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University of Wollongong

2013

Carbon

Articles 1 - 13 of 13

Full-Text Articles in Physical Sciences and Mathematics

Microwave Characterization Of Carbon Nanotube Yarns For Uwb Medical Wireless Body Area Networks, Syed Muzahir Abbas, Oya Sevimli, Michael C. Heimlich, Karu P. Esselle, B Kimiaghalam, Javad Foroughi, Farzad Safaei Jan 2013

Microwave Characterization Of Carbon Nanotube Yarns For Uwb Medical Wireless Body Area Networks, Syed Muzahir Abbas, Oya Sevimli, Michael C. Heimlich, Karu P. Esselle, B Kimiaghalam, Javad Foroughi, Farzad Safaei

Australian Institute for Innovative Materials - Papers

Carbon nanotube (CNT) yarns are novel CNT-based materials that extend the advantages of CNT from the nanoscale to macroscale applications. In this study, we have modeled CNT yarns as potential data transmission lines. Test structures have been designed to measure electrical properties of CNT yarns, which are attached to these test structures using gold paste. DC testing and microwave S-parameter measurements have been conducted for characterization. The observed frequency independent resistive behavior of the CNT yarn is a very promising indicator that this material, with its added values of mechanical resilience and thermal conductivity, could be invaluable for a range …


Polyamide 6/Multiwalled Carbon Nanotubes Nanocomposites With Modified Morphology And Thermal Properties, Nasir Mahmood, Mohammad Islam, Asad Hameed, Shaukat Saeed Jan 2013

Polyamide 6/Multiwalled Carbon Nanotubes Nanocomposites With Modified Morphology And Thermal Properties, Nasir Mahmood, Mohammad Islam, Asad Hameed, Shaukat Saeed

Australian Institute for Innovative Materials - Papers

Pure polyamide 6 (PA6) and polyamide 6/carbon nanotube (PA6/CNT) composite samples with 0.5 weight percent loading of pristine or functionalized CNTs were made using a solution mixing technique. Modification of nanotube surface as a result of chemical functionalization was confirmed through the presence of lattice defects as examined under high-resolution transmission electron microscope and absorption bands characteristic of carboxylic, sulfonic and amine chemical groups. Microstructural examination of the cryogenically fractured surfaces revealed qualitative information regarding CNT dispersion within PA6 matrix and interfacial strength. X-ray diffraction studies indicated formation of thermodynamically more stable α-phase crystals. Thermogravimetric analysis revealed that CNT incorporation …


'Laser Chemistry' Synthesis, Physicochemical Properties, And Chemical Processing Of Nanostructured Carbon Foams, Andres Seral-Ascaso, Rosa Garriga, Maria Luisa Sanjuan, Joselito M. Razal, Ruth Lahoz, Mariano Laguna, German F. De La Fuente, Edgar Munoz Jan 2013

'Laser Chemistry' Synthesis, Physicochemical Properties, And Chemical Processing Of Nanostructured Carbon Foams, Andres Seral-Ascaso, Rosa Garriga, Maria Luisa Sanjuan, Joselito M. Razal, Ruth Lahoz, Mariano Laguna, German F. De La Fuente, Edgar Munoz

Australian Institute for Innovative Materials - Papers

Laser ablation of selected coordination complexes can lead to the production of metal-carbon hybrid materials, whose composition and structure can be tailored by suitably choosing the chemical composition of the irradiated targets. This 'laser chemistry' approach, initially applied by our group to the synthesis of P-containing nanostructured carbon foams (NCFs) from triphenylphosphine-based Au and Cu compounds, is broadened in this study to the production of other metal-NCFs and P-free NCFs. Thus, our results show that P-free coordination compounds and commercial organic precursors can act as efficient carbon source for the growth of NCFs. Physicochemical characterization reveals that NCFs are low-density …


Aqueous Dispersions Of Reduced Graphene Oxide And Multi Wall Carbon Nanotubes For Enhanced Glucose Oxidase Bioelectrode Performance, Willo Grosse, Joffrey Champavert, Sanjeev Gambhir, Gordon G. Wallace, Simon E. Moulton Jan 2013

Aqueous Dispersions Of Reduced Graphene Oxide And Multi Wall Carbon Nanotubes For Enhanced Glucose Oxidase Bioelectrode Performance, Willo Grosse, Joffrey Champavert, Sanjeev Gambhir, Gordon G. Wallace, Simon E. Moulton

Australian Institute for Innovative Materials - Papers

Aqueous dispersions of reduced graphene oxide (rGO) and multi walled carbon nanotubes (MWCNT) were fabricated through a modified chemical reduction method. The significant advantage of the method developed here is the omission of any stabilising compound or organic solvent to obtain stable rGO-MWCNT dispersions. Significantly biological entities, in this case the enzyme glucose oxidase (GOx), can be successfully incorporated into the dispersion. These dispersions were characterised using XPS, SEM, zeta potential and particle size measurements which showed that the dispersion stability is not sacrificed with the addition of GOx, and significantly, the electrical properties of the rGO and MWCNTs are …


Platinum Electrodeposition On Unsupported Single Wall Carbon Nanotubes And Its Application As Methane Sensing Material, Enid Contes-De Jesus, Diana Santiago, Gilberto Casillas, Alvaro Mayoral, Cesar Magen, Miguel Jose-Yacaman, Jing Li, Carlos R. Cabrera Jan 2013

Platinum Electrodeposition On Unsupported Single Wall Carbon Nanotubes And Its Application As Methane Sensing Material, Enid Contes-De Jesus, Diana Santiago, Gilberto Casillas, Alvaro Mayoral, Cesar Magen, Miguel Jose-Yacaman, Jing Li, Carlos R. Cabrera

Australian Institute for Innovative Materials - Papers

This paper reports the decoration of single wall carbon nanotubes (SWCNTs) with platinum (Pt) nanoparticles using an electrochemical technique, rotating disk slurry electrode (RoDSE). Pt/SWCNTs were electrochemically characterized by cyclic voltammetry technique (CV) and physically characterized through the use of transmission electron microscopy (TEM), energy dispersive spectroscopy - X-ray florescence (EDS-XRF) and X-ray diffraction (XRD). After characterization it was found that electrodeposited nanoparticles had an average particle size of 4.1 ± 0.8 nm. Pt/SWCNTs were used as sensing material for methane (CH4) detection and showed improved sensing properties in a range of concentration from 50 ppm to 200 ppm parts …


Facile Synthesis Of Reduced Graphene Oxide/Mwnts Nanocomposite Supercapacitor Materials Tested As Electrophoretically Deposited Films On Glassy Carbon Electrodes, Widsanusan Chartarrayawadee, Simon E. Moulton, Chee O. Too, Byung C. Kim, Rao Yepuri, Anthony C. Romeo, Gordon G. Wallace Jan 2013

Facile Synthesis Of Reduced Graphene Oxide/Mwnts Nanocomposite Supercapacitor Materials Tested As Electrophoretically Deposited Films On Glassy Carbon Electrodes, Widsanusan Chartarrayawadee, Simon E. Moulton, Chee O. Too, Byung C. Kim, Rao Yepuri, Anthony C. Romeo, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

This paper reports on a facile synthesis method for reduced graphene oxide (rGO)/multi-walled carbon nanotubes (MWNTs) nanocomposites. The initial step involves the use of graphene oxide to disperse the MWNTs, with subsequent reduction of the resultant graphene oxide/MWNTs composites using l-ascorbic acid (LAA) as a mild reductant. Reduction by LAA preserves the interaction between the rGO sheets and MWNTs. The dispersion-containing rGO/MWNTs composites was characterized and electrophoretically deposited anodically onto glassy carbon electrodes to form high surface area films for capacitance testing. Pseudo capacitance peaks were observed in the rGO/MWNTs composite electrodes, resulting in superior performance with capacitance values up …


Flexible Supercapacitors - Development Of Bendable Carbon Architectures, Zhiqiang Niu, Lili Liu, Peter C. Sherrell, Jun Chen, Xiaodong Chen Jan 2013

Flexible Supercapacitors - Development Of Bendable Carbon Architectures, Zhiqiang Niu, Lili Liu, Peter C. Sherrell, Jun Chen, Xiaodong Chen

Australian Institute for Innovative Materials - Papers

As energy storage devices, Supercapacitors (SCs), also known as electrochemical capacitors, possess high power densities, excellent reversibility and long cycle life. SCs could be applied to diverse fields including electric vehicles, pulse power applications and portable devices. Flexible SCs have attracted significant attention for powering recently developed portable, flexible and wearable electronics. During the past several years, a variety of bendable carbon-based electrode architechtures and flexible SC devices with different designs have been successfully prepared. In this review, we will describe recent developments in the preparation of such bendable carbon-based electrode architechtures and the subsequent design of flexible SC devices. …


Flexible Cellulose Based Polypyrrole-Multiwalled Carbon Nanotube Films For Bio-Compatible Zinc Batteries Activated By Simulated Body Fluids, Sha Li, Zai Ping Guo, Cai Yun Wang, Gordon G. Wallace, Hua-Kun Liu Jan 2013

Flexible Cellulose Based Polypyrrole-Multiwalled Carbon Nanotube Films For Bio-Compatible Zinc Batteries Activated By Simulated Body Fluids, Sha Li, Zai Ping Guo, Cai Yun Wang, Gordon G. Wallace, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

This work aims to develop biocompatible non-toxic materials for implantable bio-electronic cells. Polypyrrole (PPy)–carbon nanotube (CNT) composites with varied ratios of PPy to CNTs were chemically synthesized and used as cathodes with the support of cellulose paper. Zinc foil was used as the anode material due to its non-toxicity and moderate dissolution rate in aqueous solutions. Simulated body fluids (SBFs) with various protein concentrations were applied as electrolytes in this battery system. The PPy–CNT|Zn cell is capable of being discharged up to 24.5 hours at a current density of 60 μA cm−2 in a protein free SBF. The batteries …


Simply Mixed Commercial Red Phosphorus And Carbon Nanotube Composite With Exceptionally Reversible Sodium-Ion Storage, Wei-Jie Li, Shulei Chou, Jia-Zhao Wang, Hua-Kun Liu, S X. Dou Jan 2013

Simply Mixed Commercial Red Phosphorus And Carbon Nanotube Composite With Exceptionally Reversible Sodium-Ion Storage, Wei-Jie Li, Shulei Chou, Jia-Zhao Wang, Hua-Kun Liu, S X. Dou

Australian Institute for Innovative Materials - Papers

Recently, sodium ion batteries (SIBs) have been given intense attention because they are the most promising alternative to lithium ion batteries for application in renewable power stations and smart grid, owing to their low cost, their abundant natural resources, and the similar chemistry of sodium and lithium. Elemental phosphorus (P) is the most promising anode materials for SIBs with the highest theoretical capacity of 2596 mA h g-1, but the commercially available red phosphorus cannot react with Na reversibly. Here, we report that simply hand-grinding commercial microsized red phosphorus and carbon nanotubes (CNTs) can deliver a reversible capacity of 1675 …


Carbon Nanotube-Reduced Graphene Oxide Composites For Thermal Energy Harvesting Applications, Mark S. Romano, Na Li, Dennis Antiohos, Joselito M. Razal, Andrew Nattestad, Stephen Beirne, Shaoli Fang, Yongsheng Chen, Rouhollah Jalili, Gordon G. Wallace, Ray Baughman, Jun Chen Jan 2013

Carbon Nanotube-Reduced Graphene Oxide Composites For Thermal Energy Harvesting Applications, Mark S. Romano, Na Li, Dennis Antiohos, Joselito M. Razal, Andrew Nattestad, Stephen Beirne, Shaoli Fang, Yongsheng Chen, Rouhollah Jalili, Gordon G. Wallace, Ray Baughman, Jun Chen

Australian Institute for Innovative Materials - Papers

By controlling the SWNT-rGO electrode composition and thickness to attain the appropriate porosity and tortuosity, the electroactive surface area is maximized while rapid diffusion of the electrolyte through the electrode is maintained. This leads to an increase in exchange current density between the electrode and electrolyte which results in enhanced thermocell performance.


Nanocomposites Of Silicon And Carbon Derived From Coal Tar Pitch: Cheap Anode Materials For Lithium-Ion Batteries With Long Cycle Life And Enhanced Capacity, Yun-Xiao Wang, Shulei Chou, Hua-Kun Liu, S X. Dou Jan 2013

Nanocomposites Of Silicon And Carbon Derived From Coal Tar Pitch: Cheap Anode Materials For Lithium-Ion Batteries With Long Cycle Life And Enhanced Capacity, Yun-Xiao Wang, Shulei Chou, Hua-Kun Liu, S X. Dou

Australian Institute for Innovative Materials - Papers

From energy and environmental consideration, an industrial waste product, coal tar pitch (CTP), is used as the carbon source for Si/AC composite. We exploited a facile sintering method to largely scale up Si/amorphous carbon nanocomposite. The composites with 20 wt.% silicon with PVdF binder exhibited stable lithium storage ability for prolonged cycling. The composite anode delivered a capacity of 400.3 mAh g−1 with a high capacity retention of 71.3% after 1000 cycles. Various methods are used to investigate the reason for the outstanding cyclability. The results indicate that the silicon nanoparticles are wrapped by amorphous SiOx and AC in Si/AC …


Co2 Capture And Gas Separation On Boron Carbon Nanotubes, Qiao Sun, Meng Wang, Zhen Li, Yingying Ma, Aijun Du Jan 2013

Co2 Capture And Gas Separation On Boron Carbon Nanotubes, Qiao Sun, Meng Wang, Zhen Li, Yingying Ma, Aijun Du

Australian Institute for Innovative Materials - Papers

Concern about the increasing atmospheric CO2 concentration and its impact on the environment has led to increasing attention directed toward finding advanced materials and technologies suited for efficient CO2 capture, storage and purification of clean-burning natural gas. In this letter, we have performed comprehensive theoretical investigation of CO2, N2, CH4 and H2 adsorption on B2CNTs. Our study shows that CO2 molecules can form strong interactions with B2CNTs with different charge states. However, N2, CH 4 and H2 can only form very weak interactions with B 2CNTs. Therefore, the study demonstrates B2CNTs could sever as promising materials for CO2 capture and …


Highly Uniform Tio2/Sno2/Carbon Hybrid Nanofibers With Greatly Enhanced Lithium Storage Performance, Zunxian Yang, Qing Meng, Zaiping Guo, Xuebin Yu, Tailiang Guo, Rong Zeng Jan 2013

Highly Uniform Tio2/Sno2/Carbon Hybrid Nanofibers With Greatly Enhanced Lithium Storage Performance, Zunxian Yang, Qing Meng, Zaiping Guo, Xuebin Yu, Tailiang Guo, Rong Zeng

Australian Institute for Innovative Materials - Papers

Highly uniform, relatively large area TiO2/SnO 2/carbon hybrid nanofibers were synthesized by a simple method based on thermal pyrolysis and oxidation of an as-spun titanium-tin/polyacrylonitrile nanoweb composite in an argon atmosphere. This novel composite features the uniform dispersion and encapsulation of highly uniform nanoscale TiO 2/SnO2 crystals in a porous carbon matrix. The high porosity of the nanofiber composite material, together with the conductive carbon matrix, enhanced the electrochemical performance of the TiO 2/SnO2/carbon nanofiber electrode. The TiO 2/SnO2/carbon nanofiber electrode displays a reversible capacity of 442.8 mA h g-1 for up to 100 cycles, and exhibits excellent rate capability. …