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Full-Text Articles in Physical Sciences and Mathematics

Equatorial Thermospheric Wind Changes During The Solar Cycle: Measurements At Arequipa,Peru From 1983 To 1990, M. A. Biondi, J. W. Meriwether, Bela G. Fejer, S. A. Gonzalesz, D. C. Hallenbeck Sep 1991

Equatorial Thermospheric Wind Changes During The Solar Cycle: Measurements At Arequipa,Peru From 1983 To 1990, M. A. Biondi, J. W. Meriwether, Bela G. Fejer, S. A. Gonzalesz, D. C. Hallenbeck

Bela G. Fejer

Fabry-Perot interferometer measurements of Doppler shifts in the nightglow 630-nm emission line have been used to determine near-equatorial thermospheric wind velocities at Arequipa, Peru, over ∼2/3 of a solar cycle. Monthly-average nocturnal variations in the meridional and zonal wind components were calculated from the nightly data to remove short term (day-to-day) variability, facilitating display of seasonal changes in the wind patterns, as well as any additional changes introduced by the progression of the solar cycle. The measured seasonal variations in the wind patterns are more pronounced than the solar cycle variations and are more readily understandable in terms of the …


Average Vertical And Zonal F-Region Plasma Drifts Over Jicamarca, Bela G. Fejer, E. R. De Paula, S. Gonzalez, R. F. Woodman Aug 1991

Average Vertical And Zonal F-Region Plasma Drifts Over Jicamarca, Bela G. Fejer, E. R. De Paula, S. Gonzalez, R. F. Woodman

Bela G. Fejer

The seasonal averages of the equatorial F region vertical and zonal plasma drifts are determined using extensive incoherent scatter radar observations from Jicamarca during 1968–1988. The late afternoon and nighttime vertical and zonal drifts are strongly dependent on the 10.7-cm solar flux. We show that the evening prereversal enhancement of vertical drifts increases linearly with solar flux during equinox but tends to saturate for large fluxes during southern hemisphere winter. We examine in detail, for the first time, the seasonal variation of the zonal plasma drifts and their dependence on solar flux and magnetic activity. The seasonal effects on the …


Ab Initio Study Of The Intermolecular Potential Of Ar–H2o, G. Chalasinski, M. M. Szczesniak, Steve Scheiner Jan 1991

Ab Initio Study Of The Intermolecular Potential Of Ar–H2o, G. Chalasinski, M. M. Szczesniak, Steve Scheiner

Steve Scheiner

The combination of supermolecular Møller–Plesset treatment with the perturbation theory of intermolecular forces is applied in the analysis of the potential‐energy surface of Ar–H2O. The surface is very isotropic with the lowest barrier for rotation of ∼35 cm−1 above the absolute minimum. The lower bound for De is found to be 108 cm−1 and the complex reveals a very floppy structure, with Ar moving freely from the H‐bridged structure to the coplanar and almost perpendicular arrangement of the C2 –water axis and the Ar–O axis, ‘‘T‐shaped’’ structure. This motion is almost isoenergetic (energy change …


Ab Initio Study Of Intermolecular Potential Of H2o Trimer, G. Chalasinski, M. M. Szczesniak, P. Cieplak, Steve Scheiner Jan 1991

Ab Initio Study Of Intermolecular Potential Of H2o Trimer, G. Chalasinski, M. M. Szczesniak, P. Cieplak, Steve Scheiner

Steve Scheiner

Nonadditive contribution to the interaction energy in water trimer is analyzed in terms of Heitler–London exchange, SCF deformation, induction and dispersion nonadditivities. Nonadditivity originates mainly from the SCF deformation effect which is due to electric polarization. However, polarization does not serve as a universal mechanism for nonadditivity in water. In the double‐donor configuration, for example, the Heitler–London exchange contribution is the most important and polarization yields the wrong sign. Correlation effects do not contribute significantly to the nonadditivity. A detailed analysis of the pair potential is also provided. The present two‐body potential and its components are compared to the existing …


Theoretical Vibrational Study Of Fx...Nh3 (X=H, D, Li) Complexes, Y. Bouteiller, Z. Latajka, H. Ratajczak, Steve Scheiner Jan 1991

Theoretical Vibrational Study Of Fx...Nh3 (X=H, D, Li) Complexes, Y. Bouteiller, Z. Latajka, H. Ratajczak, Steve Scheiner

Steve Scheiner

This paper presents the first ab initio attempt to construct the stretching fundamentals νFX and νF...N (X=H, D, Li) in the FX...NH3 complexes taking into account the mechanical anharmonicity. A potential‐energy surface V(rFX,RF...N) grid was generated at the self‐consistent‐field and second‐order Møller–Plesset levels. The coefficients fitting the potential‐energy surface up to the fourth order have been used to compute the νFX and νF...N stretching modes. The vibrational problem is solved by means of a variational treatment which includes the effects of mechanical …


Effect Of Intermolecular Orientation Upon Proton Transfer Within A Polarizable Medium, Steve Scheiner, X. Duan Jan 1991

Effect Of Intermolecular Orientation Upon Proton Transfer Within A Polarizable Medium, Steve Scheiner, X. Duan

Steve Scheiner

Ab initio calculations are used to investigate the proton transfer process in bacteriorhodopsin. HN = CH2 serves as a small prototype of the Schiff base while HCOO- models its carboxylate-containing counterion and HO- the hydroxyl group of water of tyrosine, leading to the HCOO-.H+.NHCH2 and HO-.H+.NHCH2 complexes. In isolation, both complexes prefer a neutral pair configuration wherein the central proton is associated with the anion. However, the Schiff base may be protonated in the former complex, producing the HCOO-.+HNHCH2 ion pair, when …


Ion Irradiation Effects On Graphite With Scanning Tunneling Microscope, T. -C. Shen, R. T. Brockenbrough, J. R. Tucker, J. W. Lyding Jan 1991

Ion Irradiation Effects On Graphite With Scanning Tunneling Microscope, T. -C. Shen, R. T. Brockenbrough, J. R. Tucker, J. W. Lyding

T. -C. Shen

Scanning tunneling microscope is used to create local surface modifications by means of ion impact damage. Graphite has been used as a test case to demonstrate this local surface sputtering. Using 0.1-µs voltage pulse of - 30 to - 140 V applied to the sample in a rough vacuum of 10-2 Torr, a confined area of damage (typically about 100 Å in diameter) is usually obtained. The damaged area consists of several layers of terraces. Defects of the size of a few atoms can also be found. Electronic perturbations caused by defects can form superlattices with a spacing three times …


Competition Between Generic And Nongeneric Fronts Inenvelope Equations, James A. Powell, A. C. Newell, C. K. R. T. Jones Jan 1991

Competition Between Generic And Nongeneric Fronts Inenvelope Equations, James A. Powell, A. C. Newell, C. K. R. T. Jones

James A. Powell

Arguments are presented for understanding the selection of the speed and the nature of the fronts that join stable and unstable states on the supercritical side of first-order phase transitions. It is suggested that from compact support, nonpositive-definite initial conditions, observable front behavior occurs only when the asymptotic spatial structure of a trajectory in the Galilean ordinary differential equation (ODE) corresponds to the most unstable temporal mode in the governing partial differential equation (PDE). This selection criterion distinguishes between a "nonlinear" front, which has its origin in the first-order nature of the bifurcation, and a "linear" front. The nonlinear front …