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Physical Sciences and Mathematics Commons

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University of Arkansas, Fayetteville

2015

Journal of the Arkansas Academy of Science

Articles 1 - 6 of 6

Full-Text Articles in Physical Sciences and Mathematics

Wave Profile For Anti-Force Waves With Maximum Possible Currents, M. Hemmati, R. Horn, W. P. Childs, A. K. Meredith Jan 2015

Wave Profile For Anti-Force Waves With Maximum Possible Currents, M. Hemmati, R. Horn, W. P. Childs, A. K. Meredith

Journal of the Arkansas Academy of Science

In the theoretical investigation of the electrical breakdown of a gas, we apply a one-dimensional, steady state, constant velocity, three component fluid model and consider the electrons to be the main element in propagation of the wave. The electron gas temperature, and therefore the electron gas partial pressure, is considered to be large enough to provide the driving force. The wave is considered to have a shock front, followed by a thin dynamical transition region. Our set of electron fluid-dynamical equations consists of the equations of conservation of mass, momentum, and energy, plus the Poisson's equation. The set of equations …


Natural Nutrient Sources In The Cache River Watershed, Arkansas, M. K. Kilmer, N. Poe, S. Chappell, J. L. Bouldin Jan 2015

Natural Nutrient Sources In The Cache River Watershed, Arkansas, M. K. Kilmer, N. Poe, S. Chappell, J. L. Bouldin

Journal of the Arkansas Academy of Science

The growth of the hypoxic ‘dead zone’ in the Gulf of Mexico in recent years has placed increased focus on potential sources of nutrient pollution, with most of the focus being placed on watersheds where practices, including fertilizer application and land alterations combine to increase non-point source runoff. In this study, nutrient concentrations in surface waters of altered and unaltered areas of the Cache River Watershed, Arkansas, were compared to determine if agricultural land usage was responsible for the majority of nutrient inputs. Results suggest that for dissolved nitrites and orthophosphates, agricultural (altered) sites contribute significantly more than relatively unaltered …


Development Of Heterogeneous Photosensitized Transition Metal Oxide Water-Splitting Catalysts On Silica Support, M. P. Gajewski, H. J. Crane, M. W. Nelson Jan 2015

Development Of Heterogeneous Photosensitized Transition Metal Oxide Water-Splitting Catalysts On Silica Support, M. P. Gajewski, H. J. Crane, M. W. Nelson

Journal of the Arkansas Academy of Science

The research presented in this manuscript describes the development of photosensitized inexpensive catalysts based on readily available materials. The investigation covers synthesis and characterization of photosensitizers based on porphyrins, mechanical and thermal coating of solid support with semiconducting transition metal oxides, photosensitization of the semiconducting layer, and characterization of the photoelectrochemical properties displayed by the new materials. The process of water oxidation is of primary interest here, with little emphasis put on reduction of protons to gaseous hydrogen. Photoelectrochemically produced protons serve as a probe of effectiveness of the catalysts. Several systems are described, and two catalysts are identified as …


Bond Length - Bond Valence Relationships For Carbon - Carbon And Carbon - Oxygen Bonds, C. Harris, F. D. Hardcastle Jan 2015

Bond Length - Bond Valence Relationships For Carbon - Carbon And Carbon - Oxygen Bonds, C. Harris, F. D. Hardcastle

Journal of the Arkansas Academy of Science

In the present study, relationships are developed for determining bond orders (also referred to as bond valences or bond numbers) from published bond lengths for carbon-carbon (C-C) and carbon-oxygen (C-O) bonds. The relationships are based on Pauling’s empirical formula s = exp((Ro-R)/b)), where s is the bond order, R is the corresponding bond length, Ro is the unit valence bond length, and b is a fitting parameter. We use a recently derived relationship for the b parameter in terms of the bonding atoms’ published atomic orbital exponents. The resulting equations were checked against published x-ray diffraction (XRD) data for 176 …


Low-Level Mercury Causes Inappropriate Activation In T And B Lymphocytes In The Absence Of Antigen Stimulation, K. L. Weigand, J. L. Reno, B. M. Rowley Jan 2015

Low-Level Mercury Causes Inappropriate Activation In T And B Lymphocytes In The Absence Of Antigen Stimulation, K. L. Weigand, J. L. Reno, B. M. Rowley

Journal of the Arkansas Academy of Science

The immune system primarily utilizes two cell types for adaptive immunity: T lymphocytes and B lymphocytes. T lymphocytes are activated when antigen presenting cells (APCs) present antigen to membrane-bound T cell receptors. B lymphocytes are activated when an antigen binds to receptors embedded in the plasma membrane. In both T and B cells this antigen binding crosslinks the receptor complexes and initiates the signal transduction cascade. These cascades frequently consist of a series of intracellular molecules becoming phosphorylated in a step-wise fashion. Once activated, these cells differentiate into effector cells that clear out the stimulating antigen. Mercury, which is a …


Aquatic Effects Of A Localized Oil Spill On Lake Conway, Ar And Its Tributaries, M. E. Kennon, J. L. Bouldin Jan 2015

Aquatic Effects Of A Localized Oil Spill On Lake Conway, Ar And Its Tributaries, M. E. Kennon, J. L. Bouldin

Journal of the Arkansas Academy of Science

Oil spills, no matter where they occur, elicit environmental concern and avoiding these disasters should be a priority. Old pipelines that are not regularly maintained and carry large amounts of crude oil long distances are of particular concern. One such pipeline is the 65 year-old Pegasus pipeline owned by ExxonMobil. On March 29, 2013, 795,000 L of Wabasca Heavy Canadian crude oil spilled into a neighborhood of Mayflower, Arkansas, when the Pegasus pipeline ruptured. This spill led to the evacuation of many homes in the surrounding neighborhood. Drainage ditches in the affected neighborhood drained oil into a nearby cove of …