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University of Wollongong

Australian Institute for Innovative Materials - Papers

Series

2014

Composites

Articles 1 - 10 of 10

Full-Text Articles in Physical Sciences and Mathematics

Hydrostatic Piezoelectric Properties Of [011] Poled Pb(Mg 1/3nb2/3)O3-Pbtio3 Single Crystals And 2-2 Lamellar Composites, Lili Li, Shujun Zhang, Zhuo Xu, Xuecang Geng, Fei Wen, Jun Luo, Thomas R. Shrout Jan 2014

Hydrostatic Piezoelectric Properties Of [011] Poled Pb(Mg 1/3nb2/3)O3-Pbtio3 Single Crystals And 2-2 Lamellar Composites, Lili Li, Shujun Zhang, Zhuo Xu, Xuecang Geng, Fei Wen, Jun Luo, Thomas R. Shrout

Australian Institute for Innovative Materials - Papers

The hydrostatic piezoelectric properties of [011] poled Pb(Mg 1/3Nb2/3)O3-PbTiO3 (PMN-PT) crystals and corresponding 2-2 crystal/epoxy composites were investigated. The crystal volume ratio and compositional dependencies of the hydrostatic charge and voltage coefficients (dh and gh) and hydrostatic figure of merit (FOM) dh x gh were determined, where large FOM value of 3.2 pm2/N with high stability as a function of hydrostatic pressure was achieved for rhombohedral crystal composites. In addition, the stress amplification effects of the face-plate and different epoxy matrixes were investigated, with maximum FOM value being on the order of 92 pm2/N, indicating that 2-2 crystal/epoxy composites are …


High-Performance Sodium-Ion Batteries And Sodium-Ion Pseudocapacitors Based On Mos2/Graphene Composites, Yunxiao Wang, Shulei Chou, David Wexler, Hua-Kun Liu, S X. Dou Jan 2014

High-Performance Sodium-Ion Batteries And Sodium-Ion Pseudocapacitors Based On Mos2/Graphene Composites, Yunxiao Wang, Shulei Chou, David Wexler, Hua-Kun Liu, S X. Dou

Australian Institute for Innovative Materials - Papers

Sodium-ion energy storage, including sodium-ion batteries (NIBs) and electrochemical capacitive storage (NICs), is considered as a promising alternative to lithium-ion energy storage. It is an intriguing prospect, especially for large-scale applications, owing to its low cost and abundance. MoS2 sodiation/desodiation with Na ions is based on the conversion reaction, which is not only able to deliver higher capacity than the intercalation reaction, but can also be applied in capacitive storage owing to its typically sloping charge/discharge curves. Here, NIBs and NICs based on a graphene composite (MoS2/G) were constructed. The enlarged d-spacing, a contribution of the graphene matrix, and the …


Thermoelectric Performance Of N-Type (Pbte)0.75(Pbs)0.15(Pbse)0.1 Composites, Sima Aminorroaya Yamini, Heng Wang, Dianta Ginting, David R. G Mitchell, S X. Dou, G. Jeffrey Snyder Jan 2014

Thermoelectric Performance Of N-Type (Pbte)0.75(Pbs)0.15(Pbse)0.1 Composites, Sima Aminorroaya Yamini, Heng Wang, Dianta Ginting, David R. G Mitchell, S X. Dou, G. Jeffrey Snyder

Australian Institute for Innovative Materials - Papers

Lead chalcogenides (PbQ, Q = Te, Se, S) have proved to possess high thermoelectric efficiency for both n-type and p-type compounds. Recent success in tuning of electronic band structure, including manipulating the band gap, multiple bands, or introducing resonant states, has led to a significant improvement in the thermoelectric performance of p-type lead chalcogenides compared to the n-type ones. Here, the n-type quaternary composites of (PbTe)0.75(PbS)0.15(PbSe)0.1 are studied to evaluate the effects of nanostructuring on lattice thermal conductivity, carrier mobility, and effective mass variation. The results are compared with the similar ternary systems of (PbTe)1-x(PbSe)x, (PbSe) 1-x(PbS)x, and (PbS)1-x(PbTe)x. The …


Thermoelectric Performance Of Tellurium-Reduced Quaternary P-Type Lead-Chalcogenide Composites, Sima Aminorroaya Yamini, Heng Wang, Zachary M. Gibbs, Yanzhong Pei, David R. G Mitchell, S X. Dou, G. Jeffrey Snyder Jan 2014

Thermoelectric Performance Of Tellurium-Reduced Quaternary P-Type Lead-Chalcogenide Composites, Sima Aminorroaya Yamini, Heng Wang, Zachary M. Gibbs, Yanzhong Pei, David R. G Mitchell, S X. Dou, G. Jeffrey Snyder

Australian Institute for Innovative Materials - Papers

A long-standing technological challenge to the widespread application of thermoelectric generators is obtaining high-performance thermoelectric materials from abundant elements. Intensive study on PbTe alloys has resulted in a high figure of merit for the single-phase ternary PbTe-PbSe system through band structure engineering, and the low thermal conductivity achieved due to nanostructuring leads to high thermoelectric performance for ternary PbTe-PbS compounds. Recently, the single-phase p-type quaternary PbTe-PbSe-PbS alloys have been shown to provide thermoelectric performance superior to the binary and ternary lead chalcogenides. This occurs via tuning of the band structure and from an extraordinary low thermal conductivity resulting from high-contrast …


Microwave Autoclave Synthesized Multi-Layer Graphene/Single-Walled Carbon Nanotube Composites For Free-Standing Lithium-Ion Battery Anodes, Chao Zhong, Jia-Zhao Wang, David Wexler, Hua-Kun Liu Jan 2014

Microwave Autoclave Synthesized Multi-Layer Graphene/Single-Walled Carbon Nanotube Composites For Free-Standing Lithium-Ion Battery Anodes, Chao Zhong, Jia-Zhao Wang, David Wexler, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

Multi-layer graphene sheets have been synthesized by a time-efficient microwave autoclave method and used to form composites in situ with single-walled carbon nanotubes. The application of these composites as flexible free-standing film electrodes was then investigated. According to the transmission electron microscopy and X-ray diffraction characterizations, the average d-spacing of the graphene-single-walled carbon nanotube composites was 0.41 nm, which was obviously larger than that of the as-prepared pure graphene (0.36 nm). The reversible Li-cycling properties of the free-standing films have been evaluated by galvanostatic discharge-charge cycling and electrochemical impedance spectroscopy. Results showed that the free-standing composite film with 70 wt% …


Extrusion Printed Graphene/Polycaprolactone/ Composites For Tissue Engineering, Sepidar Sayyar, Rhys Cornock, Eoin Murray, Stephen Beirne, David L. Officer, Gordon G. Wallace Jan 2014

Extrusion Printed Graphene/Polycaprolactone/ Composites For Tissue Engineering, Sepidar Sayyar, Rhys Cornock, Eoin Murray, Stephen Beirne, David L. Officer, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

In this work fibres and complex three-dimensional scaffolds of a covalently linked graphene-polycaprolactone composite were successfully extruded and printed using a melt extrusion printing system. Fibres with varying diameters and morphologies, as well as complex scaffolds were fabricated using an additive fabrication approach and were characterized. It was found that the addition of graphene improves the mechanical properties of the fibres by over 50% and in vitro cytotoxicity tests showed good biocompatibility indicating a promising material for tissue engineering applications.


A Solvothermal Strategy: One-Step In Situ Synthesis Of Self-Assembled 3d Graphene-Based Composites With Enhanced Lithium Storage Capacity, Jingjing Ma, Jiulin Wang, Yu-Shi He, Xiao Zhen Liao, Jun Chen, Jiazhao Wang, Tao Yuan, Zi-Feng Ma Jan 2014

A Solvothermal Strategy: One-Step In Situ Synthesis Of Self-Assembled 3d Graphene-Based Composites With Enhanced Lithium Storage Capacity, Jingjing Ma, Jiulin Wang, Yu-Shi He, Xiao Zhen Liao, Jun Chen, Jiazhao Wang, Tao Yuan, Zi-Feng Ma

Australian Institute for Innovative Materials - Papers

A facile and controllable approach has been developed to synthesize three-dimensional (3D) graphene-based monoliths. Here, as a proof-of-concept experiment, self-assembled 3D CoO/graphene sheets (CoO/GS) composites with porous structures have been successfully fabricated in an ethanol medium by a one-step, in situ growth, solvothermal method. During the process, the in situ nucleation and growth of CoO particles on GS were tuned by the formation of a 3D GS network. In the as-prepared composites, the self-assembled 3D GS network around the CoO particles can not only provide a 3D conductive matrix, but also buffer the volume changes of CoO and restrain the …


Modeling Transport Properties Of Inhomogeneous Superconductor-Metal Composites, A Borroto, L Del Rio, M Arronte, Tom Johansen, E Altshuler Jan 2014

Modeling Transport Properties Of Inhomogeneous Superconductor-Metal Composites, A Borroto, L Del Rio, M Arronte, Tom Johansen, E Altshuler

Australian Institute for Innovative Materials - Papers

We propose a model for a superconductor-metal composite that allows to derive intrinsic transport properties of the superconducting phase based on 2D images of its cross section, and a minimal set of parameters. The method is tested experimentally by using, as model composite, a "transversal bridge" made on a Bi2Sr2Ca2Cu3O10+x (BSCCO)-Ag multi-filamentary tape. It is shown that the approach allows to predict the measured I−⟨E⟩ curves of the filaments. In addition, one can determine the critical current anisotropy between the longitudinal and transverse directions of the Ag-BSCCO tape, and also of …


Three-Dimensional Printing Fiber Reinforced Hydrogel Composites, Shannon Bakarich, Robert Gorkin Iii, Marc In Het Panhuis, Geoffrey M. Spinks Jan 2014

Three-Dimensional Printing Fiber Reinforced Hydrogel Composites, Shannon Bakarich, Robert Gorkin Iii, Marc In Het Panhuis, Geoffrey M. Spinks

Australian Institute for Innovative Materials - Papers

An additive manufacturing process that combines digital modeling and 3D printing was used to prepare fiber reinforced hydrogels in a single-step process. The composite materials were fabricated by selectively pattering a combination of alginate/acrylamide gel precursor solution and an epoxy based UV-curable adhesive (Emax 904 Gel-SC) with an extrusion printer. UV irradiation was used to cure the two inks into a single composite material. Spatial control of fiber distribution within the digital models allowed for the fabrication of a series of materials with a spectrum of swelling behavior and mechanical properties with physical characteristics ranging from soft and wet to …


One-Step Synthesis Of Graphene/Polypyrrole Nanofiber Composites As Cathode Material For A Biocompatible Zinc/Polymer Battery, Sha Li, Kewei Shu, Chen Zhao, Caiyun Wang, Zaiping Guo, Gordon G. Wallace, Hua-Kun Liu Jan 2014

One-Step Synthesis Of Graphene/Polypyrrole Nanofiber Composites As Cathode Material For A Biocompatible Zinc/Polymer Battery, Sha Li, Kewei Shu, Chen Zhao, Caiyun Wang, Zaiping Guo, Gordon G. Wallace, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

The significance of developing implantable, biocompatible, miniature power sources operated in a low current range has become manifest in recent years to meet the demands of the fast-growing market for biomedical microdevices. In this work, we focus on developing high-performance cathode material for biocompatible zinc/polymer batteries utilizing biofluids as electrolyte. Conductive polymers and graphene are generally considered to be biocompatible and suitable for bioengineering applications. To harness the high electrical conductivity of graphene and the redox capability of polypyrrole (PPy), a polypyrrole fiber/graphene composite has been synthesized via a simple one-step route. This composite is highly conductive (141 S cm …