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Full-Text Articles in Physical Sciences and Mathematics
Studying Suspended Sediment Concentrations In The South Chickamauga Creek Of Chattanooga, Tn Using Satellite Imagery, Digital Image Processing, And Numeric Modeling, Abigail Faxon
Honors Theses
In recent years, Hamilton County, TN has experienced extensive urban growth. According to US Census data, Hamilton County welcomed more than 33,000 new residents in the last decade. There is increased concern about the environmental sustainability of Chattanooga’s urban growth because significant impervious surface development has taken place along the South Chickamauga Creek. This leaves the creek subject to increased urban runoff, which often carries sediments with different municipal pollutants. Thus, monitoring turbidity in the stream water is important to determine the sustainability of urban development in Chattanooga, TN. In this research, we have compared the viability of using different …
Theoretical Studies Of Benzoquinone Reactivity In Acidic And Basic Environments, Natali Majoras
Theoretical Studies Of Benzoquinone Reactivity In Acidic And Basic Environments, Natali Majoras
Honors Theses
Quinones are a class of organic compounds containing a six-membered unsaturated ring with two carbonyl groups. They are biologically relevant mostly due to their ability to participate in redox reactions. Prior experiments in our lab showed that quinones can induce protein modifications that are pH dependent. In an acidic environment the modifications were less significant than in a basic environment. Previous computational studies have also been carried out to model, in neutral solutions, the reaction between various quinones and various amines. Various amine groups are used as a model for the amino group of lysine to represent protein modification. The …
The Effects Of Dissolved And Suspended Solids On Freshwater Meiofauna, Jessica Cline
The Effects Of Dissolved And Suspended Solids On Freshwater Meiofauna, Jessica Cline
Honors Theses
Meiofauna include small-sized animals (< 1mm) distributed in all aquatic ecosystems on Earth, where they play fundamental trophic and ecological roles. The biodiversity of marine meiofauna and its links with anthropogenic activities is routinely investigated, however, freshwater communities are less known. This is particularly true for the Southeastern United States, which is greatly investigated and elected a hotspot of biodiversity for larger species but very little is known about the meiofauna. The purpose of this research is to reveal the biodiversity of meiofauna from the Tennessee River and test for potential correlations with anthropogenic activities. As a proxy for pollution, dissolved and suspended solids were considered in this study. The research hypothesis is that meiofaunal biodiversity would be affected by possible changes of dissolved and suspended solids in the water column. Possible mechanisms causing biodiversity shifts could be ascribed to osmotic stresses of animals to cope with variation in dissolved solids or, more indirectly, because different sunlight penetration caused by suspended solids would affect primary production. To test the hypothesis, water samples were collected from nine stations located along the Tennessee River in Hamilton County. Each station was visited three times, and, during each visit, environmental parameters (including dissolved and suspended solids) were measured. Meiofauna biodiversity (estimated as richness, community composition, and phylogenetic diversity) was revealed using a metagenomic approach. Statistical analyses were applied to test for possible correlations between the biodiversity estimates and the measured environmental parameters. Results show a high biodiversity of meiofauna with more than 200 amplicon-sequence variants distributed across 10 metazoan phyla. Environmental conditions are highly variable among stations and statistical analyses show that while both dissolved solids (TDS) and turbidity (suspended solids, NTU) did not significantly affect meiofauna biodiversity in the collected samples, various other water, and sediment metrics were found to be significant predictors of meiofauna biodiversity. In conclusion, the results of this project not only reveal for the first time the meiofauna biodiversity from the Tennessee River, but also suggest that meiofauna could be used as bioindicators for several anthropogenic activities in freshwater ecosystems.
Synthesis And Characterization Of Organometallic Complexes For Biological Imaging, Emily Stumbo
Synthesis And Characterization Of Organometallic Complexes For Biological Imaging, Emily Stumbo
Honors Theses
Luminescent transition metal complexes are of interest for biological imaging applications due to their unique photophysical properties including large Stokes shift, long fluorescence lifetimes, and tunable emission. Altering ligand structure is a useful way to manipulate the charge transfer (CT) and mixed character states that give these complexes their photophysical properties. A series of organometallic complexes containing ligands with externally facing nitrogens has been prepared and synthesized. Complexes of the form Pt (II)(tbbpy)(C2-py), Re(CO)3(N^N), Ir(C^N)2(N^N), and Ir(C^N)2(N^O) have been studied for their potential application as biological imaging agents. The goal of this project is to compare the properties of these …
The Impact Of Water Infrastructure Inequality On Marginalized Communities, Indra Khalsa
The Impact Of Water Infrastructure Inequality On Marginalized Communities, Indra Khalsa
Honors Theses
America’s current system of water infrastructure poses a threat not only to the environment but also to public health. The water crisis reveals the stark inequalities that exist from both an environmental justice and a social justice perspective. There is a growing concern that without adequate investment from federal resources, the problems related to this issue will only worsen the longer they are neglected. There is little information about how specific environmental and social factors combine with water infrastructure to create long-term infrastructure inequalities. However, this thesis explores the disparities in water infrastructure affordability, vulnerability patterns, and environmental hazards. It …