Physical Sciences and Mathematics Commons^™

Intramolecular Spin-Orbit Coupling In Naphthalene Analogs, Francis Elliott Shoup Iii

Chemistry and Chemical Biology ETDs

The objective of this study was to gain additional insight into the phenomenon of spin-orbit coupling in molecules by examining the intramolecular mechanisms responsible for the phosphorescence of certain types of molecules. Spectrocopic investigations of a series of aromatic hydrocarbons, aromatic heterocyclics, and some of their halogen derivatives are reported. Experimental measurements included absorption spectra, total emission spectra, polarized emission spectra, obtained by the method of photoselection, and radiative lifetimes.

Crystal Field Splitting In Rare Earth Chelates, Walter George Perkins

Chemistry and Chemical Biology ETDs

Investigations of ligand field effects in the spectra of trisdibenzoyl­methide, trisbenzoylacetonate, and trisacetylacctonatc chelates of trivalent ytterbium and thulium are reported. Chelate absorption and luminescence spectra corresponding to intra-4f electronic transitions exhibit line split­tings similar in magnitude to the crystal field splitting observed in the spectra of inorganic complexes of the rare earth ions.

Absorption spectra of carbon tetrachloride solutions of all the che­lates studied were measured in the visible and near infrared regions. Each ytterbium chelate exhibits an absorption band at 9800A, consisting of three well-resolved peaks. Thulium intra-4f absorption bands appear at 4700A, 6800A, 8000A, 12000A, and 17000A. …

The Atmospheric Neutron Spectrum At High Altitudes, Michael Sydor

Physics & Astronomy ETDs

A measurement of neutron flux in the range 30 -130 Mev at altitudes of 10, 670 feet and 100,000 feet was performed with a directionally sensitive proton recoil detector. The detector consisted of two counters of scintillator plastic which measured dE/dx and energy of proton recoils originating in a third plastic scintillator. Charged particles were eliminated by a guard counter. Energy calibration was performed with charged cosmic ray particles; efficiency and angular sensitivity were calculated. The angular response was checked at 10,670 feet, where a reasonable angular distribution of cosmic ray neutrons could be assumed.

Four balloon flights to 100,000 …

Spectroscopic Studies Of Tris (2,2'-Bipyridine)- And Tris (I, 10-Phenanthroline) Iron (Ii), -Ruthenium (Ii), And -Osmium (Ii)., Sonia Lee Sabath

Chemistry and Chemical Biology ETDs

The tris(2,2'-bipyridine)- and tris(l,10-phenanthroline) complexes of iron(II), ruthenium(II), and osmium(II) were synthesized, purified, and characterized by analyses. The solution absorption spectra of the compounds were measured both in the ultraviolet and visible regions. The observed ultraviolet absorption bands of the ruthenium and osmium complexes were assigned entirely to transitions, the prominent bands being assigned to ligand (perturbed) transitions by comparison with the published assignments of the corresponding bands in analogous iron complexes. The visible absorption spectra for iron(II) and ruthenium(II) complexes were attributed entirely to singlet-singlet charge transfer transitions. The strong visible absorption bands of osmium(II) complexes were also assigned …

The Synthesis And Evaluation Of Some 2-Arylindenes And 2-Aryl-3h-Benz[E]Indenes As Liquid Scintillation Solutes, James Leslie Schornick

Chemistry and Chemical Biology ETDs

A scintillator, in the chemical sense, is a system which can convert radioactive particle energy to visible and near ultraviolet photon energy. A phenomenon related to scintillation is fluorescence. The difference between scintillation and fluorescence is the source of excitation energy. In the case of scintillation, the exciting energy comes from radioactive particles, while in fluorescence, the exciting energy comes from ultraviolet light.

On The Solar Magnetic Field In Inter-Planetary Space, Jacqueline H. Hill

Earth and Planetary Sciences ETDs

The purpose of this thesis is to determine, experimentally and theoretically, an axially symmetric current distribution which would simulate the currents believed to flow in interplanetary space around the sun. The general magnetic field of the sun is assumed to originate as a dipole field which induces currents in the plasma of the solar atmosphere. The dipole field is in turn modified by the induced currents. This phenomenon is often described in terms or a diamagnetism of the plasma. In the limiting case, this diamagnetism would almost completely prevent the inducing field from penetrating the plasma.

Force-On-The-Wall Calculations For One-Dimensional Dense Gases With Intermolecular Potentials., Thomas Daniel Butler

Physics & Astronomy ETDs

The theoretical study of dense gases with strong intermolecular forces is impeded by lack of sufficient experimental which to compare predictions of the properties. High speed computers can supply this information by calculating the detailed dynamics of molecular assemblages, thereby taking the place of an actual physical experiment. This information supplied by the computers not only can test the validity of existing theories, but also it can indicate directions for possible im­provement in the theoretical approximations.

In order to show the adaptability of computers to this task, this thesis deals with the theoretical and computer-experimental study of the force exerted …

The Diffraction Of Polarized Light By A Conducting Straight Edge In The Geometrical Shadow, Richard W. Morris

Physics & Astronomy ETDs

Theory predicts that the diffraction pattern of a conduction straight edge will show deviations from the diffraction pattern of a non-conductor, and further, that these deviations will depend upon the polarization of the incident light. In this experiment the diffraction of polarized, coherent light from a monochromatic source by a metallic straight edge was studied in a region near the edge of the geometrical shadow. Two orientations of the polarization were used: one with the E vector of the polarized light parallel to the diffracting edge, and the other with the E vector perpendicular to the diffracting edge. Three different …

Determination Of The Orientation Of Air-Borne Instrumentation, David G. Miller

Physics & Astronomy ETDs

Air-borne devices have been used as a means of observation and collection of information in meteorology and atmospheric physics for many years. Only in recent years, however, has the increasing use of such devices been made for astronomical observations. A balloon-borne telescope at 80,000 to 100,000 feet, for example, has many advantages: the distortion, absorption and scattering of light by the atmosphere and the dependence on weather conditions, which plagues earthbound observations, are essentially eliminated. It seems apparent that astronomical observation will eventually be able to be made only by air­borne or satellite observatories. The decline in usefulness of the …

Single Crystals Of "Globular Molecules" From The Melt, Charles A. Aeby

Physics & Astronomy ETDs

This thesis is an investigation of the possibility of growing single crystals of dl-camphene, d-camphor, and cyclohexanol. These are organic compounds, characterized by "globular molecules", which form plastic crystals immediately below their melting point. Single crystals were desired in order to study, by ultra-sound techniques, properties pertinent to the evaluation of the elastic constants of these crystals. Primary emphasis was placed on growing crystals of dl-camphene, since it is conveniently handled at room temperatures.

Methods of growth from the melt were chosen because of the relatively fast growth rates, compared to vapor or solution techniques. Secondary considerations were simplicity of …

Large Angle Scattering Of Polarized Light By A Straight Edge, Theodore S. Fahlen

Physics & Astronomy ETDs

The purpose of this experiment was to observe the light diffracted into the geometrical shadow of a sharp and a blunt metallic straight edge using a polarized, very intense, highly coherent light source. The light source used was a ruby laser, and a Nicol prism was used to linearly polarize the laser light. Two polarizations of the laser beam were used: One with the E vector of the incident beam oriented parallel to the edge of the straight edge, and the other with the E vector oriented perpendicular to the edge. One photomultiplier tube was used to monitor the pulsed …

Phase Changes In Solid Cyclohexanol, William T. Griffith

Physics & Astronomy ETDs

Cyclohexanol is one of a group of organic compounds which exist in a “plastic crystal" solid phase, which is intermediate in its properties between the liquid phase and the solid phases stable at lower temperatures. It has been well established that the odd properties of the plastic crystal phase are due to the relatively unhindered rotation of the molecules about their lattice positions. At temperatures often considerably below the freezing point, these compounds undergo a solid-solid phase transformation in which this rotational freedom is lost. The heats and entropies of transformation at this lower transition point are generally larger than …

The Geology Of The Northern And Eastern Parts Of The Ladron Mountains, Socorro County, New Mexico., Bruce A. Black

Earth and Planetary Sciences ETDs

The Laron Mountains are & westward-tilted fault block and an important western bounding structure of the Rio Grande depression in the Albuquerque-Belen basin. The main massif is a complex of both igneous and metamorphic Precambrian rocks. It consists of a thick sequence of steeply east-dipping quartzite & and schists which are predominantly a product of low- to medium- grade regional Precambrian metamorphism. Granitic gneiss is ptygmatically folded with abundant schist remnant in a large area on the eastern flank of the mountains and represents an ultrametamorphic product of anatexis. All metamorphic rocks have been invaded by two later Precambrian granites. …

The Effect Of Cesium Vapor On The Emission Characteristics Of Uranium Carbide At Elevated Pressures, Philip W. Kidd

Physics & Astronomy ETDs

The saturated emission current from uranium carbide in the presence of cesium vapor were measured for four different bath temperatures: 167˚C, 197˚C, 227˚C, and 250˚C (the cesium arrival rates μ_a, in atoms/cm², were 3x10¹⁸, 1x10¹⁹, 3x10¹⁹ and 6x10¹⁹). The measurements were made with a “plasma anode” type tube immersed in a constant temperature oil bath. The design of the tube is shown, and the electronic circuitry is given with an explanation of the method of measurement. The experimental data for “electron emission vs 1000/T” was plotted for the experimental …

Some Information - Theoretical And Empirical Techniques In Statistical Inference, Chaitanya Swarup

Mathematics & Statistics ETDs

This study is divided into two seemingly disjoint parts -- one containing EMPIRICAL (Bayesian and Non-Bayesian) approach and the second containing INFORMATION-THEORETICAL techniques in problems of statistical estimation and tests of hypotheses. But in the end, both approaches have been brought together for solving ENCODING problems of COMMUNICATION THEORY to unify the whole dissertation.

Slope Deposits Of The Pennsylvanian Haymond Formation, Marathon Region, Texas, Walter E. Dean Jr.

Earth and Planetary Sciences ETDs

The Haymond Formation of the Marathon basin, Texas consists mainly of a sequence of more than 12,000 siltstone-shale couplets which, combined with the similar couplets of the older Tesnus Formation, form a sequence of "flysch" sediments more than 10,000 feet thick deposited on the eastern slope of the subsiding Llanoria geosyncline. The Haymond Formation contains no diagnostic fossils; its age is known only as Lower Pennsylvanian, probably Atokan.

Potential Diuretic Agents;The Synthesis Of 4, 7-Disubstituted Derivatives Of 2-Phenylimidazo [4, 5-D]Pyridazine., Miriam P. Malm

Chemistry and Chemical Biology ETDs

"The maintenance of the water balance of an organism is of prime importance for its physiologic well-being." (1) Water, which composes approximately two-thirds of the entire human body weight, is the fluid in which all vital chemical reactions occur. A loss of 25 percent of body water usually proves fatal. The inherent physical and chemical properties of water render it as the ideal fluid to meet the physiological demands of the organism.