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Metastable Anions Of Dinitrobenzene: Resonances For Electron Attachment And Kinetic Energy Release, A. Mauracher, S. Denifl, A. Edtbauer, M. Hager, M. Probst, Olof E. Echt, T. D. Maerk, P. Scheier, T. A. Field, K. Graupner

Physics & Astronomy

Attachment of free, low-energy electrons to dinitrobenzene (DNB) in the gas phase leads to DNB as well as several fragment anions. DNB, (DNB-H), (DNB-NO), (DNB-2NO), and (DNB-NO(2)) are found to undergo metastable (unimolecular) dissociation. A rich pattern of resonances in the yield of these metastable reactions versus electron energy is observed; some resonances are highly isomer-specific. Most metastable reactions are accompanied by large average kinetic energy releases (KER) that range from 0.5 to 1.32 eV, typical of complex rearrangement reactions, but (1,3-DNB-H)(-) features a resonance with a KER of only 0.06 eV for loss of NO. (1,3-DNB-NO)(-) offers a rare …