Physical Sciences and Mathematics Commons^™

Degradation Of Trichloroethene By Radicals Produced By Oxygenation Of Various Reduced Iron Minerals, Jonathon Michael Deeter

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Fe(II)-containing minerals (often as oxides and sulfides) are commonly present in the shallow subsurface and aquifers. Recent studies have shown that Fe(II) can generate reactive oxygen species upon oxygenation. This bench-scale investigation examined the generation of radical species from [Fe(II)]-containing mineral phases when exposed to oxygen. The Fe(II)-minerals in this study were chemically-reduced hydrous ferric oxide (HFO) and goethite, magnetite, and mackinawite (FeS). This research demonstrated that trichloroethene (TCE) can rapidly degrade by radicals produced from Fe(II)-containing oxides if gaseous oxygen is introduced in reactors. In contrast, there was little or no TCE degradation from oxygenation of freshly-prepared ferrous sulfide …

Paradoxical Behavior In Groundwater Levels In Response To Precipitation Events, Alexandra Shelters

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Groundwater levels are expected to fluctuate with precipitation, rising when precipitation increases and falling when it decreases. However, observations often show that groundwater levels rise in months when precipitation has decreased from the previous month, or alternately, falls in months when precipitation has increased from the previous month. Such paradoxical behavior is documented in a 30-year record for a monitoring well in southwestern Ohio. This record was analyzed to evaluate the hypothesis that mass balance controls the change in groundwater level such that changes cannot be predicted solely from monthly changes in precipitation. Though precipitation may vary from one month …

Linking The Variance Of Permeability And Porosity To Newly Interpreted Lithofacies At The Site Of The Illinois Basin - Decatur Project, Decatur, Illinois, Ritu Chaity Ghose

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For effective geological sequestration of CO_2, it is critical to understand the processes associated with CO_2 movement and trapping in reservoirs, which requires a proper understanding of a diverse set of heterogeneous geologic properties. A highly-resolved data set from the Cambrian lower Mt. Simon sandstone reservoir (Unit A) in Decatur, Illinois, was used in a new approach to analyzing the variance of permeability and porosity. Newly interpreted bedding types, along with other factors, including grain size, and presence of bleached alterations, were considered in the analysis of variance. The results reveal that the factors contributing most to the sample variance …

Atmospheric Effects On Radar/Ladar Detection Of Seismic Activity, Michelle Frances Via

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This thesis investigates how well ground vibrations can be detected at ladar or radar wavelengths and how the atmosphere may impact the observation of such activity. First understanding atmospheric hindrances at each of these wavelengths is helpful to prioritize by those yielding best transmission results. A prerequisite to the outdoor field experiment performed for this study involves analyzing atmospheric effects characterization at six probable wavelengths using the Laser Environmental Effects Definition and Reference tool (LEEDR) developed by the Air Force Institute of Technology's (AFIT) Center for Directed Energy (CDE). These wavelengths, selected from the shortwave infrared and microwave portions of …

Processing And Interpretation Of Illinois Basin Seismic Reflection Data, Katherine M. Gigandet

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An anonymous oil company released 2D dynamite reflection data from the Illinois basin to be reprocessed and interpreted by Wright State University. The aim of the project is to exhaustively apply different seismic processing methods to the data to determine if any improvement in the imaging and interpretation may be accomplished. The data interpretation procedure convolved extracted wavelets from the final migrated section with reflectivity calculated from well log data provided. Once major formation tops were identified attribute analysis was applied to locate potential oil volumes of interest.

The raw shot records from this impulse data are dominated by guided …