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Full-Text Articles in Physical Sciences and Mathematics
On The Path To Multi-Electron Redox Chemistry With Bimetallic Systems, Nathalie Metta
On The Path To Multi-Electron Redox Chemistry With Bimetallic Systems, Nathalie Metta
Open Access Theses & Dissertations
The following study is presented in two sections, in the first, a novel digold (II) complex with semi-bridging chlorides supported by two bulky formamidinates was synthesized for the purpose of studying late-transition metal multi-electron redox chemistry. Electrochemical analysis shows one non-reversible reduction. Although the electrochemistry of this complex is restricted, the compound shows interesting electronic properties. The crystal structure reveals a geometry distortion of the Au2ï?-Cl2 core. The coupling of an unoccupied orbital and an occupied orbital through a vibrational mode, causes a distortion in the geometry of the molecule lowering the D2h symmetry to C2h. This is an example …
Triphenylamine-, Porphyrin- And Fullerene-Based Derivatives For Photovoltaic And Other Applications, Danisha Marie Rivera Nazario
Triphenylamine-, Porphyrin- And Fullerene-Based Derivatives For Photovoltaic And Other Applications, Danisha Marie Rivera Nazario
Open Access Theses & Dissertations
Proper collection of charges at the electrodes is an important process in organic solar cells. Interfacial layers between the electrodes and the photoactive layer have been design to improve charge collection and ohmic contacts. The most studied interfacial layer between the anode and the photoactive layer is the negatively charged polymer poly(3,4-ethylendioxythiophene):poly(styrenesulfonate) (PEDOT:PSS), that possesses good hole transporting ability. However, inhomogeneities at the surface of the electrode after deposition of the polymer lower the stability and performance of the OPV devices. Triphenylamine (TPA) derivatives have received increased attention in the organic solar cells (OSCs) field because of their favorable light …
Elucidating The Electronic Structure Of Multiple Bonded Systems: Synthesis And Characterization Of Bimetallic Tungsten And Ruthenium Complexes, Karen Ventura
Open Access Theses & Dissertations
The following study is presented in two sections. In the first section variable-temperature magnetic and structural data of two pairs of diruthenium isomers (having an idealized D4h symmetry), one pair having axial ligands and the formula Ru2(DArF)4Cl (where DArF is the anion of a diarylformamidine isomer, and Ar = p-anisyl or m-anisyl) and the other one being essentially identical but devoid of axial ligands and having the formula [Ru2(DArF)4]BF4, show that the axial ligands have a significant effect on the electronic structure of the diruthenium core. Variable-temperature crystallographic and magnetic data as well as density functional theory (DFT) calculations unequivocally …