Physical Sciences and Mathematics Commons^™

Procedural Content Generation: Using A.I. To Generate Playable Content, Osler Kendall Moore Jr.

Honors Theses

This thesis is about using Artificial Intelligence in regards to Procedural Content Generation to help try and avoid a deadlock scenario in a hypothetical dungeon exploring game. The deadlock scenario is essentially having a key being placed in a room that’s inaccessible to the player. An example of such a scenario would be if the key to room A being in Room B, the key to room B was in room A, and the player was in room C. The program generates the dungeon world with a random number of rooms inside it, each room also having a random number …

Biomimetic Adhesive Thiol-Ene Films For Improved Adhesion, Laken L. Kendrick

Honors Theses

Current dental restoration materials fall short in adhesion and often pull away from the surface of the tooth upon curing. This project seeks to design polymers that can adhere to wet, heterogeneous surfaces as potential materials for dental restoration applications. The goal of this project is to mimic the structure and adhesive properties of natural adhesives containing 3,4-dihydroxyphenyl-L-alanine (DOPA). We will synthesize mono- and di-functional DOPA derivatives with catechol functionality and investigate their adhesion compared to their non-catechol-containing alternative through incorporation into a model thiol-ene photopolymerization. Functional group conversion, real time kinetics, and adhesion data will be used to analyze …

2-Domination And Annihilation Numbers, Sean C. Patterson

Honors Theses

Using information provided by Ryan Pepper and Ermelinda DeLaVina in their paper On the 2-Domination number and Annihilation Number, I developed a new bound on the 2- domination number of trees. An original bound, γ₂(G) ≤ (n+n₁)/ 2 , had been shown by many other authors. Our goal was to generate a tighter bound in some cases and work towards generating a more general bound on the 2-domination number for all graphs. Throughout the span of this project I generated and proved the bound γ₂(T ) ≤ …

Relativistic And Non-Relativistic Proton-Nucleus Scattering, Kinsey Ann Elisabeth Zarske-Williamson

Honors Theses

Calculations for proton-nucleus scattering often rely on transition amplitudes. We implement new transition amplitudes [7] with the relativistic equations. We can find the matrix elements of the operators between the usual Dirac spinor basis or the helicity spinor basis. The operators can also be written as a linear combination of non-relativistic spin operators. To transform from one basis to another, we need to find a transformation matrix. We must establish what one of the factors that appears in the transformed expression means in order to correctly complete our transformation matrix. Once this is resolved, our transformation matrix will be complete.

Analysis Of The Mechanical Properties Of Dgebf/4,4’-Dds Thermoset Systems As A Function Of Cure Rate, Chase B. Thompson

Honors Theses

The relationship between macroscopic mechanical and thermal properties and ramp rate during cure of epoxy-amine systems consisting of the epoxide resin digylcidyl ether of bisphenol F (DGEBF, provided Hexion specialty chemicals) and 4,4-diaminodiphenyl sulfone (4,4-DDS, provided by Atul Sulpho) were probed using Dynamic Mechanical Analysis (DMA), Positron Annihilation Lifetime Spectroscopy (PALS), and compression testing. These systems were cured in a programmable oven; the samples were heated from 35°C to 180°C at ramp rates of 0.5, 1.0, 1.5, 2.0, 2.5, 5.0, 10, and 15°C/min. Even as the ramp rates during the cure of these materials was changed, there was very little …

Modeling The Diffusion Of Heat Energy Within Composites Of Homogeneous Materials Using The Uncertainty Principle, Elyse M. Garon

Honors Theses

The purpose of this project is to model the diffusion of heat energy in one space dimension, such as within a rod, in the case where the heat flow is through a medium consisting of two or more homogeneous materials. The challenge of creating such a mathematical model is that the diffusivity will be represented using a piecewise constant function, because the diffusivity changes based on the material. The resulting model cannot be solved using analytical methods, and is impractical to solve using existing numerical methods, thus necessitating a novel approach.

The approach presented in this thesis is to represent …

The Effects Of Recreational Rock Climbing On Vascular And Nonvascular Plant Communities In Southeastern Tennessee, Caitlin A. Ruby

Honors Theses

Popularity for non-consumptive outdoor recreations has rapidly increased over the past decades. With many national and state park regulations failing to regulate rock climbing, scholars are concerned for the amount of ecological disturbance that may occur if left unmonitored. Visual assessments to disturbance disparities between remote climbing locales and contradictory scientific literature confirmed the need for further research on the effects of rock climbing on cliff ecology. Two climbing centers were focused in Southeastern Tennessee: Foster Falls in Sequatchie County and Leda in Hamilton County. Convenience sampling was used to collect 24 transects from intermediately graded routes and 24 transects …

Polymerization Of Blocked Isocyanate Functional Polymer Surfaces And Post-Polymerization Modification By Thiol-Isocyanate Reactions, Chase A. Tretbar

Honors Theses

Direct polymerization of isocyanate-functional monomers has been achieved with controlled radical polymerizations (CRP) for precisely engineered modification platforms with highly reactive side chains. However, despite the success of these strategies, the inherent reactivity of isocyanates still leads to adverse side reactions, such as hydrolysis, that are difficult to suppress. Phenol, lactam, and oxime-based blocking agents have been used to limit the reactivity of isocyanates in applications such as multicomponent urethane coating systems. The reactivity of these blocked isocyanates can be restored by thermal deprotection of the blocking agent to achieve the desired reactions. In this work, we use blocked isocyanate-functional …