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Full-Text Articles in Physical Sciences and Mathematics

Microscopic Role Of Carbon On Mgb2 Wire For Critical Current Density Comparable To Nbti, Jung Ho Kim, Sangjun Oh, Yoon-Uk Heo, Satoshi Hata, Hiroaki Kumakura, Akiyoshi Matsumoto, Masatoshi Mitsuhara, Seyong Choi, Yusuke Shimada, Minoru Maeda, Judith Macmanus-Driscoll, S X. Dou Jan 2012

Microscopic Role Of Carbon On Mgb2 Wire For Critical Current Density Comparable To Nbti, Jung Ho Kim, Sangjun Oh, Yoon-Uk Heo, Satoshi Hata, Hiroaki Kumakura, Akiyoshi Matsumoto, Masatoshi Mitsuhara, Seyong Choi, Yusuke Shimada, Minoru Maeda, Judith Macmanus-Driscoll, S X. Dou

Australian Institute for Innovative Materials - Papers

Increasing dissipation-free supercurrent has been the primary issue for practical application of superconducting wires. For magnesium diboride, MgB2, carbon is known to be the most effective dopant to enhance high-field properties. However, the critical role of carbon remains elusive, and also low-field critical current density has not been improved. Here, we have undertaken malic acid doping of MgB2 and find that the microscopic origin for the enhancement of high-field properties is due to boron vacancies and associated stacking faults, as observed by high-resolution transmission electron microscopy and electron energy loss spectroscopy. The carbon from the malic acid almost uniformly encapsulates …


Ch4, Co, And H2o Spectroscopy For The Sentinel-5 Precursor Mission: An Assessment With The Total Carbon Column Observing Network Measurements, A Galli, A Butz, R A. Scheepmaker, O Hasekamp, J Landgraf, P Tol, D Wunch, N M. Deutscher, G C. Toon, P O. Wennberg, D W. T Griffith, I Aben Jan 2012

Ch4, Co, And H2o Spectroscopy For The Sentinel-5 Precursor Mission: An Assessment With The Total Carbon Column Observing Network Measurements, A Galli, A Butz, R A. Scheepmaker, O Hasekamp, J Landgraf, P Tol, D Wunch, N M. Deutscher, G C. Toon, P O. Wennberg, D W. T Griffith, I Aben

Faculty of Science - Papers (Archive)

The TROPOspheric Monitoring Instrument (TROPOMI) will be part of ESA’s Sentinel-5 Precursor (S5P) satellite platform scheduled for launch in 2015. TROPOMI will monitor methane and carbon monoxide concentrations in the Earth’s atmosphere by measuring spectra of back-scattered sunlight in the short-wave infrared (SWIR).


Enhanced Hydrogen Storage Properties Of Naalh4 Co-Catalysed With Niobium Fluoride And Single-Walled Carbon Nanotubes, Jianfeng Mao, Zaiping Guo, Hua-Kun Liu Jan 2012

Enhanced Hydrogen Storage Properties Of Naalh4 Co-Catalysed With Niobium Fluoride And Single-Walled Carbon Nanotubes, Jianfeng Mao, Zaiping Guo, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

The effects of single-walled carbon nanotubes (SWCNTs) as a co-catalyst with NbF5 on the dehydrogenation and hydrogenation kinetics of NaAlH4 were investigated by X-ray diffraction, Fourier transform infrared spectroscopy, differential thermal analysis, temperature-programmed desorption, and isothermal hydrogen ab/desorption techniques. It has been revealed that there is a synergistic effect of SWCNTs and NbF5 on the de/rehydrogenation of NaAlH4, which improves the hydrogen de/absorption performance when compared to adding either SWCNTs or NbF5 alone. For example, the apparent activation energy for the first-step and the second-step dehydrogenation of the co-doped NaAlH4 sample is estimated to be 85.9 …


A Simple Route To Carbon Micro- And Nanorod Hybrid Structures By Physical Vapour Deposition, Jin Chu, Xiaoyan Peng, Ali Aldalbahi, Marc In Het Panhuis, Rafael Velazquez, Peter X. Feng Jan 2012

A Simple Route To Carbon Micro- And Nanorod Hybrid Structures By Physical Vapour Deposition, Jin Chu, Xiaoyan Peng, Ali Aldalbahi, Marc In Het Panhuis, Rafael Velazquez, Peter X. Feng

Faculty of Science - Papers (Archive)

Tilted well-aligned carbon micro- and nano-hybrid rods were synthesized on Si at different substrate temperatures and incident angles of carbon source beam using the hot filament physical vapour deposition technique. The morphologic surfaces, chemical compositions and bond structures of the oblique carbon rod-like structures were investigated by scanning electron microscopy, field emission scanning electron microscopy, transmission electron diffraction and Raman scattering spectroscopy. The field emission behaviour of the fabricated samples was also measured.


Power To You: Carbon Nanotube Muscles Are Going Strong, Geoffrey M. Spinks Jan 2012

Power To You: Carbon Nanotube Muscles Are Going Strong, Geoffrey M. Spinks

Australian Institute for Innovative Materials - Papers

Just on a year ago my colleagues and I announced our discovery that carbon nanotube yarns could be made to twist and rotate at great speeds when electrically stimulated. In this way we had created "artificial muscles" that could change their shape in response to stimulus.


Hollow Nitrogen Containing Core/Shell Fibrous Carbon Nanomaterials As Support To Platinum Nanocatalysts And Their Tem Tomography Study, Cuifeng Zhou, Zongwen Liu, Xusheng Du, David Rg Mitchell, Yiu-Wing Mai, Yushan Yan, Simon Peter Ringer Jan 2012

Hollow Nitrogen Containing Core/Shell Fibrous Carbon Nanomaterials As Support To Platinum Nanocatalysts And Their Tem Tomography Study, Cuifeng Zhou, Zongwen Liu, Xusheng Du, David Rg Mitchell, Yiu-Wing Mai, Yushan Yan, Simon Peter Ringer

Australian Institute for Innovative Materials - Papers

Core/shell nanostructured carbon materials with carbon nanofiber (CNF) as the core and a nitrogen (N)-doped graphitic layer as the shell were synthesized by pyrolysis of CNF/polyaniline (CNF/PANI) composites prepared by in situ polymerization of aniline on CNFs. High-resolution transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared and Raman analyses indicated that the PANI shell was carbonized at 900 degress C. Platinum (Pt) nanoparticles were reduced by formic acid with catalyst supports. Compared to the untreated CNF/ PANI composites, the carbonized composites were proven to be better supporting materials for the Pt nanocatalysts and showed superior performance as catalyst …


Free-Standing Single-Walled Carbon Nanotube/Sno2 Anode Paper For Flexible Lithium-Ion Batteries, Lukman Noerochim, Jia-Zhao Wang, Shulei Chou, David Wexler Jan 2012

Free-Standing Single-Walled Carbon Nanotube/Sno2 Anode Paper For Flexible Lithium-Ion Batteries, Lukman Noerochim, Jia-Zhao Wang, Shulei Chou, David Wexler

Australian Institute for Innovative Materials - Papers

Free-standingsingle-walledcarbonnanotube/SnO2 (SWCNT/SnO2) anodepaper was prepared by vacuum filtration of SWCNT/SnO2 hybrid material which was synthesized by the polyol method. From field emission scanning electron microscopy and transmission electron microscopy, the CNTs form a three-dimensional nanoporous network, in which ultra-fine SnO2 nanoparticles, which had crystallite sizes of less than 5 nm, were distributed, predominately as groups of nanoparticles on the surfaces of singlewalled CNT bundles. Electrochemical measurements demonstrated that the anodepaper with 34 wt.% SnO2 had excellent cyclic retention, with the high specific capacity of 454 mAh g−1 beyond 100 cycles at a current …


Irradiation Si On Carbon Nanotube Paper As A Flexible Anode Material For Lithium-Ion Batteries, Shulei Chou, Mihail Ionescu, Jia-Zhao Wang, Brad Winton, Hua-Kun Liu Jan 2012

Irradiation Si On Carbon Nanotube Paper As A Flexible Anode Material For Lithium-Ion Batteries, Shulei Chou, Mihail Ionescu, Jia-Zhao Wang, Brad Winton, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

Silicon single walled carbon nanotube composite paper was modified by low energy ion implantation using 5i to obtain a flexible composite paper. Raman and FE-SEM results show that structure of SWCNT could be destroyed by the implantation. Electrochemical measurements display that the implanted SI can improve the specific capacity and the reversible capacity of CNT paper. After 50 cycles, the specific capacity of 5Hmplanted CNT paper is 30 per cent higher than the pristine CNT.


Validation Of Iasi Forli Carbon Monoxide Retrievals Using Ftir Data From Ndacc, T Kerzenmacher, B Dils, N Kumps, T Blumenstock, C Clerbaux, P F. Coheur, P Demoulin, Omaira Garcia, M George, David W. Griffith, F Hase, J Hadji-Lazaro, D Hurtmans, Nicholas B. Jones, E Mahieu, Justus Notholt, Clare Paton-Walsh, U Raffalski, T Ridder, M Schneider, C Servais, M De Maziere Jan 2012

Validation Of Iasi Forli Carbon Monoxide Retrievals Using Ftir Data From Ndacc, T Kerzenmacher, B Dils, N Kumps, T Blumenstock, C Clerbaux, P F. Coheur, P Demoulin, Omaira Garcia, M George, David W. Griffith, F Hase, J Hadji-Lazaro, D Hurtmans, Nicholas B. Jones, E Mahieu, Justus Notholt, Clare Paton-Walsh, U Raffalski, T Ridder, M Schneider, C Servais, M De Maziere

Faculty of Science - Papers (Archive)

Carbon monoxide (CO) is retrieved daily and globally from space-borne IASI radiance spectra using the Fast Optimal Retrievals on Layers for IASI (FORLI) software developed at the Universit´e Libre de Bruxelles (ULB). The IASI CO total column product for 2008 from the most recent FORLI retrieval version (20100815) is evaluated using correlative CO profile products retrieved from groundbased solar absorption Fourier transform infrared (FTIR) observations at the following FTIR spectrometer sites from the Network for the Detection of Atmospheric Composition Change (NDACC): Ny-A° lesund, Kiruna, Bremen, Jungfraujoch, Iza˜na and Wollongong. In order to have good statistics for the comparisons, we …


Atmospheric Carbon Dioxide Retrieved From The Greenhouse Gases Observing Satellite (Gosat): Comparison With Ground-Based Tccon Observations And Geos-Chem Model Calculations, A Cogan, H Boesch, R Parker, L Feng, Paul Palmer, J-F Blavier, Nicholas M. Deutscher, Ronald Macatangay, Justus Notholt, C M. Roehl, Thorsten Warneke, Debra Wunch Jan 2012

Atmospheric Carbon Dioxide Retrieved From The Greenhouse Gases Observing Satellite (Gosat): Comparison With Ground-Based Tccon Observations And Geos-Chem Model Calculations, A Cogan, H Boesch, R Parker, L Feng, Paul Palmer, J-F Blavier, Nicholas M. Deutscher, Ronald Macatangay, Justus Notholt, C M. Roehl, Thorsten Warneke, Debra Wunch

Faculty of Science - Papers (Archive)

We retrieved column-averaged dry air mole fractions of atmospheric carbon dioxide (XCO 2) from backscattered short-wave infrared (SWIR) sunlight measured by the Japanese Greenhouse gases Observing SATellite (GOSAT). Over two years of XCO 2 retrieved from GOSAT is compared with XCO 2 inferred from collocated SWIR measurements by seven ground-based Total Carbon Column Observing Network (TCCON) stations. The average difference between GOSAT and TCCON XCO 2 for individual TCCON sites ranges from -0.87 ppm to 0.77 ppm with a mean value of 0.1 ppm and standard deviation of 0.56 ppm. We find an average bias between all GOSAT and TCCON …


Conducting Composite Materials From The Biopolymer Kappa-Carrageenan And Carbon Nanotubes, Ali Aldalbahi, Jin Chu, Peter Feng, Marc In Het Panhuis Jan 2012

Conducting Composite Materials From The Biopolymer Kappa-Carrageenan And Carbon Nanotubes, Ali Aldalbahi, Jin Chu, Peter Feng, Marc In Het Panhuis

Faculty of Science - Papers (Archive)

Conducting composite films containing carbon nanotubes (CNTs) were prepared by using the biopolymer kappa-carrageenan (KC) as a dispersant. Rheological studies indicated that 0.5% w/v was the appropriate KC concentration for dispersing CNTs. Our results showed that multiwalled nanotubes (MWNTs) required less sonic energy than single-walled nanotubes (SWNTs) for the dispersion process to be complete. Films prepared by vacuum filtration exhibited higher conductivity and improved mechanical characteristics compared to those prepared by evaporative casting. All composite films displayed sensitivity to water vapour, but MWNT films were more sensitive than SWNT films.


Electrical And Mechanical Characteristics Of Buckypapers And Evaporative Cast Films Prepared Using Single And Multi-Walled Carbon Nanotubes And The Biopolymer Carrageenan, Ali Aldalbahi, Marc In Het Panhuis Jan 2012

Electrical And Mechanical Characteristics Of Buckypapers And Evaporative Cast Films Prepared Using Single And Multi-Walled Carbon Nanotubes And The Biopolymer Carrageenan, Ali Aldalbahi, Marc In Het Panhuis

Faculty of Science - Papers (Archive)

The electrical and mechanical characteristics of composite materials prepared using evaporative casting and vacuum filtration of carbon nanotubes (CNTs) dispersed in the biopolymer s-carrageenan (IC) are reported. It is demonstrated that the contact angle of water with films is proportional to the CNT mass and volume fraction, which is used to compare the properties of buckypapers with those of evaporative cast films. Multi-walled carbon nanotube films were found to exhibit higher conductivity values compared to those observed for single-walled carbon nanotubes composites at comparable contact angle values up to true nanotube volume fraction of 0.12. Buckypapers prepared by varying the …