Physical Sciences and Mathematics Commons^™

Origin And Tectonic Evolution Of The Southern Appalachian Neoacadin Crystalline Core: Evidence From The Geology Of The Gilreath 7.5-Minute Quadrangle, North Carolina, Crystal Gayle Wilson

Masters Theses

Detailed geologic mapping of the Gilreath 7.5-minute quadrangle recognizes the northernmost continuation of the Brindle Creek fault, a terrane boundary that separates Neoproterozic-Ordovician metasedimentary and metavolcanic rocks of the western Tugaloo terrane (western Inner Piedmont) from Silurian-Devonian metasedimentary rocks and Devonian-Mississippian anatectic granitoids of the Cat Square terrane (eastern Inner Piedmont). The Brindle Creek fault is folded in the study area and exposes the Ordovician Brooks Crossroads Granite in a reentrant. Low high-field strength element concentrations and a flatter rare earth element patterns typical of western Inner Piedmont granitoids, support a footwall setting for the Brooks Crossroads Granite.

New geochemical …

Multiple Resolution Nonparametric Classifiers, David Laurence Beck

Masters Theses

Bayesian discriminant functions provide optimal classification decision boundaries in the sense of minimizing the average error rate. An operational assumption is that the probability density functions for the individual classes are either known a priori or can be estimated from the data through the use of estimating techniques. The use of Parzen- windows is a popular and theoretically sound choice for such estimation. However, while the minimal average error rate can be achieved when combining Bayes Rule with Parzen-window density estimation, the latter is computationally costly to the point where it may lead to unacceptable run-time performance. We present the …

Development Of Novel Synthetic Methods Utilizing Organometallic Reagents And Total Synthesis Of Eupomatilone 2, Chunlan Chen

Masters Theses

This dissertation summarizes the development of novel synthetic methods involving organometallic reagents and their application in the total synthesis of the natural product eupomatilone 2. These newly discovered reactions include the palladium-catalyzed cross-coupling of allyl acetates with organosiloxanes and the diastereoselective synthesis of cis- and trans-a-methylene-y-lactones utilizing Baylis-Hillman adducts as precursors. Another important aspect of the research is the application of some of the methods in total synthesis of eupomatilone 2.

The new synthetic methodologies involving organometallic reagents developed in this dissertation are important transformations in modern organic synthesis. Mild reaction conditions, tolerance of various organic functional groups, and high …

Neutron Diffraction Study Of Heavy Water Intercalation In Superconducting Deuterated Sodium Cobaltate Na0.35Coo21.4d2O, Cinzia Metallo

Masters Theses

When Na-deficient Na_xCoO₂ is intercalated with water¹ or heavy water², it becomes a superconductor. The maximum critical temperature of 4.5 K is found for the composition Na_xCoO₂yD₂O (x= 0.3 and y=1.4). In spite of its low transition temperature, several similarities with high temperature superconducting cuprates have raised interest in this compound. Nevertheless, up to now, a clear understanding of the role of water has not been achieved.

Since superconductivity appears only when water is inserted in the parent compound, the goal of this research work was to understand …

Photochemical Route To The Production Of Fullerene Allotropes, Olga Ovchinnikova

Masters Theses

A photochemical route to the formation of two C₆₀ molecules which are bridged by one and up to eighteen carbon atoms to form bucky-dumbbell shaped molecules, i.e., C₆₀ > C < C₆₀ to C₆₀ > C = C = C = C = C = C = C = C = C = C < C₆₀, etc. is described. Irradiation of C60 in solutions of chloroform and iodine (magenta color) with pulsed laser light from the frequency tripled (355 nm) Nd:YAG laser produced a dark crimson color. Matrix assisted laser desorption ionization (MALDI) negative ion mass spectroscopy was used to …

Petrogenesis Of Apollo 15 Olivine-Normative And Quartz-Normative Mare Basalts, Darren W. Schnare

Masters Theses

New data are presented for four Apollo 15 low-Ti mare basalts, two from the olivine-normative suite (15106, and 15555) and two from the quartz-normative suite (15475, and 15499). Previous studies have examined the relationships between these groups on the basis of whole-rock chemistry, many with analyses that may have been of insufficient sample-size, or of limited range of elements analyzed. To determine a relationship between these basalts, these samples have been analyzed for their mineral major-element and trace-element compositions by electron-microprobe and laser-ablation inductively-coupled-plasma mass-spectrometry, respectively.

The trace-element compositions of the main silicate phases, olivine, pyroxene, and plagioclase, are consistent …

Variational And Partial Differential Equation Models For Color Image Denoising And Their Numerical Approximations Using Finite Element Methods, Miun Yoon

Masters Theses

Image processing has been a traditional engineering field, which has a broad range of applications in science, engineering and industry. Not long ago, statistical and ad hoc methods had been main tools for studying and analyzing image processing problems. In the past decade, a new approach based on variational and partial differential equation (PDE) methods has emerged as a more powerful approach. Compared with old approaches, variational and PDE methods have remarkable advantages in both theory and computation. It allows to directly handle and process visually important geometric features such as gradients, tangents and curvatures, and to model visually meaningful …

Applications Of Mass Spectrometry To Synthetic Copolymers, Elizabeth Angela Stewart

Masters Theses

Over the last decade, application of mass spectrometry has grown immensely especially in polymer characterization. The focus of this thesis is to assess and extend the applicability of matrix-assisted laser desorption ionization mass spectrometry (MALDI MS) and electrospray ionization mass spectrometry (ESI MS) in the analysis of synthetic copolymers.

Characterization of a non-ionic copolymer was attempted. The copolymer was styrene-co-maleic anhydride, which is in a class of copolymers that are used for commercial applications where low viscosity, high polarity and/or high reactivity are needed. MALDI-TOF MS was employed to obtain weight and number average molecular weight values (M_w and …

Four-Dimensional Mvct Imaging And Spatial Translation Of Helical Tomotherapy Dose Distributions Using Sinogram Modification, Samuel Scott Outten

Masters Theses

Helical tomotherapy systems have the unique attribute of using sinograms as a machine input and a machine output. These sinograms have well understood properties that may allow for operational changes that simplify and/or improve radiation treatment.

In the first part of this work, the detector array output sinogram of an MVCT imaging study is used to produce images of an object at different locations along a pattern of motion and the multi-leaf collimator (MLC) control sinogram is used to translate dose distributions in space. A temporal re-binning algorithm was written that divided the MVCT sinogram projections into positional bins that …

Mechanisms For Increasing Respiratory Capacity Through Ontogeny In The Blastoid Genus Pentremites, Troy A. Dexter

Masters Theses

This study was conducted to determine how the hydrospires in blastoids (the respiratory channels through which blastoids respire) change in shape and capacity during ontogeny. As the volume of a blastoid increases ontogenetically, the respiratory capacity of the hydrospires must increase to match the additional respiratory requirements. Ontogenetically, volume increases at a cubic rate, therefore the surface area of the respiratory structures should increase at a similar rate. Using transverse cross sections of the theca through an ontogenetic series in two species of the blastoid Pentremites, the surface area and volume of the hydrospires was quantified. The data demonstrated …

Structural And Dynamical Studies Of Superacids And Superacidic Solutions Using Neutron And High Energy X-Ray Scattering, Jamie John Molaison

Masters Theses

The diffusive motions of the Brønsted superacid, hydrogen fluoride, have been studied using quasielastic neutron scattering. Neutron and high energy X-ray diffraction measurements on the Lewis superacid, antimony pentafluoride, are presented along with the results of three applied data models. Finally, structural information was obtained for a 9:1 FSO₃H:NH₃ solution using neutron diffraction with isotopic substitution and nuclear magnetic resonance.

Ultraviolet Image Analysis Of Spacecraft Exhaust Plumes, Karen L. Norton

Masters Theses

Data obtained during the April 26, 2000 MirEx experiment is used to infer the chemical mechanisms responsible for ultraviolet radiation observed to emanate from Russian spacecraft exhaust plumes in low Earth orbit. The principle objective of this experiment was to use the Mir Space Station instruments to study the plume collisional processes occurring in the rarified atmosphere of the far-field; at distances greater than one kilometer away from the spacecraft. This was accomplished by observing the automated Progress cargo ship as the auxiliary engines were being retrofired in a ram-burn configuration at 330 kilometers in altitude above Earth. The primary …

A Quantitative Study Of Scaling Properties Of Fracture Networks, Ankur Roy

Masters Theses

Fracture networks and their scaling properties are important from both an academic and practical perspective since they play a significant role in many areas ranging from crustal fluid flow to studies of earthquakes. Over the years, researchers have employed a wide variety of techniques to quantify the complexities of fractured media. These range from deterministic, process-based approaches employing the laws of physics, to ones involving the applications of geostatistics and more recently, fractal geometry. Fractals are irregular entities that show self-similarity over a wide range of scales and can be quantified by the fractal dimension, D. It is important …

Advantages Of “Function Domain Sets” Confidence Intervals Over Hypotheses Comparison Tests Of One Mean Residual Life (Mrl) Function Dominating An Improved Baseline And Of Two Mrl Functions Comparisons With Applications In Modern Engineered Composite Wood Products: One Sample And Two Sample Cases. Also Exploring General Theory, Insights, And Applications Of Mrl Functions, Jonathan Cody Steele

Masters Theses

In this thesis, we analyze mean residual life (MRL) functions and unique “function domain sets” confidence intervals to identify important opportunities for improving quality of medium density fiberboard (MDF). We stress these tools have tremendous potential for many other forest products (e.g., various composites, natural woods), not just MDF.

These “function domain sets” confidence intervals can assess variation in quality where one MRL function dominates an industrial baseline. Assessments of the internal bond of MDF illuminate opportunities for helpful improvements, plus perform valid statistical comparisons of different types of MDF. For example, these MRL methods detect a new, higher-valued MDF …

Coarse Structures And Higson Compactification, Christian Stuart Hoffland

Masters Theses

FOLLOWING John Roe in his Lectures on Coarse Geometry, we begin by describing the large-scale structure of metric spaces by means of coarse maps between them, those being maps which preserve distances at large scales. Using these techniques, we demonstrate that the real numbers and the integers have the same large scale structure--or are coarsely equivalent--but that the real line is coarsely equivalent to neither the Euclidean plane nor the set of positive real numbers. Following a generalization of these concepts for general topological spaces with the introduction of an abstract coarse structure on the space, we show, among …

Nikolski's Approach To The Theorems Of Beurling And Nyman Regarding Zeros Of The Riemann Ζ-Function, Jared R. Bunn

Masters Theses

In this thesis we present the proof of a theorem by Nikolai Nikolski. This theorem leads to a more general theorem by Nikolski regarding zero free regions of the Riemann ζ-function. This theorem is an improvement on the theorems that Nyman and Beurling proved in the nineteen fifties. Nikolski’s approach uses, in addition to step function approximations introduced by Nyman, distance functions to give more flexibility, including possible numerical experiments. The introduction discusses the Riemann Hypothesis, which always surrounds any study of the Riemann ζ-function.

The background material discussed in this thesis gives all the necessary prerequi- sites …

Effect Of Land Use On Total Suspended Solids And Turbidity In The Little River Watershed, Blount County, Tennessee, Heather Melanie Hart

Masters Theses

The Little River (LR) originates in the Great Smoky Mountains National Park (GSMNP), providing drinking water to thousands of residents inBlountCountyas it makes its way to theTennessee River. The upper reaches of the LR watershed have excellent water quality, qualifying it as a hydrologic benchmark river and outstanding national resource. A large outdoor recreation economy has grown dependent on the pristine land and water resources, including whitewater kayaking and rafting, cold and warm water fisheries, hiking, swimming and camping. However, in recent years there has been a documented overall decline in the biological diversity of the LR in the lower …

An Investigation Into A Microwave-Enhanced Solvent-Free Mannich Condensation Reaction, Kristy Lynn Homburger

Masters Theses

Microwave irradiation has gained in popularity in recent years since it has been found to accelerate various chemical reactions. Microwaves are generally considered to be more environmentally friendly than traditional methods for activating chemical reactions. An investigation into a microwave-enhanced, solventless Mannich condensation was performed. The efficiency of a standard household microwave was compared to that of an industrial microwave, with the industrial microwave proving to be more effective. The advantages of using microwave irradiation for a Mannich condensation include milder reaction conditions, the absence of solvent, less waste, and shorter reaction times. The reaction between terminal alkynes, secondary amines, …

Geochemical Characterization Of Coastal Pond And Adjacent Soil Organic Matter From Two Distinct Field Areas Of The Mcmurdo Dry Valleys, Antarctica, Meg E. Howard

Masters Theses

The McMurdo Dry Valleys (MDV), Antarctica contains some of the few ice-free oases on the continent, and is one of the coldest, driest places on earth. Despite the harsh conditions, the MDV supports an abundance of biological communities within soil and aquatic systems. Bioavailable carbon is present in these systems in the form of ancient and modern sources. An additional source of bioavailable carbon that has largely been ignored may be represented by desiccated and disseminated microbial mats (coastal pond organic matter, or CP-OM) originating in ephemeral coastal meltwater ponds of the MDV. The goal of this study is to …

Surface Studies Of Selective Hydrogen Desorption From Silicon, Jason Kenneth Smith

Masters Theses

This thesis examines quantum confined quasi-one-dimensional structures on silicon surfaces. An in situ prepared and hydrogenated Si(100)-(2x1) is investigated, on which a quasi-dimensional nanostructure is fabricated via scanning tunneling microscopy. Also, the feasibility of STM-based nanolithography on an ex situ hydrogenated Si(111)-(1x1) surface is explored. Using methods such as those discussed herein it is possible to create quasi one-dimensional semiconducting metallic nanowires as well as contact pads, useful for four point probe measurements at the nanoscale. Using a STM, dimer wide strips of hydrogen are removed from the passivated layer to reveal bare silicon surface bonds forming a nanowire approximately …

Biomarker And Stable Isotope Characterization Of Coastal Pond Organic Matter, Mcmurdo Dry Valleys, Antarctica, Melissa Margaret Hage

Masters Theses

Small coastal ponds containing photosynthetic microbial mat communities represent a potentially significant source of labile organic carbon within the McMurdoDryValleys, Antarctica. To distinguish coastal pond derived organic matter (CPDOM) from other sources of organic matter in the dry valleys, I investigated bulk organic carbon and nitrogen isotopic signatures and phospholipid fatty acid (PLFA) profiles of benthic microbial mats located at two sites, HjorthHillCoastand GarwoodValley. The average δ¹³C values at Hjorth Hill Coast and Garwood Valley are -10.91 ‰ and -10.19 ‰, respectively. The average δ¹⁵N values are 3.73 ‰ and -1.25 ‰, respectively. Microbial mats from …

Free Radical Polymerization In Room Temperature Ionic Liquids, Xiao Ma

Masters Theses

No abstract provided.

Pyrogenic Polycyclic Aromatic Hydrocarbons From Carboniferous, Triassic, And Modern Chars: Potential Relations To Paleoatmospheric Oxygen Content, Patrick Jerome Schuneman

Masters Theses

Atmospheric oxygen concentrations may have dramatically fluctuated throughout the Phanerozoic. Because oxygen is critical to fire, major oxygen fluctuations may have significantly affected biomass burning occurrences, suggesting that wildfires would have been more prevalent at times of elevated oxygen. Fossil charcoal abundances in the geologic record qualitatively reflect this relationship. Land plants evolved by the late Silurian, and the earliest true forests evolved by the mid-Devonian, while oxygen levels were still low. Fuel accumulations and oxygen content probably did not reach sufficient levels to sustain burning until the late-Devonian. There are only one or two isolated examples of fossil charcoal …

Novel Materials Used In Hydrogen Energy Economy, Hongliang Zhou

Masters Theses

The purpose of this study was to do some efforts in developing some novel polymer materials which could have the potential use in hydrogen pipelines and PEM fuel cell.

In the project of developing hydrogen pipelines, sulfonated PET, sulfonated PET/Clay and PET/Clay were produced by the method of solvent-mixing. Characterizations with TEM, SAXS were made to determine the exfoliation degree of nanocomposites. TGA was carried out to measure the thermal stability, and hydrogen permeability was also taken in order to measure the H2 gas barrier performance. It was found that the addition of clay into S-PET or PET could decrease …

Structural And Magnetic Investigations Of Cs2Agf4 And Its Doped Derivatives, Michelle Renee Dolgos

Masters Theses

This thesis describes the structural and magnetic properties of solid state silver fluorides such as Cs₂AgF₄ and its doped derivatives. A wide range of techniques such as X-ray and neutron diffraction, susceptibility measurements and inelastic neutron scattering experiments are used to characterize these materials. Silver fluorides are important given their strongly correlated magnetic behavior and the potential to discover a new class of high T_C materials. Few studies have been done on silver (II) fluorides as their characterization has been problematic due to their inherent air and water sensitivity. This study is the first to accurately …

Forage Quality And Performance Of Tall Fescue Hay Amended With Broiler Litter And Commercial Fertilizer, Stacy L. Clark

Masters Theses

Broiler chickens are a leading agricultural commodity in Tennessee. Many broiler operations are located in eastern and middle Tennessee where a common land use is tall fescue (Festuca arundinacea Schreb.) hay and pasture, for cow-calf and dairy operations. Litter from broiler operations is land applied on fescue at rates that often exceed the recommended phosphorus (P) and potassium (K) rates. Surveys of forage quality conducted by the University of Tennessee Extension in 2001 found that many forages across the state had higher than recommended K and sulfur levels and were deficient in copper (Cu) and other nutrients. In spring 2004 …

Investigating The Origin Of Precambrian Molar-Tooth Carbonate, John Curtis Crawford

Masters Theses

Molar-Tooth (MT) is an enigmatic carbonate structure that consists of a complex array of variously shaped voids filled with an unusual microspar cement. Most current research has been focused on the mechanism of formation of molar-tooth voids, and the leading model suggests a subsurface, soft-sediment, gas escape mechanism. However, little is known about the calcite microspar that fills MT voids. Brittle deformation of MT structures during sediment compaction indicates that lithification of MT voids is essentially synsedimentary. Under cathodoluminescence (CL) microscopy, MT microspar appears as small (3-12 µm), spheroidal to rhombic, non- luminescent cores surrounded by luminescent, isopachous overgrowths. Crystal …

Contact Metamorphism Of Calc-Silicate Rocks In The Belmont Contact Aureole, Central Nevada, Kelly Plummer

Masters Theses

This study focuses on the contact metamorphism of the Ordovician Zanzibar and Toquima Formations by the Cretaceous Belmont Pluton in central Nevada. I mapped the distributions of tremolite and diopside to determine the location of isograds. These isograds are the result of the reactions: 8 quartz + 5 dolomite + H₂O = 3 calcite + tremolite + 7 CO₂ and tremolite + 2 quartz + 3 calcite = 5 diopside + 3 CO₂ + H₂O. Pressure of metamorphism is estimated at between 4 kbar and 1 kbar, but is not definite because of uncertainty …

Hydrothermal Diamond Anvil Cell Studies: A Possible New Calibration Mineral And Applications To The Hydrous-Carbonate Mineral, Nesquehonite., Cara Kim Mulcahy

Masters Theses

In this study, modifications are made to the experimental setup of the Bassett-type hydrothermal diamond anvil cell facilities at the University of Tennessee. Several modifications to the HDAC setup were found to increase the number of successful experimental runs by reducing fluid loss: ·

Gaskets were no longer polished or only lightly polished using 1µm diamond polishing compound. This prevented the formation of a wedge-shaped gasket. ·

Gasket diameter was reduced to equal the diameter of the diamond anvil surface to prevent “tipping” of the gasket and the possible introduction of foreign material between the gasket and diamond anvils.

Sample …

Origin And Classification Of Middle Wallace Breccias, Mesoproterozoic Belt Supergroup, Montana And Idaho, Quintin M. Overocker

Masters Theses

A series of enigmatic breccias in the Wallace Formation, Mesoproterozoic Belt Supergroup, have been variously interpreted as originating from: (1) syndepositional downslope slumping; (2) syndepositional evaporite dissolution and collapse; or (3) post- depositional tectonic faulting. Each hypothesis carries its own implications regarding the depositional and diagenetic history of the Belt basin. Examination of several Middle Wallace breccia outcrops suggests that they can be grouped into two distinct categories based on size of breccia bodies, clast size, and relationships with surrounding strata, and matrix composition. Results indicate that rather than a single origin, these two breccia groups originate from distinctly different …