Physical Sciences and Mathematics Commons^™

Modified Polysulfone Nanofiltration Membrane Synthesis For Hydraulic Fracturing Water Recycle, Blake Alexander Johnson

Graduate Theses and Dissertations

The use of hydraulic fracturing has resulted in significant increases in the yield of oil and natural gas, as water pumped into wells at high pressure cracks the formations and releases the hydrocarbons that are locked in the rocks. This process has created large volumes of brackish water that is very difficult to process and is often disposed of into injection wells. Suspended solids and some dissolved solids are more readily removed, but the multivalent ions found in certain salts can precipitate in a well and complicate the reuse of flowback in future hydraulic fracturing operations.

Nanofiltration, a membrane separation …

Hydrology-Biology Response Relationships In The Ozark Highlands, Dustin Thomas Lynch

Graduate Theses and Dissertations

I examined flow-ecology relationships among stream communities in the Ozark Highlands, USA. I sampled fish, crayfish, and benthic macroinvertebrates during two consecutive summers, including a drought year (2012) and a flood year (2013). Biological response variables related to community structure were assessed via two different statistical methods: an Information Theoretic approach relating response variables to a priori selected predictor variables incorporating hydrology, habitat, geomorphology, and water quality, and canonical ordination using forward selection to relate these same response variables to a large assortment of hydrologic metrics. In addition to assessing metrics related to predicted natural flow, flow alteration at gaged …

Metal Mobilization In Groundwater, Bauxite, Ar, Steven Alexander Hamlin

Graduate Theses and Dissertations

The Wilcox Aquifer of Bauxite, AR contains bauxite ore deposits that may contribute heavy metals to groundwater. Twenty-four wells were sampled for aluminum, iron, manganese, zinc, lead, barium, nitrate, sulfate, sodium, alkalinity, calcium, magnesium, chloride, pH, total organic carbon, and total dissolved solids. A Wilcoxon Rank-Sum compared the similarity of the three geographic areas covered in the study. All parameters for wells in Bauxite and Sardis failed to reject the null hypothesis, signifying that wells all occupy the Saline Formation. 2/3rds of the parameters from BFI261 and the Bauxite region did not agree, suggesting the two areas do not occupy …

Effects Of Landscape Disturbances On Autotrophic Processes Within Arkansas Ozark Streams, Bradley J. Austin

Graduate Theses and Dissertations

Land-use change is one of the most widespread human impacts and can influence abiotic and biotic processes within surrounding streams. For example, streams in agricultural and urban watersheds receive greater light and nutrient inputs that can promote increased algal growth and primary production. Natural gas (NG) infrastructure development, a recent land use change in many regions, may also stimulate forested stream primary production, by reducing forest cover and increasing sediments and nutrient transport. I sampled streams across a NG activity gradient for algal biomass and gross primary production (GPP) to assess potential effects of this emerging land-use type. Algal biomass …

Stable Isotopes As A Tool To Characterize Carbon Cycling And Develop Hydrologic Budgets In Mantled Karst Settings, Katherine Knierim

Graduate Theses and Dissertations

Isotopes of water (δ2H/δ18O), carbon dioxide (δ13C-CO2), and dissolved inorganic carbon (δ13C-DIC) were used to explore water quality, trace carbon cycling, and quantify recharge sources through mantled karst and into Blowing Spring Cave (BSC). Of the possible sources of contamination in the BSC recharge area, septic-tank effluent was hypothesized to degrade water quality at the spring outlet of BSC because of the dominance of septic tanks for waste treatment, unsuitable topography and soil for septic-tank absorption fields, increased nitrate and chloride concentrations concomitant with increased urbanization, and increased Escherichia coli with discharge. Carbon cycling between the soil and BSC was …

Controls On Dissolution Rate Variation At A Pair Of Underflow-Overflow Springs At The Savoy Experimental Watershed, Kiefer Allen Vaughn

Graduate Theses and Dissertations

Physical dissolution experiments and numerical modeling have been used in the past to study limestone dissolution rates. Numerical models have typically used constant dissolution rates, whereas rates in nature vary in time. Limestone tablets allow natural estimation of rates over month time scales, but these rates cannot necessarily be extrapolated to geologic timescales and also do not aid our understanding of short term variability. This study characterizes natural variability in these rates and examines potential causes of that variability from first principles. This may enable more accurate projections of dissolution rates within models. This study combines measurement of physical and …

Subsurface Fluid Flow Through The Mississippian Section Of North-Central Oklahoma, Carolyn Brown

Graduate Theses and Dissertations

This study consisted of using drill stem tests, seismic amplitude data, and well logs to create the parameters needed to construct a groundwater flow model for a portion of Osage County. At the start, a potentiometric map of Osage County, Oklahoma was generated to use as a basis for the initial hydraulic heads and the constant heads in the model. Next, three seismic amplitude images were produced in a seismic interpretation program, OpenDtect, to base the hydraulic conductivity values on. In addition, utilizing Gamma Ray on 12 separate wells east-west across the county, a structural cross-section was created within Petra. …

Habitat Assessment And Ecological Restoration Design For An Unnamed Tributary Of Stone Dam Creek, Conway, Arkansas, Paige E. Boyle, Mary C. Savin, James A. Mccarty, Marty D. Matlock

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

Urbanization can lead to increased sedimentation, erosion, pollution, and runoff into streams. The United States Environmental Protection Agency’s (USEPA) Rapid Bioassessment Protocols (RBPs) are sets of guidelines that can be used to assess a habitat’s sedimentology, hydrology, vegetation, and geomorphology to determine impairment. An unnamed tributary of Stone Dam Creek on the University of Central Arkansas (UCA) campus in Conway, Arkansas runs partially underground and through the urbanized UCA campus watershed. The stream was assessed using the USEPA’s RBPs to determine impairment of the stream, and received a RBP score of 71.2 out of 200 compared to 153.5 in a …