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Investigating The Unique Reactivity Of Novel Hx (X=Cl, Br) Reagents With Alkenes And Alkynes., Rene E. Ebule
Investigating The Unique Reactivity Of Novel Hx (X=Cl, Br) Reagents With Alkenes And Alkynes., Rene E. Ebule
Electronic Theses and Dissertations
The addition of hydrogen halides to carbon-carbon unsaturated systems is a classic synthetic transformation that gives rise to a variety of halogenated products as well as building blocks.1 The different routes to achieve hydrohalogenation make use of the hydrogen halides either in the gaseous form2 or in solution3, or their surrogates4. Only second to dihalogens, hydrogen halides are the most atom efficient source of halogenation. However, hydrogen halides are reactive gases at ambient temperature, posing a major challenge in their application. Handling gaseous hydrogen halide reagents requires expert knowledge and specialized equipment. We have …