Barite Growth: The Role Of Spectator Ions In Elementary Step Edge Growth Kinetics And Hillock Morphology, Sarah A. Jindra Jan 2017

Hydrothermal Atomic Force Microscopy Investigation Of Barite Growth: The Role Of Spectator Ions In Elementary Step Edge Growth Kinetics And Hillock Morphology, Sarah A. Jindra

Browse all Theses and Dissertations

To better understand the role of spectator ions in barite growth, the kinetics of step edge growth on barite (001) surfaces were studied under various salt solutions. Hydrothermal Atomic Force Microscopy (HAFM) was used to investigate the effect of background electrolytes (NaCl, NaBr and NaNO3) as a function of saturation index and ionic strength (I) on barite growth sourced at dislocations at 108 oC. Results show that hillock morphology is affected by I, as well as type of anion, where the prevalence of steps aligned on the [010] direction is highest under Cl- There is a modest increase in kinetic …