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University of South Carolina

Faculty Publications

2013

Articles 1 - 19 of 19

Full-Text Articles in Physical Sciences and Mathematics

Contributions To Pion Decay From Lorentz Violation In The Weak Sector, Brett David Altschul Oct 2013

Contributions To Pion Decay From Lorentz Violation In The Weak Sector, Brett David Altschul

Faculty Publications

Lorentz violation in the weak sector would affect the β-decay lifetimes of pions. The decay amplitude may be rendered anisotropic, but only an isotropic violation of boost invariance can affect the net lifetime in the center-of-mass frame. However, since the rest frames of the pions that produce the NuMI neutrino beam at Fermilab vary with the rotation of the Earth, it is possible to constrain anisotropic Lorentz violation using prior analyses of sidereal variations in the event rate at the MINOS near detector. The resulting bounds on weak-sector Lorentz violation are at the 10−4 level, a substantial improvement over …


Short, Strong Halogen Bonding In Co-Crystals Of Pyridyl Bis-Urea Macrocycles And Iodoperfluorocarbons, Michael F. Geer, James Mazzuca, Mark D. Smith, Linda S. Shimizu Sep 2013

Short, Strong Halogen Bonding In Co-Crystals Of Pyridyl Bis-Urea Macrocycles And Iodoperfluorocarbons, Michael F. Geer, James Mazzuca, Mark D. Smith, Linda S. Shimizu

Faculty Publications

No abstract provided.


Protein Structure Validation And Identification From Unassigned Residual Dipolar Coupling Data Using 2d-Pdpa, Arjang Fahim, Rishi Mukhopadhayay, Ryan Yandle, James H. Prestegard, Homayoun Valafar Aug 2013

Protein Structure Validation And Identification From Unassigned Residual Dipolar Coupling Data Using 2d-Pdpa, Arjang Fahim, Rishi Mukhopadhayay, Ryan Yandle, James H. Prestegard, Homayoun Valafar

Faculty Publications

More than 90% of protein structures submitted to the PDB each year are homologous to some previously characterized protein structure. The extensive resources that are required for structural characterization of proteins can be justified for the 10% of the novel structures, but not for the remaining 90%. This report presents the 2D-PDPA method, which utilizes unassigned residual dipolar coupling in order to address the economics of structure determination of routine proteins by reducing the data acquisition and processing time. 2D-PDPA has been demonstrated to successfully identify the correct structure of an array of proteins that range from 46 to 445 …


A Supramolecular Strategy To Assemble Multifunctional Viral Nanoparticles, Limin Chen, Xia Zhao, Yuan Lin, Yubin Huang, Qian Wang Aug 2013

A Supramolecular Strategy To Assemble Multifunctional Viral Nanoparticles, Limin Chen, Xia Zhao, Yuan Lin, Yubin Huang, Qian Wang

Faculty Publications

Using a one-pot approach driven by the supramolecular interaction between β-cyclodextrin and adamantyl moieties, multifunctional viral nanoparticles can be facilely formulated for biomedical applications.


A Forward-Secure Certificate-Based Signature Scheme, Jiguo Li, Huiyun Teng, Xinyu Huang, Yichen Zhang, Jianying Zhou Aug 2013

A Forward-Secure Certificate-Based Signature Scheme, Jiguo Li, Huiyun Teng, Xinyu Huang, Yichen Zhang, Jianying Zhou

Faculty Publications

Cryptographic computations are often carried out on insecure devices for which the threat of key exposure raises a serious concern. In an effort to address the key exposure problem, the notion of forward security was first presented by Günther in 1990. In a forward-secure scheme, secret keys are updated at regular periods of time; exposure of the secret key corresponding to a given time period does not enable an adversary to ‘break’ the scheme for any prior time period. In this paper, we first introduce forward security into certificate-based cryptography and define the security model of forward-secure certificate-based signatures (CBSs). …


Spatial And Seasonal Variability Of Dissolved Organic Matter In The Cariaco Basin, Laura Lorenzoni, Gordon T. Taylor, Claudia R. Benitez-Nelson, Dennis A. Hansell, Enrique Montes, Robert Masserini, Kent Fanning, Ramón Varela, Yrene Astor, Laurencia Guzmán, Frank E. Muller-Karger Jun 2013

Spatial And Seasonal Variability Of Dissolved Organic Matter In The Cariaco Basin, Laura Lorenzoni, Gordon T. Taylor, Claudia R. Benitez-Nelson, Dennis A. Hansell, Enrique Montes, Robert Masserini, Kent Fanning, Ramón Varela, Yrene Astor, Laurencia Guzmán, Frank E. Muller-Karger

Faculty Publications

[1] Dissolved organic carbon (DOC), nitrogen (DON), and phosphorus (DOP) were measured monthly at the CARIACO Time Series station (10°30′N, 64°40′W) in the southeastern Caribbean Sea between 2005 and 2012. Marked seasonal variability in DOC concentrations was observed, with lower values (~66 µM) in the upper water column (<75 >m) during the upwelling season (December–April) due to the injection of cool, DOC‐impoverished Subtropical Underwater from the Caribbean Sea. During the rainy season (May–November) waters were stratified and upper layer DOC concentrations increased to ~71 µM. Interannual variability in surface (1 m) concentrations of DOC was also observed in response to …


Enhanced Nucleate Boiling On Horizontal Hydrophobic-Hydrophilic Carbon Nanotube Coatings, Xianming Dai, Xinyu Huang, Fanghao Yang, Xiaodong Li, Joshua Sightler, Yingchao Yang, Chen Li Apr 2013

Enhanced Nucleate Boiling On Horizontal Hydrophobic-Hydrophilic Carbon Nanotube Coatings, Xianming Dai, Xinyu Huang, Fanghao Yang, Xiaodong Li, Joshua Sightler, Yingchao Yang, Chen Li

Faculty Publications

Ideal hydrophobic-hydrophilic composite cavities are highly desired to enhance nucleate boiling. However, it is challenging and costly to fabricate these types of cavities by conventional micro/nano fabrication techniques. In this study, a type of hydrophobic-hydrophilic composite interfaces were synthesized from functionalized multiwall carbon nanotubes by introducing hydrophilic functional groups on the pristine multiwall carbon nanotubes. This type of carbon nanotube enabled hydrophobic-hydrophilic composite interfaces were systematically characterized. Ideal cavities created by the interfaces were experimentally demonstrated to be the primary reason to substantially enhance nucleate boiling


Note: A Simple Thermal Gradient Annealing Unit For The Treatment Of Thin Films, C. J. Metting, Johnathan K. Bunn, Ellen A. Underwood, Yihao Zhu, G. Koley, T. Crawford, Jason R. Hattrick-Simpers Mar 2013

Note: A Simple Thermal Gradient Annealing Unit For The Treatment Of Thin Films, C. J. Metting, Johnathan K. Bunn, Ellen A. Underwood, Yihao Zhu, G. Koley, T. Crawford, Jason R. Hattrick-Simpers

Faculty Publications

A gradient annealing cell has been developed for the high-throughput study of thermalannealing effects on thin-film libraries in different environments. The inexpensive gradientannealing unit permits temperature gradients as large as 28 °C/mm and can accommodate samples ranging in length from 13 mm to 51 mm. The system was validated by investigating the effects of annealing temperature on the crystallinity, resistivity, and transparency of tin-doped indium oxide deposited on a glass substrate by magnetron sputtering. The unit developed in this work will permit the rapid optimization of materials properties such as crystallinity, homogeneity, and conductivity across a variety of applications.


Lorentz And Cpt Violation In Scalar-Mediated Potentials, Brett David Altschul Feb 2013

Lorentz And Cpt Violation In Scalar-Mediated Potentials, Brett David Altschul

Faculty Publications

In Lorentz- and CPT-violating effective field theories involving scalar and spinor fields, there exist forms of Lorentz violation that modify only the scalar-spinor Yukawa interaction vertices. These affect low-energy fermion and antifermion scattering processes through modifications to the nonrelativistic Yukawa potentials. The modified potentials involve novel combinations of momentum, spin, and Lorentz-violating background tensors.


Neutrino Beam Constraints On Flavor-Diagonal Lorentz Violation, Brett David Altschul Feb 2013

Neutrino Beam Constraints On Flavor-Diagonal Lorentz Violation, Brett David Altschul

Faculty Publications

Breaking of isotropy and Lorentz boost invariance in the dynamics of second-generation leptons would lead to direction-dependent changes in the lifetimes of charged pions. This would make the intensity of a neutrino beam produced via pion decay a function of the beam orientation. The experimental signature of this phenomenon—sidereal variations in the event rate at a downstream neutrino detector—has already been studied, in searches for Lorentz-violating neutrino oscillations. Existing analyses of MINOS near detector data can be used to constrain the flavor-diagonal Lorentz violation coefficients affecting muon neutrino speeds at roughly the 10−5 level.


Optical Down-Conversion In Doped Znse:Tb3+ Nanocrystals, Sandip Das, K. C. Mandal Feb 2013

Optical Down-Conversion In Doped Znse:Tb3+ Nanocrystals, Sandip Das, K. C. Mandal

Faculty Publications

No abstract provided.


The Schrödinger Equation With Friction From The Quantum Trajectory Perspective, Sophya V. Garashchuk, Vaibhav Dixit, Bing Gu, James Mazzuca Feb 2013

The Schrödinger Equation With Friction From The Quantum Trajectory Perspective, Sophya V. Garashchuk, Vaibhav Dixit, Bing Gu, James Mazzuca

Faculty Publications

Similarity of equations of motion for the classical and quantum trajectories is used to introduce afriction term dependent on the wavefunction phase into the time-dependent Schrödingerequation. The term describes irreversible energy loss by the quantum system. The force offriction is proportional to the velocity of a quantum trajectory. The resulting Schrödinger equationis nonlinear, conserves wavefunction normalization, and evolves an arbitrary wavefunction into the ground state of the system (of appropriate symmetry if applicable). Decrease in energy is proportional to the average kinetic energy of the quantum trajectory ensemble. Dynamics in the high friction regime is suitable for simple models of …


Experimental Determination Of Electron-Hole Pair Creation Energy In 4h-Sic Epitaxial Layer: An Absolute Calibration Approach, S. K. Chaudhuri, K. J. Zavalla, K. C. Mandal Jan 2013

Experimental Determination Of Electron-Hole Pair Creation Energy In 4h-Sic Epitaxial Layer: An Absolute Calibration Approach, S. K. Chaudhuri, K. J. Zavalla, K. C. Mandal

Faculty Publications

No abstract provided.


Biogenic Nitrogen Gas Production At The Oxic–Anoxic Interface In The Cariaco Basin, Venezuela, E. Montes, M. A. Altabet, F. E. Muller-Karger, M. I. Scranton, R. C. Thunell, Claudia R. Benitez-Nelson, L. Lorenzoni, Y. M. Astor Jan 2013

Biogenic Nitrogen Gas Production At The Oxic–Anoxic Interface In The Cariaco Basin, Venezuela, E. Montes, M. A. Altabet, F. E. Muller-Karger, M. I. Scranton, R. C. Thunell, Claudia R. Benitez-Nelson, L. Lorenzoni, Y. M. Astor

Faculty Publications

Excess nitrogen gas (N2xs) was measured in samples collected at six locations in the eastern and western sub-basins of the Cariaco Basin, Venezuela, in September 2008 (non-upwelling conditions) and March 2009 (upwelling conditions). During both sampling periods, N2xs concentrations were below detection in surface waters, increasing to ~ 22 μmol N kg−1 at the oxic–anoxic interface ([O2] < ~ 4 μmol kg−1, ~ 250 m). Below the oxic–anoxic interface (300–400 m), the average concentration of N2xs was 24.7 ± 1.9 μmol N kg−1 in September 2008 and 27.5 ± 2.0 μmol N kg−1 in March 2009, i.e., N2xs concentrations within this depth interval were ~ 3 μmol N kg−1 higher (p < 0.001) during the upwelling season compared to the non-upwelling period. These results suggest that N-loss in the Cariaco Basin may vary seasonally in response to changes in the flux of sinking particulate organic matter. We attribute the increase in N2xs concentrations, or N-loss, observed during upwelling to: (1) higher availability of fixed nitrogen derived from suspended and sinking particles at the oxic–anoxic interface and/or (2) enhanced ventilation at the oxic–anoxic interface during upwelling.


Pan-Arctic Distributions Of Continental Runoff In The Arctic Ocean, Cédric G. Fichot, Karl Kaiser, Stanford B. Hooker, Rainer M.W. Amon, Marcel Babin, Simon Bélanger, Sally A. Walker, Ronald Benner Jan 2013

Pan-Arctic Distributions Of Continental Runoff In The Arctic Ocean, Cédric G. Fichot, Karl Kaiser, Stanford B. Hooker, Rainer M.W. Amon, Marcel Babin, Simon Bélanger, Sally A. Walker, Ronald Benner

Faculty Publications

Continental runoff is a major source of freshwater, nutrients and terrigenous material to the Arctic Ocean. As such, it influences water column stratification, light attenuation, surface heating, gas exchange, biological productivity and carbon sequestration. Increasing river discharge and thawing permafrost suggest that the impacts of continental runoff on these processes are changing. Here, a new optical proxy was developed and implemented with remote sensing to determine the first pan-Arctic distribution of terrigenous dissolved organic matter (tDOM) and continental runoff in the surface Arctic Ocean. Retrospective analyses revealed connections between the routing of North American runoff and the recent freshening of …


Isotopic (Δ13c, Δ14c) Analysis Of Organic Acids In Marine Samples Using Wet Chemical Oxidation, Susan Q. Lang, G. L. Früh-Green, S. M. Bernasconi, L. Wacker Jan 2013

Isotopic (Δ13c, Δ14c) Analysis Of Organic Acids In Marine Samples Using Wet Chemical Oxidation, Susan Q. Lang, G. L. Früh-Green, S. M. Bernasconi, L. Wacker

Faculty Publications

We present a method for the isolation and off-line isotope analysis of formate and acetate in marine samples. Organic acids are separated by high performance liquid chromatography and collected in glass Exetainer® screw-capped vials that have been prespiked with an oxidant and flushed with helium. The vials are subsequently heated to convert the organic compounds to CO2 for radiocarbon and δ13C analysis. Small aliquots are sampled for measurement of δ13C by isotope ratio mass spectrometry, whereas the majority of the CO2 is saved for radiocarbon analysis by accelerator mass spectrometry using a gas ion …


Simulation Studying Effects Of Multiple Primary Aberrations On Donut-Shaped Gaussian Beam, Chen Zhang, K. Wang, J. Bai, Y. Liu, Guiren Wang Jan 2013

Simulation Studying Effects Of Multiple Primary Aberrations On Donut-Shaped Gaussian Beam, Chen Zhang, K. Wang, J. Bai, Y. Liu, Guiren Wang

Faculty Publications

In this paper, we demonstrate the variation of donut-shaped depletion pattern which influenced by multiple primary aberrations. The simulation is base on a common stimulation emission of depletion (STED) system composed by Gaussian laser and vortex phase plate. The simulation results are helpful guidelines for analyzing the aberration of depletion patterns in real situations.


An Acid Catalyzed Reversible Ring-Opening/Ring-Closure Reaction Involving A Cyano-Rhodamine Spirolactam, H. Li, H. Guan, X. Duan, J. Hu, Guiren Wang, Qian Wang Jan 2013

An Acid Catalyzed Reversible Ring-Opening/Ring-Closure Reaction Involving A Cyano-Rhodamine Spirolactam, H. Li, H. Guan, X. Duan, J. Hu, Guiren Wang, Qian Wang

Faculty Publications

Cyanamide was introduced into the rhodamine spirolactam framework to produce a colorless and non-fluorescent compound RBCN. It shows a reversible ring-opening/ring-closure process in response to the solution pH, which exhibits an “ON/OFF” switching in its fluorescence. Different from other rhodamine-type dyes, the ring-open form of RBCN is stable in protic solvents under neutral, near neutral and basic conditions, showing a pink color and very strong fluorescence. We also demonstrated the potential of RBCN in live cell imaging.


Applications Of High Throughput (Combinatorial) Methodologies To Electronic, Magnetic, Optical, And Energy-Related Materials, Martin L. Green, Ichiro Takeuchi, Jason R. Hattrick-Simpers Jan 2013

Applications Of High Throughput (Combinatorial) Methodologies To Electronic, Magnetic, Optical, And Energy-Related Materials, Martin L. Green, Ichiro Takeuchi, Jason R. Hattrick-Simpers

Faculty Publications

High throughput (combinatorial) materials science methodology is a relatively new research paradigm that offers the promise of rapid and efficient materials screening, optimization, and discovery. The paradigm started in the pharmaceutical industry but was rapidly adopted to accelerate materials research in a wide variety of areas. High throughput experiments are characterized by synthesis of a “library” sample that contains the materials variation of interest (typically composition), and rapid and localized measurement schemes that result in massive data sets. Because the data are collected at the same time on the same “library” sample, they can be highly uniform with respect to …