Physical Sciences and Mathematics Commons^™

A Field-Programmable Metamaterial Using Memristor As A Stable Switcher, Taekuk Hong

Theses and Dissertations

Before the memristor was discovered, there were RLC circuits as representative passive devices. However, the fourth fundamental two-terminal circuit has been discovered by Dr. Leon Chua in 1971 and has been called a memristor. The memristor is a compound word of memory and resistor, and is an element whose resistive value is not constant and whose resistive value changes depending on the applied voltage and is recorded as a memory. It is mainly used in resistive switching and is the center of this research theme. A metamaterial is artificially created material that has never been found in nature. The theory …

Structural, Functional And Biochemical Studies To Elucidate The Molecular Basis Of Xenobiotic Metabolism Of Tetranychus Uritcae, A Major Agricultural Pest, Ricardo Hernandez Arriaza

Theses and Dissertations

The two-spotted spider mite, Tetranychus urticae, is a major cosmopolitan pest that feeds on more than 1,100 plant species, including 150 crops. Such a wide host range indicates this mite’s unparalleled xenobiotic responsiveness that is also coincident with their ability to rapidly develop resistance to pesticides. An unprecedently large detoxifying machinery is one of the main biological traits responsible for their extraordinary adaptation potential and devastating effect on crops. Availability of the whole genome sequence revealed expansions in all major detoxifying families and demonstrated that this genome has been enriched by horizontally transferred genes from bacteria and fungi. Motivated by …

Unusual High-Frequency Mechanical Properties Of Polymer-Grafted Nanoparticle Melts, Mayank Jhalaria, Yu Chang, Yucheng Huang, Brian C. Benicewicz, Sanat K. Kumar, George Fytas

Faculty Publications

Brillouin light spectroscopy is used to measure the elastic moduli of spherical polymer-grafted nanoparticle (GNP) melts as a function of chain length at fixed grafting density (0.47  chains/nm²) and nanoparticle radius (8 nm). While the moduli follow a rule of mixtures (Wood’s law) for long chains, they display enhanced elasticity and anomalous dissipation for graft chains <1⁢0⁢0  kDa. GNP melts with long polymers at high 𝜎 have a dry zone near the GNP core, surrounded by a region where the grafts can interpenetrate with chain fragments from adjacent GNPs. We propose that the departures from Wood’s law for short chains are due to the effectively larger silica volume fraction in the region where sound propagates—this is caused by the short, interpenetrated chain fragments being pushed out of the way. We thus conclude that transport mechanisms (of gas, ions, sound, thermal phonons) in GNP melts are radically different if interpenetrated chain segments can be “pushed out of the way” or not. This provides a facile new means for manipulating the properties of these materials.

Concurrent Identification, Characterization, And Reconstruction Of Protein Structure And Mixed-Mode Dynamics From Rdc Data Using Redcraft, Hanin Rafiq Omar

Theses and Dissertations

A complete understanding of the structure-function relationship of proteins requires an analysis of their dynamic behaviors and the static structure. However, all current approaches to studying dynamics in proteins have their shortcomings. A conceptually attractive and alternative approach simultaneously characterizes a protein's structure and its intrinsic dynamics⁠. Ideally, such an approach could solely rely on RDC data-carrying both structural and dynamical information. The major bottleneck in utilizing RDC data in recent years has been attributed to a lack of RDC analysis tools capable of extracting the pertinent information embedded within this complex data source.

Here we present a comprehensive strategy …

Lakshadweep High Propagation And Impacts On The Somali Current And Eddies During The Southwest Monsoon, Paul A. Ernst, Bulusu Subrahmanyam, Corinne B. Trott

Faculty Publications

Climatological eddies in the Arabian Sea (AS), including the Lakshadweep High (LH) and the Great Whirl (GW), play major roles in the regional fluxes of upper ocean properties. For the first time, we apply an eddy tracking algorithm to the LH using altimetric sea surface height observations from 1993 through 2019. We additionally analyze the LH's water mass composition throughout its life cycle using the 1/12° Global eddy resolving physical ocean and sea ice reanalysis (GLORYS12). We observe that the second annual downwelling coastal Kelvin wave's (CKW) arrival during the winter monsoon is primarily responsible for generating the LH. In …

12 C(E,E'Pn) Measurements Of Short Range Correlations In The Tensor-To-Scalar Interaction Transition Region, I. Korover, J. R. Pybus, A. Schmidt, F. Hauenstein, M. Duer, O. Hen, E. Piasetzky, L. B. Weinstein, D. W. Higinbotham, S. Adhikari, K. Adhikari, M. J. Amaryan, Giovanni Angelini, H. Atac, L. Barion, M. Battaglieri, A. Beck, I. Bedlinkskiy, Fatiha Benmokhtar, Steffen Strauch, Ralf W. Gothe, Krishna Chandra Neupane, Et. Al.

Faculty Publications

High-momentum configurations of nucleon pairs at short-distance are probed using measurements of the C-12(e, e' p) and C-12(e, e' pN) reactions (where N is either n or p), at high-Q(2) and x(B) > 1.1. The data span a missing-momentum range of 300-1000 MeV/c and are predominantly sensitive to the transition region of the strong nuclear interaction from a Tensor to Scalar interaction. The data are well reproduced by theoretical calculations using the Generalized Contact Formalism with both chiral and phenomenological nucleon-nucleon (NN) interaction models. This agreement suggests that the measured high missing-momentum protons up to 1000 MeV/c predominantly belong to short-ranged …

An Operational Overview Of The Export Processes In The Ocean From Remote Sensing (Exports) Northeast Pacific Field Deployment, David A. Siegel, Ivona Cetinic, Jason R. Graff, Craig M. Lee, Norman Nelson, Mary Jane Perry, Inia Soto Ramos, Deborah K. Steinberg, Ken Buesseler, Roberta Hamme, Andrea J. Fassbender, David Nicholson, Melissa M. Omand, Marie Robert, Andrew Thompson, Vinicius Amaral, Michael Behrenfeld, Claudia R. Benitez-Nelson, Kelsey Bisson, Emmanuel Boss, Et. Al.

Faculty Publications

The goal of the EXport Processes in the Ocean from RemoTe Sensing (EXPORTS) field campaign is to develop a predictive understanding of the export, fate, and carbon cycle impacts of global ocean net primary production. To accomplish this goal, observations of export flux pathways, plankton community composition, food web processes, and optical, physical, and biogeochemical (BGC) properties are needed over a range of ecosystem states. Here we introduce the first EXPORTS field deployment to Ocean Station Papa in the Northeast Pacific Ocean during summer of 2018, providing context for other papers in this special collection. The experiment was conducted with …

From Cellular To Holistic: Development Of Algorithms To Study Human Health And Diseases, Casey Anne Cole

Theses and Dissertations

The development of theoretical computational methods and their application has become widespread in the world today. In this dissertation, I present my work in the creation of models to detect and describe complex biological and health related problems. The first major part of my work centers around the creation and enhancement of methods to calculate protein structure and dynamics. To this end, substantial enhancement has been made to the software package REDCRAFT to better facilitate its usage in protein structure calculation. The enhancements have led to an overall increase in its ability to characterize proteins under difficult conditions such as …

Population Dynamics Of A Recently Described And Rare Plant Species: Stachys Caroliniana (Lamiaceae), Shelby Moody

Theses and Dissertations

Stachys caroliniana J.B. Nelson & D.A. Rayner, a newly described ‘hedge-nettle’ is found in two locations in South Carolina. The first known collection of this species is from the Santee Coastal Reserve in Charleston County. The second location (the type locality) is from the Tom Yawkey Wildlife Center in Georgetown County, approximately 8 air miles northeast of the first location. This study focused on the population in Georgetown County. Population dynamics of Stachys caroliniana were studied in order to provide management guidelines to South Carolina Department of Natural Resources for this species. This was achieved by assessing suitable habitat conditions, …

Ecohydrology And Groundwater Dynamics In A Salt Marsh Island, Andrea L. H. Hughes

Theses and Dissertations

Tidal salt marshes are extraordinarily productive and valuable ecosystems that provide via groundwater a not insignificant portion of coastal solute and nutrient budgets. Among the many goods and services they provide are habitat for diverse wildlife, protection for coastal communities during storms, and protection for coastal surface waters by filtering anthropogenic pollutants. One threat to the health of tidal salt marshes along the East Coast have been episodes of Acute Marsh Dieback (AMD) from 1999 to 2001. Dieback was observed at North Inlet salt marsh from 2000 to 2001. Since salt marsh hydrology is dominated by the local tidal regime, …

Approximate Quantum Trajectory Method For Modeling Chemical Reaction Dynamics: Application To Enzymatic Proton Transfer, James William Mazzuca

Theses and Dissertations

Molecular dynamics simulations, providing a detailed picture of the reaction mechanism, is an essential tool for theoretical and experimental chemists. In these simulations the nuclei are typically treated as classical particles, but under some conditions (low energies and temperatures, processes involving multiple electronic states) a classical description is inappropriate. Quantum effects of nuclear motion, such as tunneling and zero-point energy can play an important role in determining a reaction mechanism, yet exact quantum dynamics methods are limited to reactive systems of just 3-4 atoms. Central to this work is the development and implementations of an efficient trajectory-based methodology, in which …

Dynamics And Rheology Of Biaxial Liquid Crystal Polymers, Sarthok K. Sircar

Theses and Dissertations

In this thesis we derive a hydrodynamical kinetic theory to study the orientational response of a mesoscopic system of nematic liquid crystals in the presence of an external flow field. Various problems have been attempted in this direction. First, we understand the steady-state behavior of uniaxial LCPs under an imposed elongational flow, electric and magnetic field respectively. We show that (1) the Smoluchowski equation can be cast into a generic form, (2) the external field is parallel to one of the eigenvectors of the second moment tensor, and (3) the steady state probability density function is of the Boltzmann type. …

Semiclassical Dynamics With Quantum Trajectories: Formulation And Comparison With The Semiclassical Initial Value Representation Propagator, Sophya Garashchuk, Vitaly A. Rassolov

Faculty Publications

We present a time-dependent semiclassical method based on quantum trajectories. Quantum-mechanical effects are described via the quantum potential computed from the wave function density approximated as a linear combination of Gaussian fitting functions. The number of the fitting functions determines the accuracy of the approximate quantum potential (AQP). One Gaussian fit reproduces time-evolution of a Gaussian wave packet in a parabolic potential. The limit of the large number of fitting Gaussians and trajectories gives the full quantum-mechanical result. The method is systematically improvable from classical to fully quantum. The fitting procedure is implemented as a gradient minimization. We also compare …