Physical Sciences and Mathematics Commons^™

Development Of A Multiband Remote Sensing System For Determination Of Unsaturated Soil Properties, Cyrus D. Garner

Graduate Theses and Dissertations

A multiband system including active microwave sensing and visible-near infrared reflectance spectroscopy was developed to measure unsaturated soil properties in both field and laboratory environments. Remote measurements of soil volumetric water content (θv), soil water matric potential (ψ), and soil index properties (liquid limit [LL], plastic limit [PL], and clay fraction [CF]) were conducted. Field-based measurement of θv was conducted using a ground-based radar system and field measurements within 10 percentage points of measurements acquired with traditional sampling techniques were obtained. Laboratory-based, visible and near infrared spectroscopy was found to be capable of obtaining empirical, soil specific regression functions (partial …

Understanding N-Nitrosodimethylamine Formation In Water: Chloramine Chemistry, Kinetics, And A Proposed Reaction Pathway, Huong Thu Pham

Graduate Theses and Dissertations

The formation of N-nitrosodimethylamine (NDMA) in drinking water systems is a concern because of its potential carcinogenicity and occurrence at toxicologically relevant levels. The postulated mechanism for NDMA formation involves a substitution between dichloramine and amine-based precursors to form an unsymmetrical dimethylhydrazine (UDMH), which is then oxidized by ground-state molecular oxygen to form NDMA. However, this latter reaction is spin forbidden, thus likely occurs at a slow rate. It is hypothesized that the reaction between monochloramine and hydroxylamine (a nitrification product) may form an intermediate, which is involved in the NDMA formation pathway. This intermediate may also be generated from …

Asbestos Cement Pipe Condition Assessment And Remaining Service Life Prediction, Abiy Melles Ghirmay

Graduate Theses and Dissertations

This research details a condition assessment of asbestos cement (AC) pipe within in the Bella Vista Village Property Owners Association water distribution system. Bella Vista Village contains appropriately 300 miles of AC pipe with nominal diameters from 6-14 inch. The goal of the research is to determine the current condition of AC pipe within the system and predict future performance of the pipes. AC pipe samples were obtained from 23 locations disturbed across the distribution system with nominal pipe diameters of 6-8 inch. Estimates of current level of degradation were obtained using phenolphthalein staining and hardness measurements of each sample. …

Trend Analysis Of Water Quality In Northwest Arkansas Streams Reflects Changes In The Watershed, Zachary Paul Simpson

Graduate Theses and Dissertations

Watershed export of nutrients, sediments, and chemicals impacts receiving waters. Changes within the watershed (e.g., anthropogenic or climatic) can alter the transport of constituents in streams. Stream monitoring is crucial for understanding these effects. This study developed a potential improvement to flow-adjusting constituent concentrations in streams, an important step of analyzing monitoring data in lotic systems for trends. The method incorporates a K-fold cross-validation procedure to optimize a model explaining the relationship between the concentration and streamflow, thus providing a valuable tool to researchers in water quality. Additionally, two case studies were conducted on watersheds located in northwest Arkansas using …

Evaluating A Measure-Calculate Method For Determining Sediment Oxygen Demand In Lakes, Adrian Beirise

Graduate Theses and Dissertations

A steady-state mass diffusion model used with simple measurable and calculable inputs for determining sediment oxygen demand (SOD) is compared to an intact core incubation (ICI) SOD method using samples from three lakes. The mass diffusion model coupled with inputs is known as the measure-calculate method (M-C) and is a potential alternative to existing methods for measuring SOD which are more complex, time-consuming, and costly. The M-C method requires inputs for volumetric sediment oxygen uptake (Ṅsed), sediment density and porosity, and water properties. Ṅsed was determined by suspending sediment in oxygen-saturated water with a DO probe and determining the steady …

Electrodeionization Versus Electrodialysis: A Clean-Up Of Produced Water In Hydraulic Fracturing, Brigitte Marie Rodgers

Graduate Theses and Dissertations

Electrodeionization (EDI) is a widely studied process ranging from applications in wastewater clean-up in the food and beverage industry to purifying organic compounds. To date, there are no apparent studies on applying this technology to produced wastewater recovered from hydraulic fracking sites. Water consumption within hydraulic fracturing sites can reach in the upwards of millions of gallons per site, so a need for a water recycling process becomes necessary within areas where water requirements are scarce. Implementation of an EDI module that is capable of handling high salt solutions from produced wastewater in subsequent fracturing practices will decrease overall water …

The Role Of Organic Matter In The Fate And Transport Of Antibiotic Resistance, Metals, And Nutrients In The Karst Of Northwest Arkansas, Victor Lee Roland Ii

Graduate Theses and Dissertations

Organic matter (OM) in the environment acts as a nutrient, but may also act as a transport vector for harmful chemical compounds and bacteria. Acetate is a labile form of OM produced during fermentation in anaerobic lagoons used to store animal fecal-waste from concentrated animal feeding operations (CAFOs). Dry and liquid fertilizers from CAFOs pose a threat to groundwater by introducing excessive amounts of nutrients (e.g. OM, nitrate and ammonia), metals, and antibiotic compounds. In the epikarst of Northern Arkansas in the Buffalo River watershed additional input of labile dissolved organic carbon (DOC) from liquid CAFO waste-fertilizers was hypothesized to …

Field Observations And Computer Modeling Of Tornado-Terrain Interaction And Its Effects On Tornado Damage And Path, Nawfal Shihab Ahmed

Graduate Theses and Dissertations

Tornado forces on structures have been a research focus for the past decades, and some comparisons have been made to distinguish between straight boundary layer (SBL) wind and tornado wind forces on specific structures. However, very little attention has been paid to terrain effects on tornado damage and path. Available damage investigation data for four tornado locations (Joplin-2011, Tuscaloosa-2011, Parish-2011 and Mayflower-2014) is utilized to explore terrain effects on tornado damage and path. Google Earth, site visits and aerial images are employed to study the influence of terrain on an extent of damage and path variation. Additionally, a three dimensional …

Impact Of Extreme Summer Temperatures On Bridge Structures, Ryan Hagedorn

Graduate Theses and Dissertations

Climate change and its effect on weather in the United States is a well-documented phenomenon. In particular, extreme heat waves have become more intense, more frequent, and longer lasting, especially in the southern United States. As with much of America’s transportation infrastructure, prestressed concrete bridge girders experience the effects of these heat waves. Uneven heating of optimized bridge girder sections results in large non-linear temperature gradients. In this study, temperature was monitored in three different AASHTO I-girders to determine the vertical and transverse temperature gradients in a pre-deck placement condition. It was determined that the current design standard, which uses …

An Empirical Water Quality And Best Management Practice Prioritization Model For Select Arkansas Watersheds, James Mccarty

Graduate Theses and Dissertations

The purpose of this study was to prioritize subwatersheds using water quality data and watershed characteristics. Water quality data was provided through studies by the Arkansas Natural Resources Commission, Beaver Water District, Arkansas Water Resources Center, and publicly available USGS gage data. A total of 114 sites across five HUC-8 watersheds were analyzed, including 12 USGS gages. Watershed characteristic data was retrieved from USGS and Arkansas GeoStore geodatabase repositories. A significant linear relationship between baseflow and stormflow nutrient concentrations was established allowing for the use of baseflow concentrations in the prioritization methodology. Pearson correlation, linear regression, classification and regression tree, …

Assessing Trichloromethane Formation And Control In Algal-Stimulated Waters Amended With Nitrogen And Phosphorus, Clinton Mash

Graduate Theses and Dissertations

Nitrogen (N) and phosphorus (P) enrichments can stimulate algal growth in drinking water sources, which can cause increased production of disinfection byproduct (DBP) precursors. However, the effect of systematic N and P enrichments on DBP formation and control has not been adequately studied. In this work, we enriched samples from a drinking water source - sampled on April 5, May 30, and August 19, 2013 - with N and P to stimulate algal growth at N:P ratios covering almost five orders of magnitude (0.2-4,429). To simulate DBP-precursor removal processes at drinking water treatment plants (DWTPs), the samples were treated with …

Assessing The Impact Of Chlorine Residual On Trihalomethane And Haloacetonitrile Formation Under Chlorination And Chloramination Disinfection Regimes, Thien Duc Do

Graduate Theses and Dissertations

A disinfection byproduct (DBP) formation potential (FP) test can be used to indirectly measure the concentration of DBP precursors in natural waters, permitting assessment of various DBP-related treatment processes and control strategies. While these tests require a 7-day chlorine residual (CR) between 3-5 mg L^-1 as Cl², it is not well known if this recommended residual corresponds to the true DBPFP (i.e., the maximum concentrations) for trihalomethanes (THMs) and haloacetonitriles (HANs). In this study, THMs and HANs were quantified as a function of CR under three common disinfection regimes: (1) free chlorine at pH 7.0 (FC7), (2) …

Evaluation Of Broiler Litter Heat Production During Windrowing & Nitrogen Based Gas Emission Mitigation Using Biofilter, Min Lei

Graduate Theses and Dissertations

Ammonia emission from animal feeding operations (AFOs) has negative effects on environment and animals' health. Thus measuring and mitigating ammonia emission from AFOs is important for environmental protection. In chapter I, different ammonia measurements were discussed and a mitigation technology- biofilter was represented.

In-house windrowing of built-up litter has been used by broiler producers to reduce pathogen loads and rejuvenate litter for the next flock. When litter is piled up for an extended period during downtime, heat generated by the litter pile can become a substantial heat source due to the metabolism of microorganisms. In chapter II, heat production rates …

Variability In The Hydraulic Conductivity Of A Test Pad Liner System Using Different Testing Techniques, Matthew Jonathan Nanak

Graduate Theses and Dissertations

Historic methods (the time lag approach, the velocity approach, and the Z-t approach), utilized to reduce two stage borehole test data, were evaluated. Two of the historic methods provided viable results and were used for this research project. Additionally, these two methods are recommended for reducing two stage borehole test data in the future.

Flexible wall permeameter and soil index laboratory testing were conducted on the soil used to construct three environmentally controlled compacted clay liners (test pads) to develop a zone of acceptance (placement window). Using the results from the laboratory testing, two acceptance criterions were evaluated, while one …

A Watershed Scale Evaluation Of Selected Second Generation Biofeedstocks On Water Quality, Gurdeep Singh

Graduate Theses and Dissertations

This study compares a novel simulation approach to the conventional Soil and Water Assessment Tool (SWAT) modeler's approach for targeting biofuel crop production on marginal lands. In conventional SWAT modeling approach, non-spatial definition of hydrological response units (HRUs) results in the simulation of biofuel crops on both marginal and non-marginal land. This study provides an alternative approach in which a marginal-land raster was integrated into the land use and land cover (LULC) raster in such a way that the land uses were divided into marginal and non-marginal components. This modified LULC was used for model setup which resulted in marginal …

Effects Of Testing Time On Anaerobic Toxicity Assessment, Omolola Atinuke Akintomide

Graduate Theses and Dissertations

Anaerobic digestion has been widely used for wastewater treatment for decades. Several Anaerobic Toxicity tests have been developed to screen wastewater for toxicity and assess the treatability of such toxicants. However, past research and reviews on Biochemical Methane Potential (BMP) test and Anaerobic Toxicity Assay (ATA) were considered in this study.

The experimental tests included ammonium-nitrogen and sodium chloride toxicity tests with varied concentration and solid retention time. These tests were designed to demonstrate the impact of ammonia- nitrogen and sodium chloride on the biological degradation process. The anaerobic test set-up includes bench-scale test reactors and respirometers used for measuring …

Magnitude And Frequency Of Floods For Rural, Unregulated Streams Of Tennessee By L-Moments Method, Hongxiang Yan

Graduate Theses and Dissertations

This study presents a regional frequency analysis of Tennessee using the well-known Bulletin-17B method standardly used in the United States and the relatively new and developing L-Moments methods. Flood frequency characteristics were defined for 416 gaging stations located primarily in rural and lightly developed areas of Tennessee. All the gaging stations have 10 or more years of record through 2006. Using the L-Moments method, the generalized extreme value distribution was identified as the most robust distribution for each of four hydrologic areas. Multiple regression equations were also calculated for estimating the flood frequency of ungaged, unregulated, rural streams in each …

The Development Of A High Performance Concrete To Store Thermal Energy For Concentrating Solar Power Plants, Emerson Esmond John

Graduate Theses and Dissertations

In recent years, due to rising energy costs as well as an increased awareness of the environmental effects of greenhouse gas emissions produced through traditional forms of energy production, there is great interest in developing alternative sources of energy. One of the most viable alternative energy sources is solar energy. In particular, concentrating solar power (CSP) technologies have been identified as an option for meeting utility needs in the U.S. Southwest. These systems are required to produce electricity not only during periods of high solar radiation but also during times of reduced radiation due to cloud cover, and even extend …

Synergy Of Alum And Chlorine Dioxide For Curbing Disinfection Byproduct Formation Potential At Central Arkansas Water, Corey W. Granderson

Graduate Theses and Dissertations

Central Arkansas Water (CAW), the water utility for Little Rock, AR, draws their source water from Lake Maumelle and Lake Winona. To curb disinfection byproduct (DBP) formation, CAW has begun retrofitting their two plants to use chlorine dioxide as an alternative primary disinfectant followed by free chlorine secondary disinfection in the distribution system. In this study, fluorescence parallel factor (PARAFAC) analysis was combined with free chlorine simulated distribution system (SDS) tests and DBP formation potential (DBPFP) tests to study the benefit of chlorine dioxide primary disinfection (CDPD) with alum coagulation. Of the DBPs screened, trichloromethane (TCM) was formed in highest …

Mathematical Modeling Of Fluid Spills In Hydraulically Fractured Well Sites, Oluwafemi Michael Taiwo

Graduate Theses and Dissertations

Improved drilling technology and favorable energy prices have contributed to the rapid pace at which the exploitation of unconventional natural gas is taking place across the United States. As a natural gas well is being drilled, reserve pits are constructed to hold the drilling fluids and other materials returned from the drilling process. These reserve pits can fail, and when they do, plant and animal life of the surrounding area may be adversely affected. This project develops a screening tool for a suitable location for a reserve pit. This work will be a critical piece of the Infrastructure Placement Analysis …

Removal Of Disinfection By-Product Precursors Using Magnetic Ion Exchange (Miex(R)): The Effects Of Ph And Source Water Variability, Sarah Cousins

Graduate Theses and Dissertations

Disinfection by-products (DBPs) form as an unintended result of drinking water disinfection, from chemical reactions between disinfectants (e.g., free chlorine) and naturally occurring dissolved organic matter (DOM). At present, 11 DBPs are regulated in treated drinking waters due to potential adverse health effects, including four trihalomethanes (THMs). Despite nearly 40 years of DBP research, compliance with DBP regulations remains a challenge for many drinking water treatment plants (DWTPs), including the four DWTPs located on the Beaver Lake Reservoir in Northwest Arkansas. Due to the high net negative surface charge on DOM, anion exchange is one potentially viable method for removing …

Water Quality Trends For Section 319 Priority Watersheds In Northwest Arkansas, 1997-2010, Bryan William Bailey

Graduate Theses and Dissertations

Northwest Arkansas contains two Section 319 Priority Watersheds that the Arkansas Natural Resources Commission (ANRC) has identified as being impacted by point and nonpoint sources of pollution (i.e., phosphorus, nitrogen, and sediment), and the Arkansas Water Resources Center (AWRC) has monitored the water quality at several sites within these watersheds. Water-quality data has been collected over the last decade within the Illinois River Watershed (HUC #11110103) and the Upper White River Basin (Beaver Reservoir HUC# 11010001), each watershed containing three sampling sites. The Illinois River Watershed sites are located on the Illinois River, Osage Creek, and Ballard Creek, and the …