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Full-Text Articles in Physical Sciences and Mathematics
Synthesis Of Palladium And Palladium-Copper Nanostructures As Electrocatalysts, Haibin Wu
Synthesis Of Palladium And Palladium-Copper Nanostructures As Electrocatalysts, Haibin Wu
Graduate Theses and Dissertations
Pd and its alloys are alternatives of Pt as promising catalysts and electrocatalysts for many reactions. Size controlled synthesis of nanoparticles remains a major research subject, since smaller size particles show better catalytic performance. In this work, we developed a modified chemical wet method to prepare Pd and Pd-Cu nanostructures with uniform small size. Different sizes and shapes of Pd nanostructures were successfully synthesized by using the two reducing agents (i.e., L-ascorbyl-6-palmitate or phenylphosphinic acid). The reducing agents play a role to control the final morphologies and sizes of particles. The use of L-ascorbyl-6-palmitate favors to form irregular branch shapes …
Static And Dynamical Properties Of Ferroelectrics And Related Material In Bulk And Nanostructure Forms, Zhigang Gui
Static And Dynamical Properties Of Ferroelectrics And Related Material In Bulk And Nanostructure Forms, Zhigang Gui
Graduate Theses and Dissertations
Ferroelectrics (FE) and multiferroics (MFE) have attracted a lot of attentions due to their rich and novel properties. Studies towards FE and MFE are of both fundamental and technological importance. We use a first-principles-based effective Hamiltonian method, conventional ab-initio packages and linear-scale three-dimension fragment method to investigate several important issues about FE and MFE. Tuning the properties of FE and MFE films are essential for miniaturized device applications, which can be realized through epitaxial strain and growth direction. In this dissertation, we use the effective Hamiltonian method to study (i) BaTiO 3 films grown along the (110) pseudocubic direction on …