Physical Sciences and Mathematics Commons^™

Integration Of Algae And Biomass Processes To Synthesize Renewable Bioproducts For The Circular Economy, Jessica Martin

USF Tampa Graduate Theses and Dissertations

Rapid population growth and global industrialization have substantially heightened the demand for fossil-based fuels and products in various sectors of the global economy, including energy production, transportation fuels, and as raw materials for petrochemicals. The intense consumption of fossil fuels has caused immense environmental impacts, especially pertaining to carbon dioxide emissions. Shifting to renewable feedstocks (raw materials) is expected to reduce these emissions by lowering the carbon footprint of fuels and products compared to traditional fossil-derived alternatives. This transition aligns with the goal of creating a sustainable and circular economy, emphasizing efficient resource use, and reducing waste generation through recycling …

Booker Creek: Wet Season Water Quality Trends In A Florida Urban Stream, Alexandra M. Shostak

USF Tampa Graduate Theses and Dissertations

Booker Creek, a 1.9-mile stream with a 4.9-mi2 watershed, flows southeast through highly urbanized St. Petersburg, Florida, and empties into Bayboro Harbor, which connects with Tampa Bay. This study collected and analyzed water quality data for several parameters (TN, TP, nitrate-nitrite, ammonia, orthophosphate, chl-a, fecal coliform, dissolved oxygen, pH, turbidity, temperature, and salinity) every two weeks, at four different sites, during the 2022 wet season to characterize the current state and geographic variability of Booker Creek. Current creek sampling regimes, though consistent, do not sample at multiple sites along the creek. Urban streams do not display uniform water quality along …

Labile Dissolved Nickel (Ni) Concentrations In The North Pacific, Calyn M. Crawford

USF Tampa Graduate Theses and Dissertations

Nickel (Ni) is an important micronutrient for phytoplankton and bacteria that serves as a required co-factor in several metalloenzymes. Despite these known biological uses, total dissolved Ni concentrations remain elevated in global surface waters, in contrast to the surface depletion commonly observed for macronutrients and other nutrient-type trace elements. A prevailing hypothesis for the muted depletion of dissolved Ni concentrations in surface waters is that dissolved Ni in seawater is not in a bioavailable form. The chemical lability of Ni in seawater provides insight into Ni speciation and bioavailability, but few measurements have been made in the open ocean to …

Tree Planting As An Adaptive Management Tool For Climate Change In Morocco, Stephanie J. Robinson

USF Tampa Graduate Theses and Dissertations

The practice of planting fruit trees to combat climate change impacts in Morocco has been growing in popularity with support from the Moroccan government and non-profit organizations. Although it is often considered a successful adaptive management tool, tree planting initiatives (TPIs) in arid lands have not been thoroughly analyzed, their management is unstandardized, and these initiatives can cause harm when trees are planted in areas that cannot support them. To implement tree planting better these TPIs need to find areas where the trees they are introducing have the best chance of survival without negatively impacting the surrounding ecosystem and human …

Use Of Silica Dust And Lunar Simulants For Assessing Lunar Regolith Exposure, Layzamarie Irizarry-Colon

USF Tampa Graduate Theses and Dissertations

The utilization of the lunar regolith holds immense potential for future space exploration, but the potential health risks associated with lunar regolith are a significant concern. This literature review seeks to critically assess the use of silica and lunar simulants standards and permissible exposure limits (PELs) to evaluate the adverse health effects of lunar regolith. The literature review covers an extensive analysis of existing research, health risks, toxicological properties, and physical and chemical composition associated with silica, lunar simulants, and lunar regolith by using three main sources: regulations, scholarly articles, and Kennedy Space Center (KSC) discussion. This comprehensive analysis forms …

Organizing And Communicating Health: A Culture-Centered And Necrocapitalist Inquiry Of Groundwater Contamination In Rural West Bengal, Parameswari Mukherjee

USF Tampa Graduate Theses and Dissertations

As a discursive point of praxis, this dissertation project seeks to record knowledge from below around the overlaps between health, water and health interventions emerging from rural communities located in North 24 Parganas and Purulia in West Bengal that are disproportionately impacted by water-insecurity. My dissertation also documents how multiple-stakeholders such as local NGOs, international NGOs, non-profits, and donor agencies organize access to safe water and health interventions for the water-insecure communities located in North 24 Parganas and Purulia. The integration of the CCA and necrocapitalism afford theoretical and methodological guidance in this dissertation to help document the localocentric stories …

Exploratory Data-Driven Models For Water Quality: A Case Study For Tampa Bay Water, Sandra Sekyere

USF Tampa Graduate Theses and Dissertations

Water, a crucial resource for sustaining life, covers approximately 70% of the earth's surface. Nonetheless, the quality of water is deteriorating rapidly due to the rapid growth of urban areas and industries, which is a worrying trend causing harm to human health and the ecosystem. Water quality forecasting has a key role in water resources management by enabling effective pollution control, ecosystem monitoring, and decision-making.

Previously, traditional statistical models were used to forecast water quality, but they were unable to examine the non-linear relationships between water quality parameters, and they assumed that all datasets were distributed normally. This study uses …

Analysis Of Ostds Failure Potential Due To Sea-Level Rise And Other Inundation Factors: An Integrated Geo-Spatial Analysis, Alec Colarusso

USF Tampa Graduate Theses and Dissertations

While many aspects of climate change are well-studied, the vulnerability of Onsite Sewage Treatment and Disposal Systems (OSTDS) to sea-level rise (SLR) has not been thoroughly examined despite the potentially significant environmental impacts, including nutrient and pathogen loading. Research gaps include the need to determine the suitability of models to predict groundwater inundation due to SLR and the consequent impact on OSTDS. As such, this study aims to compare Bathtub/hydrostatic and physics-based/MODFLOW/3D numerical modeling methods of simulating groundwater inundation from SLR to identify OSTDS vulnerability to failure due to a reduction in the height of the vadose zone (saturation or …

Characteristics And Hydraulic Behavior Of Adsorptive Media For Use In Permeable Reactive Barriers, Shelby Rocha

USF Tampa Graduate Theses and Dissertations

The Cargill ditch is located on the property of Se7en Wetlands, a 1600-ac treatment wetland system in Lakeland, Polk County, Florida. The Se7en Wetlands property was previously utilized for phosphate mining prior to the construction of the system. Nonpoint nutrient sources derived from remnants of abandoned phosphate mines – known as “legacy phosphorus” – become mobilized by stormwater runoff and impair surface water bodies by promoting harmful algal blooms (HABs). Thus, the Cargill ditch likely conveys nutrient rich flow resulting from legacy phosphorus and is thought to be one contributing factor in the occurrence of HABs within the treatment wetland …

Predicting Groundwater Spring Locations From Topographic And Climatic Data Using Maxent Modeling, Ayten Ece Koc

USF Tampa Graduate Theses and Dissertations

The World Resources Institute reveals that 17 countries face extremely high levels of water stress. Moreover, with increasing population and industrialization, the gap between water supply and demand increases day by day around the world. Groundwater is a key freshwater source, and springs are important resources as they enable to access groundwater. Therefore, it is crucial to monitor, protect, and manage groundwater springs. The first step in spring management is to recognize and define freshwater resources and to determine the locations of groundwater springs that serve as natural discharge points. Traditionally, field studies have been employed to determine the locations …

Prepare For, Respond To, Recover, And Learn From Disasters: Using Data-Driven Methods To Model And Understand Disaster Resilience, Jinwen Xu

USF Tampa Graduate Theses and Dissertations

Community resilience reflects the ability of human communities to prepare for, respond to, recover, and learn from disastrous events. Community resilience carries different meanings in different phases of disaster management (i.e., preparedness, response, recovery, and mitigation). With the emergence of new geospatial data sources, human activities now can be captured through social media, mobile signals, and nighttime illuminations, which makes it possible to describe the conditions among various communities before, during, and after disasters. Therefore, this dissertation explored the use of different types of geospatial data sources (social media, nighttime light remote sensing, land-use data, and census survey data) during …

An Analysis Of The Oil Pollution Act Of 1990: Regulatory Calibration In Anticipation Of 21st Century Environmental Disasters, Jessica S. Thornton

USF Tampa Graduate Theses and Dissertations

After federal the Oil Pollution Act of 1990 (OPA 90) was promulgated in response to the Exxon Valdez oil spill in Alaska, it helped restructure the nation’s environmental response capabilities and modernize the commercial shipping industry to effectively decrease environmental shipping disasters. However, in the 33 years since OPA 90’s inception, the oil and gas industry has transformed, especially in the offshore realm, as industry adopts new drilling technologies to gain access to deeper and heretofore untapped maritime environments. Though there have been two catastrophic offshore drilling accidents since the turn of the 21st century, OPA 90 remains categorically unchanged, …

Land Use/Land Cover Uncertainty Analysis Using Hydrological Modeling In The Northern Watershed Of Lake Okeechobee, Andres Lora Santos

USF Tampa Graduate Theses and Dissertations

Over the past 150 years, Florida has undergone a major land-form transformation, transitioning from a natural to a primarily built environment. The state's population has grown exponentially, from less than 50,000 residents in the 1850s to approximately 22 million residents today. This population growth has led to significant changes in land use, including urbanization, mining, and agriculture. This trend is expected to continue, with projections indicating an increase in urbanization across the state. 2070 land use/land cover projections were used as input for the Watershed Assessment Model (WAM) to analyze the potential impact of these changes on flow, total nitrogen …

Data-Driven State Estimation For Improved Wide Area Situational Awareness In Smart Grids, Md Jakir Hossain

USF Tampa Graduate Theses and Dissertations

Wide area situational awareness (WASA) in smart grids includes automatic monitoring, perception and detection of anomalies in these systems. The goal of WASA is to make smart grids aware of their physical and operational state for more effective operational decisions and control. As such, tracking the system's state or state estimation is one of the key objectives of WASA. The extensive integration of cyber elements into smart grids, such as large deployment of various monitoring and measurement devices, provides new opportunities to improve WASA. However, the tight coupling of power grids with cyber components introduces vulnerabilities to cyber and physical …

Quantifying A 21-Year Surface Water And Groundwater Interaction In A Ridge And Valley Lake Environment Using A Highly Constrained Modeling Approach, Richard T. Bowers Jr.

USF Tampa Graduate Theses and Dissertations

Karst lakes are ubiquitous in ridge terrain settings in limestone aquifer coastal plain environments. In west-central Florida, these lakes are frequently connected to the Upper Floridan aquifer and have unique aquifer recharge characteristics. They have been selectively studied because they commonly have no or very limited surface water discharge and limited drainage areas, have appreciable surface water and groundwater interaction and leak to the deep aquifer. An innovative modeling approach was developed to collectively understand and more precisely quantify this vertical leakage, both from a lake-specific and regional water budget standpoint, for a 21-year study period (2000-2020). A unique, calibrated …

Surviving A Broken System: Synergies Between Solidarity Economies And Sustainable Development Goals, Julie Beach

USF Tampa Graduate Theses and Dissertations

Capitalism has created problems including wealth polarization, rapid depletion of natural resources, and pervasive systemic societal issues. Hard work is not enough to solve the unequal distribution and barriers preventing access to necessities. Sustainable Development Goals (SDGs) were created to remedy the harsh reality of global inequities and negative environmental impacts by working towards a more just and equitable future for all. Solidarity Economies (SE) offer an alternative framework to achieve these goals.

This research used multiple qualitative methods to investigate the synergies between SE and SDGs in a growing urban environment. St. Petersburg, FL struggles with affordable housing, food …

Sports And Greenhouse Gas Emissions: Building A Better Framework For Sustainable Sports Operations, Austin Anahory

USF Tampa Graduate Theses and Dissertations

This thesis analyzes the approach to sustainability of American soccer leagues and provides a Greenhouse Gas (GHG) Inventory of the Tampa Bay Rowdies. Sustainability and climate change are rising concerns for most industries, especially the sports industry as it will face many immediate and long term impacts. To address these issues, a sustainability analysis was done of each USL Championship team to assess prominence of sustainability topics from their website. To conduct the GHG inventory, the GHG Protocol was followed and resulted in assessing Scope 1, 2, and 3 of the given soccer team. Assumptions were used to estimate missing …

Coupling 210Pb And 14C To Constrain Carbon Burial Efficiency Of Blue Carbon Ecosystems, Tynisha R. Martin

USF Tampa Graduate Theses and Dissertations

Blue carbon ecosystems cover a small global area but have the potential to sequester large amounts of organic carbon (OC) from the coastal ocean in the sediment. Organic carbon is continually remineralized and exported in the dissolved form, which is currently only poorly accounted for in blue carbon budgets. Constraining carbon cycling in blue carbon systems is complicated by the range of carbon sources and sinks in the system and high export rates from the system. By coupling 14C and 210Pb chronometers to ascertain the amount of primary production stored within peat, it is possible to study carbon transport through …

Assessing The Human-Health Risk Of Exposure To Pathogens From Beach Sands, Javier Federico Gallard-Góngora

USF Tampa Graduate Theses and Dissertations

Fecal contamination at recreational beaches impacts the health of beachgoers, through the introduction of disease-causing microorganisms, and the well-being of communities dependent on income from recreational beach activities. Beach ecosystems are also impacted by sewage through the introduction of nutrients that can cause abnormal increases in autochthonous microorganisms which can impact the population of larger organisms in the ecosystem. Fecal contamination is introduced into sand via untreated sewage, direct deposition of human feces into sand, runoff, and deposition of animal feces into sand. The introduction of fecal contamination into sand exposes individuals to pathogens (disease causing microorganisms) which can result …

Antibiotic-Resistant Escherichia Coli And EnterococcusSpp. In Sand And Water At Tampa Bay Beaches, Jennifer K. Sabater

USF Tampa Graduate Theses and Dissertations

As antibiotic resistance in the environment continues to rise there is an increased concern that infections may become harder to treat as bacteria acquire genes for multidrug resistance. Recreational beach waters in the Tampa Bay area are routinely monitored by the Florida Department of Environmental Protection for the presence of fecal indicator bacteria (FIB) such as Escherichia coli and enterococci. Exceedances of beach action values (BAV) 235 CFU/100 mL (E. coli) and 70 CFU/100 mL (enterococci) indicate the presence of fecal contamination which is associated with an increased risk of disease for beachgoers. Antibiotic-resistant E. coli and Enterococcus spp. have …

Assessing Environmental Sensitivity In San Diego County, California, For Bird Species Of Special Concern, Eda Okan Kilic

USF Tampa Graduate Theses and Dissertations

It is widely recognized that desertification constitutes one of the biggest environmental problems on Earth. Desertification negatively impacts the future of humans and other living things all over the globe. Therefore, the assessment of desertification is essential to both monitor and combat desertification. A number of models are routinely applied to assess desertification. The MEDALUS model is one of the most popular approaches, identifying desertification risk based on an environmentally sensitive area index (ESAI) that integrates climate, vegetation, soils, groundwater, and socio-economic factors to obtain an overall rating. The goal of this study was to measure the potential impacts of …

Integration Of Sustainability Into Higher Education Policies: A Case Study Of The University Of South Florida, Mehmet Z. Apaydin

USF Tampa Graduate Theses and Dissertations

Sustainability and the United Nations Sustainable Development Goals (SDGs) are not new notions for higher education institutions (HEIs). However, well-organized efforts to make campuses "sustainable" are not common, and the efforts are modest compared to the institutional capabilities. This thesis, a case study of the University of South Florida (USF), was designed to explore how sustainability values and SDGs are incorporated into higher education policies. To accomplish this, the study employed a mixed method design that includes a literature review, an overview of policies and implementations, document content analysis, a program and course inventory, a keyword analysis, and semi-structured interviews. …

Isotopic Study Of The Waters From The Sulphur Springs Catchment, Tampa, Florida, Esra Zengin

USF Tampa Graduate Theses and Dissertations

A stable isotope study was carried out using precipitation, spring water, groundwater well sample, and a seawater sample during the wet season in the Sulphur Springs watershed in Tampa, Florida. Studies that track long term isotopic variation over wet seasons are limited in the region. To fill this knowledge gap, this study aims to quantify the contributions of precipitation and diffuse sources to discharge in Sulphur Springs. A three-component mixing model was applied using δ18O and δ2H values to determine different source water contributions to spring water discharge. The three-component mixing model calculations suggest spring water consists mainly of diffuse …

Measuring Sustainable Development Through Tax Increment Financed Brownfield Redevelopment Statutes: A Florida Case Study, Jeff Burton

USF Tampa Graduate Theses and Dissertations

This research measures the theoretically sustainable development synergy of United States’ redevelopment, tax increment, and brownfield statutes and questions local redevelopment professionals on this combination’s implementation. This policy’s integration and application measurements guide increased knowledge and best practice methods in the path of America’s population migration into urbanized areas, thus managing the economic, environmental, and social impacts for future generations.

This examination used a pragmatic, qualitative, and quantitative mixed-method approach to identify, collect, code, and analyze redevelopment, tax increment, and state brownfields laws. An exhaustive literature review of the laws’ histories explained when and why they exist. In addition, a …

Desertification Risk Analysis For Wildlife In The Desert Renewable Energy Conversation Plan Area Of California, Serdar Sagdic

USF Tampa Graduate Theses and Dissertations

Desertification is one of the primary threats facing the sustainability of the Earths’s natural resources. Desertification it is an outcome of human impacts to ecosystems and alterations of climate patterns resulting in land degradation and adverse effect on natural resources, vegetation loss, soil infertility, and water scarcity. These changes influence the existence and distribution of wildlife by reducing the availability and quality of habitat that provides food, water, cover, and other life requisites. Therefore, this study aimed at evaluation of potential desertification risks on wildlife species in the Desert Renewable Energy and Conservation Plan (DRECP) area of California.

The DRECP …

Watershed Management For Nutrient Control In Taylor Creek And Nubbins Slough, Florida, Rachael Z. Cooper

USF Tampa Graduate Theses and Dissertations

Despite efforts to improve water quality within the watershed since the 1970s, harmful algal blooms (HABs) still occur within Lake Okeechobee (LO). HABs are harmful to the people, the ecosystem, and the economy dependent on the lake. Taylor Creek Nubbins Slough (TCNS) is a subwatershed of the lake, contributing to a large percentage of the nutrient loading. Due to the size and complexity of LO’s watershed, two smaller basins within the TCNS subwatershed were selected to evaluate the following research questions: (1) How do water quality trends contrast between two basins? (2) How do nutrient load and treatment within the …

Using Fine-Scale Aquatic Habitat Data To Construct Dreissenid Sdms In The Laurentian Great Lakes, Grace C. Henderson

USF Tampa Graduate Theses and Dissertations

The invasion of the Laurentian Great Lakes by aquatic invasive species (AIS) has been the subject of investigation for decades, due to their dramatic alterations to the ecosystem and high economic costs. Two AIS with the largest impacts are dreissenid zebra and quagga mussels, and though these species have been studied extensively, questions remain about what factors control their distributions, and whether lake warming will alter these distributions. Species distribution models (SDMs) offer a powerful tool to examine the relationship between species presences and environmental variables, which are typically bioclimactic data. The creation of the Aquatic Habitat (AqHab) dataset containing …

Soil Accretion And Mass Accumulation In A Scrub And Fringe Mangrove Forest In Biscayne Bay, Florida, Jessica A. Jacobs

USF Tampa Graduate Theses and Dissertations

This study estimated soil accretion and mass (organic carbon (OC), total nitrogen (TN), and total soil) accumulation in a scrub and fringe mangrove forest in Biscayne Bay, FL, to assess how forests of different morphologies (scrub vs. fringe) have kept pace with recently accelerating rates of sea-level rise. Accretion rates (AR) were estimated using the Constant Initial Concentration (CIC) model of lead-210 deposition and it was determined that the scrub forest has accreted at 1.3 ± 0.2 mm yr-1 over 75 years and the fringe forest at 2.8 ± 0.4 mm yr-1 over 92 years. The fringe forest estimate met …

Efficient Management Of Nitrogen And Phosphorus At Centralized Water Reclamation Facilities, Helene Kassouf

USF Tampa Graduate Theses and Dissertations

A variety of process configurations are employed at municipal water reclamation facilities (WRFs), such as 5-stage Bardenpho, oxidation ditch, modified Ludzack-Ettinger (MLE) process, and sidestream recycle. However, all of these configurations face certain challenges in achieving optimum treatment of nitrogen and phosphorus. In this dissertation, the driving objectives were to: (1) quantitatively assess the fate of nitrogen and phosphorus (mass fluxes) at a treatment facility that employs biological nutrient removal, aerobic digestion, and sidestream recycle, (2) evaluate the performance of a microbial fuel cell (MFC) as a technology to remove nitrogen from sidestreams at a treatment plant that employs that …

Pressure Retarded Osmosis: A Potential Technology For Seawater Desalination Energy Recovery And Concentrate Management, Joshua Benjamin

USF Tampa Graduate Theses and Dissertations

Currently, a significant challenge with reverse osmosis-based desalination is reducing the energy consumption and environmental impacts of the process. This project analyzed the viability of using pressure-retarded osmosis (PRO) for energy recovery in seawater desalination facilities using brine concentrate (the draw solution) and other water sources (the feed solution) such as wastewater effluent. The primary goal of this project is to decrease the cost and overall energy consumption of seawater desalination through PRO-based energy recovery. Process modeling, statistical and sensitivity analysis, energy and cost analysis, geospatial and GIS analysis, laboratory-scale testing, water quality analysis, SEM-EDS microscopy, computational fluid dynamics (CFD), …