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University of Wollongong

Australian Institute for Innovative Materials - Papers

Series

2014

Battery

Articles 1 - 7 of 7

Full-Text Articles in Physical Sciences and Mathematics

Three-Dimensional-Network Li3v2(Po4) 3/C Composite As High Rate Lithium Ion Battery Cathode Material And Its Compatibility With Ionic Liquid Electrolytes, Jiantie Xu, Shulei Chou, Cuifeng Zhou, Qinfen Gu, Hua-Kun Liu, S X. Dou Jan 2014

Three-Dimensional-Network Li3v2(Po4) 3/C Composite As High Rate Lithium Ion Battery Cathode Material And Its Compatibility With Ionic Liquid Electrolytes, Jiantie Xu, Shulei Chou, Cuifeng Zhou, Qinfen Gu, Hua-Kun Liu, S X. Dou

Australian Institute for Innovative Materials - Papers

A high performance Li3V2(PO4)3 cathode material for lithium ion batteries was synthesized by the microwave-assisted hydrothermal method followed by a post annealing process. The synchrotron X-ray diffraction analysis results confirmed that single-phase Li3V2(PO4)3 with monoclinic structure was obtained. Scanning electron microscope and transmission electron microscope images revealed that the as-prepared Li3V 2(PO4)3 was composed of nanowires and microsized particles. Electrochemical results demonstrated that the Li 3V2(PO4)3 electrode measured at 10 C after 500 cycles can deliver discharge capacities of 85.4 mAh g-1 and 103.4 mAh g-1, with a capacity retention of 99.3% and 95.9%, in the voltage ranges of 3.0-4.3 …


One-Step Synthesis Of Graphene/Polypyrrole Nanofiber Composites As Cathode Material For A Biocompatible Zinc/Polymer Battery, Sha Li, Kewei Shu, Chen Zhao, Caiyun Wang, Zaiping Guo, Gordon G. Wallace, Hua-Kun Liu Jan 2014

One-Step Synthesis Of Graphene/Polypyrrole Nanofiber Composites As Cathode Material For A Biocompatible Zinc/Polymer Battery, Sha Li, Kewei Shu, Chen Zhao, Caiyun Wang, Zaiping Guo, Gordon G. Wallace, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

The significance of developing implantable, biocompatible, miniature power sources operated in a low current range has become manifest in recent years to meet the demands of the fast-growing market for biomedical microdevices. In this work, we focus on developing high-performance cathode material for biocompatible zinc/polymer batteries utilizing biofluids as electrolyte. Conductive polymers and graphene are generally considered to be biocompatible and suitable for bioengineering applications. To harness the high electrical conductivity of graphene and the redox capability of polypyrrole (PPy), a polypyrrole fiber/graphene composite has been synthesized via a simple one-step route. This composite is highly conductive (141 S cm …


Soc Estimation For Lifepo4 Battery In Evs Using Recursive Least-Squares With Multiple Adaptive Forgetting Factors, Van Huan Duong, Hany A. Bastawrous, Kai Chin Lim, Khay Wai W. See, Peng Zhang, S X. Dou Jan 2014

Soc Estimation For Lifepo4 Battery In Evs Using Recursive Least-Squares With Multiple Adaptive Forgetting Factors, Van Huan Duong, Hany A. Bastawrous, Kai Chin Lim, Khay Wai W. See, Peng Zhang, S X. Dou

Australian Institute for Innovative Materials - Papers

This work presents a novel technique which is simple yet effective in estimating electric model parameters and state-of-charge (SOC) of the LiFePO4 battery. Unlike the well-known recursive least-squares-based algorithms with single constant forgetting factor, this technique employs multiple adaptive forgetting factors to provide the capability to capture the different dynamics of model parameters. The validity of the proposed method is verified through experiments using actual driving cycles.


Microwave Autoclave Synthesized Multi-Layer Graphene/Single-Walled Carbon Nanotube Composites For Free-Standing Lithium-Ion Battery Anodes, Chao Zhong, Jia-Zhao Wang, David Wexler, Hua-Kun Liu Jan 2014

Microwave Autoclave Synthesized Multi-Layer Graphene/Single-Walled Carbon Nanotube Composites For Free-Standing Lithium-Ion Battery Anodes, Chao Zhong, Jia-Zhao Wang, David Wexler, Hua-Kun Liu

Australian Institute for Innovative Materials - Papers

Multi-layer graphene sheets have been synthesized by a time-efficient microwave autoclave method and used to form composites in situ with single-walled carbon nanotubes. The application of these composites as flexible free-standing film electrodes was then investigated. According to the transmission electron microscopy and X-ray diffraction characterizations, the average d-spacing of the graphene-single-walled carbon nanotube composites was 0.41 nm, which was obviously larger than that of the as-prepared pure graphene (0.36 nm). The reversible Li-cycling properties of the free-standing films have been evaluated by galvanostatic discharge-charge cycling and electrochemical impedance spectroscopy. Results showed that the free-standing composite film with 70 wt% …


Enhanced Sodium-Ion Battery Performance By Structural Phase Transition From Two-Dimensional Hexagonal-Sns2 To Orthorhombic-Sns, Tengfei Zhou, Wei Kong Pang, Chaofeng Zhang, Jianping Yang, Zhixin Chen, Hua-Kun Liu, Zaiping Guo Jan 2014

Enhanced Sodium-Ion Battery Performance By Structural Phase Transition From Two-Dimensional Hexagonal-Sns2 To Orthorhombic-Sns, Tengfei Zhou, Wei Kong Pang, Chaofeng Zhang, Jianping Yang, Zhixin Chen, Hua-Kun Liu, Zaiping Guo

Australian Institute for Innovative Materials - Papers

Structural phase transitions can be used to alter the properties of a material without adding any additional elements and are therefore of significant technological value. It was found that the hexagonal-SnS2 phase can be transformed into the orthorhombic-SnS phase after an annealing step in an argon atmosphere, and the thus transformed SnS shows enhanced sodium-ion storage performance over that of the SnS2, which is attributed to its structural advantages. Here, we provide the first report on a SnS@graphene architecture for application as a sodium-ion battery anode, which is built from two-dimensional SnS and graphene nanosheets as complementary building blocks. The …


Cuo Single Crystal With Exposed {001} Facets-A Highly Efficient Material For Gas Sensing And Li-Ion Battery Applications, Dawei Su, Xiuqiang Xie, S X. Dou, Guoxiu Wang Jan 2014

Cuo Single Crystal With Exposed {001} Facets-A Highly Efficient Material For Gas Sensing And Li-Ion Battery Applications, Dawei Su, Xiuqiang Xie, S X. Dou, Guoxiu Wang

Australian Institute for Innovative Materials - Papers

Single crystal copper oxide nanoplatelets with a high percentage of {001} facets were synthesized by a facile hydrothermal approach. The as-prepared materials were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, field emission scanning electron microscopy, and high resolution transmission microscopy. Via density functional theory calculations, it was found that the {001} facets are active crystal planes. When the single crystal CuO nanoplatelets were applied as an anode material in Li-ion batteries, they demonstrated outstanding electrochemical performance with high lithium storage capacity, satisfactory cyclability, and excellent high rate capacity. When used as a sensing material in gas sensors, they exhibited …


A Novel Codoping Approach For Enhancing The Performance Of Polypyrrole Cathode In A Bioelectric Battery, Yang Yang, Caiyun Wang, Chunming Zhang, Dan Wang, Dannong He, Gordon G. Wallace Jan 2014

A Novel Codoping Approach For Enhancing The Performance Of Polypyrrole Cathode In A Bioelectric Battery, Yang Yang, Caiyun Wang, Chunming Zhang, Dan Wang, Dannong He, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

A conducting polymer (CP) based bioelectric battery provides a promising alternative to commercial lithium batteries to drive biomedical devices. However, the low power density limits practical application. Here, we synthesize a polypyrrole (PPy)/anthraquinone sulfonate (AQS)/reduced graphene oxide (r-GO) composite via a facile electrochemical route, and use this as a novel cathode material for bioelectric batteries. The presence of r-GO significantly enhanced the electrochemical properties of PPy and led to greatly improved cell performance compared to that of PPy/AQS. The resultant PPy/AQS/r-GO composite delivered a maximum power density of 6240.5 mW m(-2), 14.2 times higher than that of PPy/p-toluenesulfonate (pTS) as …