Physical Sciences and Mathematics Commons^™

Pfas Mass Balance, Donovan Vitale

Honors Theses

First-generation, PFOS-dominant Aqueous Film Forming Foam (AFFF) concentrate of approximately 200 gallons was released to the sewer system from the Kalamazoo/Battle Creek International Airport on March 30, 2021. The AFFF release migrated to the Kalamazoo Water Reclamation Plant (KWRP), raising plant effluent above the Department of Environment, Great Lakes, and Energy (EGLE) PFOS water quality standard for a total of 46 days post-spill, although the influent concentrations exhibited sharp declines after only 7 days. By sampling influent, effluent, and biosolids daily, the only known long duration, high-frequency PFAS data set of an accidental AFFF release was generated. This study has …

Active Vs Passive Investing, Garret Buchheit

Honors Theses

With the increased popularity of passive investing, the long-term investment success of active management is being questioned more frequently. For this reason, this research seeks to find whether actively managed funds produce sufficient returns that cover the fees and management costs associated with them. A comparative analysis was made with 5401 actively managed U.S. mutual funds and several common market indices over three, five, and ten-year time spans ranging from 2012 to 2021. Additionally, an analysis was made comparing active and passive management in the recessionary period of 2007 to 2009. Finally, analysis was conducted on annual holdings turnover rates …

Industry 4.0, Zachary Zeitler

Honors Theses

The ultimate goal of this project is to automate quality control processes on various machines which include 3D printers, welders, routers, CNCs, and more. Using the “Digital Twin” approach, we want to automate monitoring, data collection, data analysis, and corrective action. Our involvement begins with building a new piece of software that can perform two specific functions and collect data from cameras. We are not attempting to analyze the data, make corrective action, or design a final version of the physical attributes. Our software provides the user with the ability to capture an image set or a 3D scan and …

A View Into Secondary Education Mathematics, Thomas Krieger Jr.

Honors Theses

Teaching methods, and the effects they can have on students, are important to consider for a classroom because when teaching you should allow for every student to have an opportunity. Every student should feel encouraged in the classroom, however not every method may allow for that. An important task for a teacher is to find out how to reach their students in their classroom; be it adapting methods or choosing when to implement one item over another. This task differs with every student that enters the classroom as no student is the same. Every students’ differences stem from their academic …

Exploring The Effects Of Tree Roots On Infiltration Process, Nazife Onaral

Masters Theses

Effects of the root structures on soil infiltration dynamics are not clearly defined. Imaging the complex tree root structures and movement of water through the root ball is a challenging task to achieve without damaging the trees and roots by conventional methods. Commonly used methods are invasive, labor-intensive, and not easily accessible. Ground Penetrating Radar (GPR) has commonly been used to characterize soil profiles and it can be a reliable tool to map complex root structures with a novel high-resolution circular data collection technique. Electrical resistivity tomography (ERT) is another reliable geophysical method to image infiltration processes by the change …

“This Isn't Working For Me. Can We Do It A Different Way?" The Lived Experiences Of Geoscience Students With Learning Disabilities, Nina Morris

Masters Theses

The purpose of this exploratory qualitative study is to better understand the lived experiences of geoscience students with learning disabilities in their geoscience classes. Students with learning disabilities bring a unique perspective while also facing unique challenges in post-secondary education. In the literature, there is limited information on what support and teaching strategies are beneficial to this population. Undergraduate and graduate geoscience students who identify as having a learning disability from colleges and universities in the United States were recruited. Six students consented to participate in the study, and each completed a semi-structured interview. Semi-structured interviews were designed to prompt …

A Framework For Assessing The 4th Rank Dispersivity Tensor Under Anisotropic Axial Symmetries, Xiang Fan

Dissertations

Multi-dimensional expansion of the advection-dispersion equation necessitated the representation of dispersivity as a 4th rank tensor. This tensorial form of dispersivity has 81 terms in three-dimensions with a maximum of 36 independent terms that may be used to describe Fickian spreading of a dissolved contaminant plume according to intrinsic properties of a porous medium. The complexity of the 4th rank tensor has led to the common practice of simplifying the tensor to only 2 or 3 independent terms by assuming isotropic conditions, although isotropic porous media are uncommon in nature as many natural geologic systems exhibit pronounced anisotropy. A broad …

Remote Sensing Application For Landslide Detection: Monitoring Along Eastern Lake Michigan (Miami Park, Mi), Guzalay Sataer

Dissertations

I assessed the nature and spatial and temporal patterns of deformation over the Miami Park bluffs on the eastern margin of Lake Michigan and investigated the factors controlling its observed deformation. Our approach involved the following steps: (1) extracting bluff deformation rates (velocities along the line of sight of the satellite) using a stack of Sentinel-1A radar imagery in ascending acquisition geometry acquired between 2017 and 2021 and applying the Intermittent Small Baseline Subset (ISBAS) InSAR time series analysis method; (2) generating high-resolution (5 cm) elevation models and orthophotos from temporal unmanned aerial vehicle (UAV) surveys acquired in 2017, 2019, …

Kinetic And Structural Characterization Of Pseudooxynicotine Amine Oxidase From Pseudomonas Putida S16, Vishakha Choudhary

Masters Theses

Our laboratory has previously shown that nicotine oxidoreductase (NicA2), a member of the flavin-containing amine oxidase family, uses a cytochrome c protein (CycN) as its electron acceptor rather than characteristically accepted molecular oxygen. Within the Pseudomonas putida S16 genome, the nicA2 gene forms an operon with cycN and pseudooxynicotine amine oxidase (pnao), another flavin containing amine oxidase enzyme. The first two steps in the nicotine catabolism pathway are catabolized by NicA2 and Pnao. Through redox chemistry, NicA2 converts nicotine to pseudooxynicotine and Pnao converts pseudooxynicotine to 3-succinoylsemialdehyde-pyridine. In this thesis, we characterize the kinetic and structural properties of …

Probing The Equation Of State Of Neutron Stars With Heavy Ion Collisions, Om Bhadra Khanal

Dissertations

The equation of state (EOS) is a fundamental property of nuclear matter, important for studying the structure of systems as diverse as the atomic nucleus and the neutron star. Nuclear reactions, especially heavy-ion collisions in the laboratories, can produce the nuclear matter similar to those contained in neutron stars. The density and the momentum dependence of the EOS of asymmetric nuclear matter, especially the symmetry energy term, is widely unconstrained. Finding appropriate constrains, especially at higher densities of the nuclear matter, requires the development of new devices, new experimental measurements as well as advances in theoretical understanding of nuclear collisions …

Time-Dependent Photoionization Modeling Of Warm Absorbers In Active Galactic Nuclei, Dev Raj Sadaula

Dissertations

Warm absorber spectra are bound-bound and bound-free absorption features, seen in the X-ray and UV spectra from many active galactic nuclei (AGN). The widths and centroid energies of these features indicate they occur in outflowing gas moving with hundreds to thousands of km/s. Depending upon the energy and momentum of the outflow, it can affect the gas within the host galaxy. Thus, warm absorbers’ mass and energy budgets are of great interest. Estimates for these properties depend on models that connect the absorption features' observed strengths with the density, composition, and ionization state of the absorbing gas. Such models assume …

Studying The Synthesis Of 196Hg At Astrophysically Relevant Energies Through The Measurement Of Capture Reaction Cross-Sections Of (P, Γ) (P, N) And (P, Α) Reactions, Khushi Bhatt

Dissertations

Understanding the origin of all the chemical elements is an important question for the nuclear-astrophysics community. There are many unanswered questions like: What astrophysical events are responsible for the synthesis of what particular chemical elements? How many different elements were made in total? What is the abundance of each synthesized element? etc. Currently, scientists are largely depending upon theory and simulations to define nuclear and astrophysical reaction. This makes it critical to have accurate experimental nuclear physics data to input in astrophysical theoretical models. However, out of more than 20000 reactions involved in these calculations, only a very few are …

Evidence For An Early Saginaw Lobe Ice Retreat And Drainage Adjustments Across Southern Michigan, Usa, Nathan Erber

Dissertations

The Saginaw lobe of the Laurentide Ice Sheet (LIS), flowed out of Saginaw Bay, across Lower Michigan and into northern Indiana. As it retreated, the Saginaw lobe deposited the Sturgis moraine, a recessional moraine of the lobe in southern Michigan. Positioned to the west and east of the Saginaw lobe were the Lake Michigan and Huron-Erie lobes, respectively. These lobes retreated across the region asynchronously, with the Saginaw lobe retreating first. The asynchronous behavior of the lobes allowed for the Lake Michigan and Huron-Erie lobes to overprint and alter landscapes once occupied by the Saginaw lobe ice.

The Kalamazoo moraine, …

Characterization Of Mumian And Host Rock In Al-Amerat Cave, Oman., Sara Alqamshouai

Honors Theses

Mumian is a sticky black-brown material found in the Mumian cave in Wadi Al Mayh, Al Amerat, Oman. Mumian has been used for centuries as traditional medicine by the local Omani people. Though commonly ingested orally to resolve a variety of common ailments, very little is known about the Mumian material in terms of its chemical composition. The principle aim of this study is to characterize the Mumian and the host rock in terms of the mineralogy and chemical characteristics using a variety of analytic instruments, including XRD, NMR, FT-IR, XRF, and UV- VIS. A secondary goal of this study …

Mixture Of Functional Graphical Models, Qihai Liu

Dissertations

With the development of data collection technologies that use powerful monitoring devices and computational tools, many scientific fields are now obtaining more detailed and more complicatedly structured data, e.g., functional data. This leads to increasing challenges of extracting information from the large complex data. Making use of these data to gain insight into complex phenomena requires characterizing the relationships among a large number of functional variables. Functional data analysis (FDA) is a rapidly developing area of statistics for data which can be naturally viewed as a smooth curve or function. It is a method that changes the frame of data …

Mid To Late Neogene (5.9-3.7 Ma) Epeirogenic Uplift And Associated Ultramafic Volcanism, Canterbury Basin, New Zealand, Katherine Anne Dvorak

Dissertations

Cored marine sediments from Canterbury Basin Integrated Ocean Drilling Program (IODP) Expedition 317 shelf sites U1351, U1353, and upper slope Site U1352 have been resampled with emphasis on benthic foraminifera from the Late Eocene to Late Pliocene. These new data coupled with paleo water-depth and age data from the nearby Clipper-1 petroleum exploration well, are used to develop a 1-dimensional basin subsidence model for the Canterbury Basin. Our model indicates there was widespread epeirogenic uplift of 890  350m, in the mid-Neogene (5.9-3.7 million years ago), which took place during concomitant ultramafic volcanism. Close association of uplift and volcanism could …

Analysis Of The Zebrafish Olfactory System Using Immunohistochemistry And Enhanced Techniques Of Desorption Electrospray Ionization Mass Spectrometry (Desi-Ms), Tara Lynn Maser

Dissertations

Desorption electrospray ionization (DESI-MS) is an ambient ionization technique where the sample is analyzed directly from a surface with very minimal sample preparation under ambient conditions and follows ESI-like ionization mechanisms. DESI-MS has proven powerful in analyzing or imaging lipids and other small molecules directly from biological samples and even allows for subsequent histological staining and analyses. However, DESI-MS is less widely used for protein analysis due to a lack of sensitivity and the complex diversity of proteins in biological samples.

A major goal of this research has been to obtain new neurobiological knowledge by combining histology and mass spectrometry …

Study Of Deexcitation Intensities To The K-Shell In Iron 55, Eric Helgemo

Honors Theses

55Fe radioactive sources are used for x-ray calibration due to the long half-lives of 2.73 years and the optimal energies of the peaks. The source used in the experiment was generated using Western Michigan University’s Tandem Van de Graff accelerator to produce a 6 MeV proton beam which induced a 55Mn(p, n)55Fe reaction on a 10 μm 55Mn target. The emissions from this target were then measured using a silicon lithium drift x-ray detector to determine the number of instances of deexcitation through kα and kβ modes. The preliminary data discussed showed a lower relative deexcitation rate of 6.67 between …

Autonomous Eco-Driving With Traffic Light And Lead Vehicle Constraints: An Application Of Best Constrained Interpolation, Yara Hazem Mohamed Mahmoud

Masters Theses

Eco-Driving is a critical technology for improving automotive transportation efficiency. It is achieved by modifying the driving trajectory over a particular route to minimize required propulsion energy. Eco-Driving can be approached as an optimal control problem subject to driving constraints such as traffic lights and positions of other vehicles. Best interpolation in a strip is a problem in approximation theory and optimal control. The solution to this problem is a cubic spline. In this research we demonstrate the connection between Eco-Driving and best interpolation in the strip. By exploiting this connection, we are able to generate optimal Eco-Driving trajectories that …

Unsupervised Learning With Word Embeddings Captures Quiescent Knowledge From Covid-19 And Materials Science Literature, Tasnim H. Gharaibeh

Dissertations

Millions of scientific papers are produced each year and the scientific literature is continuing to grow at a head-spinning speed. Thus, massive scientific knowledge exists in solid text, but all these publications make it difficult, if not impossible, for researchers to keep in up to date with discoveries, even within a narrow scientific area. This massive amount of information also makes it difficult to find implicit and hidden connections, relationships, and dependencies within the information that may guide the direction of future research or lead to valuable new insights. So, there is a need for algorithms or models that can …

Experimental Insights Into The Origin Of Microcrystalline Calcites, Mohammed Hashim

Dissertations

A significant proportion of modern marine calcium carbonate sediments is dominated by metastable aragonite and high Mg calcite that either dissolves or stabilizes to low-Mg-calcite (calcite) or dolomite during diagenesis. Sediment dissolution and stabilization have implications for the CaCO3 budget in the ocean and carbon burial rates. Yet, the diagenetic conditions that promote each process and their relative importance are poorly understood. Further, stabilization most commonly produces calcite microcrystals that exhibit various textures and host micropores. Despite their ubiquity in the rock record, the controls on microcrystal textures remain unclear. Here, laboratory experiments were used to investigate aragonite-to-calcite stabilization as …

Parallel Resource Defined Fitness Sharing: A Study On Parallel Optimizations For Niching Algorithms, Blayne A. Rogers

Masters Theses

The exploitation of niches by genetic algorithms (GAs) is a computationally expensive, but effective, methodology for solving complex open problems and real-world applications. Niching, differentiated on the modality of sharing, casts problems in terms of the specific resources available. These concepts arise from the broader natural algorithms that encapsulate the ideas and theories used in artificial intelligence. In remediating the computational costs, a study on exploiting niche-defined parallel structures is performed in the contest of the resourcedefined fitness sharing (RFS) algorithm.

Sharing is a natural algorithm paradigm that emulates the use of resources within an environment or population. Defining these …

Instructor Selection And Use Of Virtual Field Experiences In College Geoscience Course, Kristen Foley

Masters Theses

Virtual Field Experiences (VFEs) are a growing supplement and gateway to traditional fieldwork in the geosciences. With VFEs becoming more accepted for use in college geoscience courses, how instructors find and choose VFEs for their students is critical to creating greater accessibility and future resources. VFEs that are not easily accessed by instructors may go unused, and the effort put into making them would have been wasted. This phenomenological descriptive study utilized five focus groups of college geoscience instructors in the United States. Each 1-to-1.5-hour focus group session of 3-7 participants took place on video conferencing software, which was recorded …

Irregular Orbital Domination In Graphs, Peter E. Broe

Dissertations

In recent decades, domination in graphs has become a popular area of study due in large degree to its applications to modern society and the mathematical beauty of the topic. While this area evidently began with the work of Claude Berge in 1958 and of Oystein Ore in 1962, domination did not become an active area of research until 1977 with the appearance of a survey paper by Ernest Cockayne and Stephen Hedetniemi. Since then a large number of variations of domination have surfaced and provided numerous applications to different areas of science and real-life problems. Among these variations are …

Management Of Data Brokers In Support Of Smart Community Applications, Shadha Tabatabai

Dissertations

The widespread use of smart devices has led to the Internet of Things (IoT) revolution. Big data generated by billions of devices must be analyzed to make better decisions. However, this introduces security, communication, and processing problems. To solve these problems, we develop algorithms to enhance the work of brokers. We focus our efforts on three problems.

In the first problem, brokers are used in the cloud along with Software Defined Network (SDN) switches. We formulate minimizing brokers’ load difference within a reconfiguration budget with the constraint of indivisible topics as an Integer Linear Programming (ILP) problem. We show that …

A Remote Sensing And Machine Learning-Based Approach To Forecast The Onset Of Harmful Algal Bloom (Red Tides), Moein Izadi

Dissertations

In the last few decades, harmful algal blooms (HABs, also known as “red tides”) have become one of the most detrimental natural phenomena all around the world especially in Florida’s coastal areas due to local environmental factors and global warming in a larger scale. Karenia brevis produces toxins that have harmful effects on humans, fisheries, and ecosystems. In this study, I developed and compared the efficiency of state-of-the-art machine learning models (e.g., XGBoost, Random Forest, and Support Vector Machine) in predicting the occurrence of HABs. In the proposed models, the K. brevis abundance is used as the target, and 10 …