Physical Sciences and Mathematics Commons^™

Manganese Oxide Mineral Phases Produced At Room Temperature Under Acidic Conditions Investigated With Xrd, Tem, Sem, Eds, And Bet, Nancy R. Birkner

UNLV Theses, Dissertations, Professional Papers, and Capstones

This thesis concerns characterization of synthetic manganese oxides belonging to mineral phases known as Birnessite and Cryptomelane. Presented here are the results of an experiment designed to examine the influence of sodium, potassium, chloride, and sulfate ions on the reduction of potassium permanganate under acidic conditions at room temperature to produce Birnessite and Cryptomelane. The experiments used KMnO4 as the source of Mn and the resulting Birnessite and Cryptomelane precipitates were washed with 18 Mn/cm NANOpure water at the end of syntheses. Several state-of-the-art solid state techniques were used to characterize the Mn-based oxide mineral phases. Based on the literature …

Democracy And The Environment In Latin America, Javier Albert Escamilla

UNLV Theses, Dissertations, Professional Papers, and Capstones

This study examines the ability of democratic and non-democratic states alike to protect the environment. Democracy has long been an important concept in the study of politics and environmental protection is an increasingly important issue in world politics. Advocates of democracy claim democratic states are better able to protect the environment than non-democracies. In contrast there are those that argue democracy's emphasis on individual rights leads to excessive resource consumption. This thesis employs a mixed methods approach to determine if democratic countries protect the environment more than their non-democratic counterparts. In short democracies do protect the environment better than non-democracies …

Evaluation Of Low-Temperature Fluoride Routes To Synthesize Actinide Nitrides And Oxide Solid Solutions, Gunanda Waduge Chinthaka Silva

UNLV Theses, Dissertations, Professional Papers, and Capstones

Actinide mononitrides have been considered as a possible nuclear fuel for the Generation-IV nuclear reactor systems. In the process of evaluating these actinide mononitrides as nuclear fuel, it is important to study different chemical and physical characteristics of these compounds. Synthesis of the materials is thus important. Carbothermic reduction is one of the techniques that have been used to synthesize actinide mononitrides. In this method, a mixture of actinide oxide such as UO ₂ and excess carbon is heat treated at temperatures greater than 1700 °C under a nitrogen atmosphere. The technique is however not promising in synthesizing the actinide …

Substrate Monitoring, Contaminant Monitoring, And Educational Outreach On Quagga Mussels (Dreissena Bugensis) In Lake Mead, Nevada, Sara Ann Mueting

UNLV Theses, Dissertations, Professional Papers, and Capstones

The invasive species, the quagga mussel, Dreissena bugensis, was found in Lake Mead, Nevada-Arizona, USA on January 6, 2007. Since then, researchers have been attempting to quantify the amount of damage these mussels will cause to the lower Colorado River basin. Three projects were implemented in this thesis to research the quagga mussel in Lake Mead. First, a study to determine which types of substrates quagga mussels will grow on preferentially was conducted. Six different substrates, Acrylonitrile Butadiene Styrene (ABS) plastic, High Density Polyethylene (HDPE) plastic, Concrete Underlayment Board (CUB), aluminum, stainless steel and fiberglass, were placed in the Boulder …

Trophic Interactions Associated With Indroduction Of The Invasive Quagga Mussel In Lake Mead, Nevada, Eric Michael Loomis

UNLV Theses, Dissertations, Professional Papers, and Capstones

The ecology of Lake Mead is experiencing an uncertain future since the documented arrival of the invasive quagga mussel. Interactions among constituents of the food web will undoubtedly be altered over time, adversely affecting the popular sport fishery. This study is the first in Lake Mead to present historic trends in lower trophic interactions among threadfin shad and zooplankton before, and shortly after, the arrival of quagga mussels. Shad stomach content analysis revealed cladocerans and copepods were the dominant identifiable food items in Las Vegas Bay and Overton Arm of Lake Mead. Baseline energetics data through the use of stable …

A Survey Of Monge Properties, Swetha Sethumadhavan

UNLV Theses, Dissertations, Professional Papers, and Capstones

Monge properties play an important role in theoretical computer science. Many greedy algorithms are based on such properties, as is speedup in dynamic programming. Monge properties are simple monotonicity properties which are observed and used in various settings such as resource optimization, computational geometry, statistical sampling, computational biology and coding.

Going Green In The Hospitality Industry, Christina Wilson Micioni

UNLV Theses, Dissertations, Professional Papers, and Capstones

The purpose of this research is to examine whether a hotel’s greening efforts are a reason why everyday guests or hospitality professionals choose a hotel. Do meeting planners and business travelers expect certain things while staying at a hotel? Do the personal greening activities of a guest affect their hotel stay? This will also include the housekeeping needs of the guests and why they choose the hotel. The objective of the research will be to discover whether there is guest data to support the need for hotels to become green establishments.

Water Quality Changes In A Constructed Wetland At The Springs Preserve In Las Vegas, Nevada, Aaron Mathis Miller

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Springs Preserve near downtown Las Vegas, Nevada contains a seven-acre constructed wetland. Springs Preserve managers are planning to use water from the constructed wetland to irrigate creeks immediately north of the wetland. These creeks will be used by a variety ofaquatic wildlife, including endangered amphibians sensitive to harmful metalloids, such as selenium, lead, and arsenic.

In an attempt to answer toxicological questions about contaminant concentrations in the constructed wetland, three metals and metalloids (selenium, arsenic, and lead), two nutrients (nitrogen and phosphorus), and the major ionic species were analyzed at four sampling locations for aqueous concentrations, in two separate …

A Study Of Relevance Feedback In Vector Space Model, Deepthi Katta

UNLV Theses, Dissertations, Professional Papers, and Capstones

Information Retrieval is the science of searching for information or documents based on information need from a huge set of documents. It has been an active field of research since early 19^th century and different models of retrieval came in to existence to cater the information need.

This thesis starts with understanding some of the basic information retrieval models, followed by implementation of one of the most popular statistical retrieval model known as Vector Space Model. This model ranks the documents in the collection based on the similarity measure calculated between the query and the respective document. The user …

Magnetic Sensors For Biodetection, Pranjali Vineet Sneha Deshpande

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objective of thesis is to design magnetic sensor for detection of nanoparticles. Recently integrating the standard laboratory techniques into integrated system on chip is growing attention. Recent development is to combine magnetic markers and magnetoresistive sensors together in magnetic chip. In this thesis two magnetoresistive sensors were studied and designed.

By applying magnetic fields, magnetic nanoparticles can be manipulated on-chip, which can be utilized to pull the molecules to specific binding sites or to test the binding strength and distinguish between specifically and non-specifically bound molecules

Magnetoresistive sensors are compatible with the semiconductor industry which provides electronic signal directly …

The Influence Of Carbon Source Types And Nitrate On The Performance Of The Enhanced Biological Phosphorus Removal Systems, Shamim Ara Begum

UNLV Theses, Dissertations, Professional Papers, and Capstones

This research focuses on two issues in enhanced biological phosphorus removal (EBPR). The first issue encompasses the effect of the type of carbon sources (i.e. volatile fatty acids and non volatile fatty acids) on the microbiology of EBPR. The second issue deals with the influence of denitrification on EBPR. Few studies have been performed to investigate these two issues. The recent findings on these areas are summarized below to establish the knowledge gaps this dissertation attempted to address. Details on the specific findings can be found in the literature review portion of this proposal.

Identifying Biomarkers For Resistance To Novel Cisplatin Analogues In Human Lung, Breast And Prostate Cancers, Becky Michelle Hess

UNLV Theses, Dissertations, Professional Papers, and Capstones

Cisplatin is a common therapeutic agent used in cancer treatment. Unfortunately, resistance to cisplatin in addition to severe side effects limits its use in cancer treatment. Two novel cisplatin analogues, 4DB and 4TB were shown to have varying cytotoxicity in lung, breast and prostate cancer cells. The hypothesis for this study states that the differences in 4DB and 4TB cytotoxicity among different tissue types is due to the type and efficiency of DNA repair mechanisms involved in response to these drugs.

To test the hypothesis, proteins involved in the rate limiting step of nucleotide excision repair (NER) and mismatch repair …

Case Study: Feasibility Analysis Of Renewable Energy Supply Systems In A Small Grid Connected Resort, Jody Robins

UNLV Theses, Dissertations, Professional Papers, and Capstones

This paper presents a case study on the feasibility of a small grid connected resort in the marine west coast climate of Canada to implement a renewable energy supply system. The current industry conditions of three renewable energy systems are explored including small and large wind energy conversion systems, solar photovoltaic cell systems, and energy cell systems. Furthermore, these three systems are evaluated using the power load, wind, and solar radiation information from a specific resort. The renewable energy source assessment and optimization software HOMER (National Renewable Energy Laboratory, US) is used to evaluate the costs and benefits of each …

Flowing Toward Sustainability: Two Stream Adjudications Analyzed Under The Iad Framework, Nancye Lou Bethurem

UNLV Theses, Dissertations, Professional Papers, and Capstones

One of the most significant problems impacting the western United States today is the lack of naturally occurring water resources, especially during this period of drought and explosive population growth. This has led to intense competition over water use and ownership in the arid and semi-arid regions of the United States. During this period of water resource scarcity, it is extremely important to determine the ownership of water rights in order to implement optimal management systems. Most western states use a system of "general stream adjudications" to make water rights ownership determinations.

General stream adjudications are legal proceedings used to …

The Synthesis And Systematic Evaluation Of Modified Polymeric Foams And Electrically Conductive Polyimide/Carbon/Metal Films, John Macharia Kinyanjui

UNLV Theses, Dissertations, Professional Papers, and Capstones

Thermally processed PU foams are examined as a function of processing temperatures (25, 45, 65, and 85°C) at the side, middle, and center of a simple cylindrical mold. The PU foams show both chemical and morphological differences as a function of the processing temperature and radial position within the mold. Thermal degradation of uretoneimine structures, the emergence of carbodiimide structures, and extent of reaction of isocyanate groups are measured using photoacoustic FTIR spectroscopy. Chemical gradients and morphology differences between the side, middle, and center of the molded foam are observed for all processing temperatures. The data indicate that thermal activation …

The Sheep Pass Formation, A Record Of Late Cretaceous And Paleogene Extension Within The Sevier Hinterland, East-Central Nevada, Peter Alexander Druschke

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Sevier hinterland of western North America is considered by many to be an ancient proxy for the modern Andean Puna-Altiplano or Tibetan Plateau. However, controversies exist as tectonic setting and overall paleogeography of the Sevier hinterland during the Late Cretaceous and Paleogene. The Sheep Pass Formation type section within the southern Egan Range of east-central Nevada comprises a > 1 km thick sedimentary succession spanning the latest Cretaceous to Eocene, and provides a rare opportunity to test prevailing tectonic and paleogeographic models for the Sevier hinterland. New 1:12,000 scale field mapping inthe southern Egan Range indicates that up to three …

Uncertainty, Sensitivity And Geostatistical Studies Of Flow And Contaminant Transport In Heterogeneous Unsaturated Zone, Feng Pan

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objectives of this study are: (1) to develop a methodology of estimating probability density functions (PDFs) of unsaturated hydraulic parameters when field samples are sparse, (2) to evaluate the predictive uncertainties in flow and contaminant transport due to parameter uncertainties in the layer- and local-scale heterogeneities of hydraulic parameters in unsaturated zone (UZ), (3) to investigate the contributions of the parameter uncertainties to the flow and transport uncertainties, and (4) to estimate the spatial correlation structures of hydraulic parameters by incorporating prior information and site measurements.

At layer scale, the uncertainty assessment of flow and contaminant transport in UZ …

Turn Constrained Path Planning Problems, Victor M. Roman

UNLV Theses, Dissertations, Professional Papers, and Capstones

We consider the problem of constructing multiple disjoint paths connecting a source point s to a target point t in a geometric graph. We require that the paths do not have any sharp turn angles. We present a review of turn constrained path planning algorithms and also algorithms for constructing disjoint paths. We then combine these techniques and present an O(nlogn) time algorithm for constructing a pair of edge disjoint turn constrained paths connecting two nodes in a planar geometric graph. We also consider the development of a turn constrained shortest path map in the presence of …

Desert Varnish As An Indicator Of Modern-Day Air Pollution In Southern Nevada, Piotr Nowinski

UNLV Theses, Dissertations, Professional Papers, and Capstones

Rock varnish, often called desert varnish, is a slow-growing, manganese-rich coating that accumulates on exposed rock surfaces. The mechanism of varnish formation is not fully understood, however, most authors agree that varnishes derive their components from the atmosphere. The main goal of this study was to demonstrate the potential use of desert varnish as a passive environmental monitor of present and past atmospheric pollution. Analysis of varnishes is a new field that can potentially provide records of pre-anthropogenic levels of atmospheric metals and other environmental pollutants. To evaluate the potential of desert varnish as an environmental monitoring tool, the following …

Soil Moisture And Water Stage Estimation Using Precipitation Radar, Sumit Puri

UNLV Theses, Dissertations, Professional Papers, and Capstones

In south-western United States, soil moisture data is important for drought studies in the region which is experiencing a drought for many years, whereas in South Florida, water stage data is required by hydrologists to monitor the hydrological flow in wetlands. Soil moisture data and water stage data are not sufficiently available due to sparse monitoring stations. Installation of dense measuring stations over an extended area is costly and labor intensive. Therefore, there is a need to develop an alternative method of measuring soil moisture and water stage. Microwave remote sensing has proven to be a useful tool in the …

An Evaluation Of Lead Hazards In Pre-1978 Residental Housing Within Clark County, Nevada, Usa, Erika Raquel Torres

UNLV Theses, Dissertations, Professional Papers, and Capstones

Lead poisoning remains a public health concern due to leads persistence in the environment from anthropogenic uses. Initial efforts to address the impacts of lead on vulnerable communities have included secondary prevention measures which typically occur after a child has been poisoned. However, in recent years there has been a pragmatic shift toward primary prevention efforts.

This study evaluates lead hazards identified through primary prevention activities in residential housing within Clark County, Nevada, USA. It is the first study to systematically address and evaluate pre-1978 housing in Southern Nevada. Risk assessments were conducted in 81 dwellings built prior to 1979 …

Controlled Functionalization Of Crystalline Polyolefins And Their Application In Soluble Polymer Support, Jihoon Shin

UNLV Theses, Dissertations, Professional Papers, and Capstones

Functionalization of polyolefins has been recognized as a useful methodology for the generation of new materials with a wide range of applications. Recently, crystalline or semi-crystalline polyolefins have drawn increasing attention in both industrial and academic fields as one of the most interesting engineering plastics, due to their remarkable physical and mechanical properties. This dissertation describes: (1) novel methods for the direct postfunctionalization of crystalline polyolefins to introduce functionality, (2) characterizations for the functionalized polymers to analyze their structures, molecular-weight properties, thermal properties, and hydrophilicity, and (3) an application of the modified crystalline polystyrene as a soluble polymer support for …

Substituent Effect On The Electronic And Assembling Properties Of Asymmetric Phenazine Derivatives, Bin Cao

UNLV Theses, Dissertations, Professional Papers, and Capstones

Currently, one-dimensional (1-D) nanostructures have drawn much interest because of their potential applications for nanoscale optoelectronic devices. Self-assembly (SA) based on π-conjugated systems through various intermolecular interactions has been widely used to produce 1-D nanostructure. Morphology of the assembled structures can be modified by incorporating substituents, which provide additional secondary interactions. Meanwhile, those substituents also influence the electronic properties of the molecules. Previous studies have made little effort to systematically study subsistent effects on both electronic and SA properties.

The primary objective of this research is to generate controllable 1-D structures through SA, and to provide a fundamental understanding of …

Statistical Inferences For Functions Of Parameters Of Several Pareto And Exponential Populations With Application In Data Traffic, Sumith Gunasekera

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this dissertation, we discuss the usability and applicability of three statistical inferential frameworks--namely, the Classical Method, which is sometimes referred to as the Conventional or the Frequentist Method, based on the approximate large sample approach, the Generalized Variable Method based on the exact generalized p -value approach, and the Bayesian Method based on prior densities--for solving existing problems in the area of parametric estimation. These inference procedures are discussed through Pareto and exponential distributions that are widely used to model positive random variables relevant to social, scientific, actuarial, insurance, finance, investments, banking, and many other types of observable phenomena. …

Zirconia-Magnesia Inert Matrix Fuel And Waste Form: Synthesis, Characterization And Chemical Performance In An Advanced Fuel Cycle, Kiel Steven Holliday

UNLV Theses, Dissertations, Professional Papers, and Capstones

There is a significant buildup in plutonium stockpiles throughout the world, because of spent nuclear fuel and the dismantling of weapons. The radiotoxicity of this material and proliferation risk has led to a desire for destroying excess plutonium. To do this effectively, it must be fissioned in a reactor as part of a uranium free fuel to eliminate the generation of more plutonium. This requires an inert matrix to volumetrically dilute the fissile plutonium. Zirconia-magnesia dual phase ceramic has been demonstrated to be a favorable material for this task. It is neutron transparent, zirconia is chemically robust, magnesia has good …

Two-Tank Indirect Thermal Storage Designs For Solar Parabolic Trough Power Plants, Joseph E. Kopp

UNLV Theses, Dissertations, Professional Papers, and Capstones

The performance of a solar thermal parabolic trough plant with thermal storage is dependent upon the arrangement of the heat exchangers that ultimately transfer energy from the sun into steam. The steam is utilized in a traditional Rankine cycle power plant. The most commercially accepted thermal storage design is an indirect two-tank molten salt storage system where molten salt interacts with the solar field heat transfer fluid (HTF) through a heat exchanger. The molten salt remains in a closed loop with the HTF and the HTF is the heat source for steam generation. An alternate indirect two tank molten salt …

Efficient Clustering Techniques For Managing Large Datasets, Vasanth Nemala

UNLV Theses, Dissertations, Professional Papers, and Capstones

The result set produced by a search engine in response to the user query is very large. It is typically the responsibility of the user to browse the result set to identify relevant documents. Many tools have been developed to assist the user to identify the most relevant documents. One such a tool is clustering technique. In this method, the closely related documents are grouped based on their contents. Hence if a document turns out to be relevant, so are the rest of the documents in the cluster. So it would be easy for a user to sift through the …

X-Ray Diffraction Study Of Dysprosium Single Crystal Samples In A Diamond Anvil Cell (Dac), Ognjen Grubor-Urosevic

UNLV Theses, Dissertations, Professional Papers, and Capstones

X-ray diffraction is the basis of crystallography, the study of the structure of crystals. It uses X-rays of a wavelength on the order of the size of atoms, so it can resolve the positions of individual atoms in a crystal. Illuminating the crystal with a well-collimated X-ray beam produces X-rays diffracted in a certain direction for a specific crystal orientation. By analyzing the relative phase of the incoming and outgoing scattered X-rays, the unique arrangements of atoms can be determined and the structure of the crystal can be solved.

There is a long standing controversy regarding the crystal structures and …

In Situ Element Quantification In The Hydrothermal Diamond Anvil Cell Using Synchrotron X-Ray Fluorescence With Applications Toward Subduction Zone Processes, Steven Joseph Maglio

UNLV Theses, Dissertations, Professional Papers, and Capstones

Yttrium is used in geochemical investigations of arc volcanics and metamorphic geothermometers. The ability to use Y as a geochemical tool is predicated on an understanding of the mobility of Y during fluid-saturated conditions attending metamorphic and igneous processes. The goal of this work was to use the hydrothermal diamond anvil cell (HDAC) and synchrotron radiation X-ray fluorescence to quantify, in situ, the concentration of Y in aqueous fluids at 2-5 GPa and 650 - 800 °C; conditions likely at the oceanic lithosphere - mantle wedge interface in subduction zones. Previous studies have used modified diamond anvils which limits their …

Optimization Of Channel Geometry In A Proton Exchange Membrane (Pem) Fuel Cell, Jephanya Kasukurthi

UNLV Theses, Dissertations, Professional Papers, and Capstones

Bipolar plates are the important components of the PEM fuel cell. The flow distribution inside the bipolar plate should be uniform. Non-uniform flow distribution inside the bipolar leads to poor performance of the fuel cell and wastage of expensive catalyst. A single channel PEM fuel cell is taken and electrochemical analysis is carried out on it. The results are compared with the available published experimental data obtained by other research group, and they are found to be in good agreement. A baseline design of the bipolar plate is taken and numerical analysis is carried out. The results show that the …