Physical Sciences and Mathematics Commons^™

Investigation Of Cryptotephra In Polar Ice Cores, Meredith Helmick

Electronic Theses and Dissertations

Volcanic ash (tephra) present within polar ice cores greatly supplements our understanding of past volcanism and its impacts on society and the state of the climate system. This thesis investigates the utility and limitations of ice core tephrochronology in answering questions related to volcanic source identification of ice core glaciochemical signals, tephrostratigraphy of an Antarctic ice core, and the timing of major and climate forcing eruptions. This thesis explores the efficacy of SEM-EDS measurements on ultra-fine (µm) volcanic particles for the purpose of geochemically characterizing a non-visible ice-embedded tephra and the subsequent identification of the volcanic source. In combination with …

Gold (I) Tetrathiomolybdate Clusters: Synthesis, Characterization, Computational Studies, And Reactivity With Thiophenol And Selenophenol, Dhirgam Humaidy

Electronic Theses and Dissertations

This thesis describes the synthesis and reactivity of heterometallic complexes containing medicinally active Au(I) and tetrathiomolybdate, [MoS₄]^2-. The research is motivated by the idea of multifunctional drugs, which are designed to treat diseases through two or more mechanisms of action. Five clusters of the general form, [MoS₄(AuL)₂] were prepared: C-1 (L=IPr), C-2 (L=IBzMe), C-3 (L=IMes), C-4 (L=PPh₃), and C-5 (L=PEt₃). The clusters with NHC ligands, C-1, C-2, and C-3 were prepared for the first time and thoroughly characterized by ¹H NMR,¹³C{¹H} …

Barriers To And Opportunities For Adoption In Maine’S Aquaculture Industry, Caitlin Cleaver

Electronic Theses and Dissertations

Aquaculture, or the farming of marine species, can diversify coastal economies, but development of this industry is hindered by negative perceptions or regulatory constraints. Commercial fishers are logical adopters of aquaculture, but can also mount opposition to its growth. This dissertation utilized innovation theory to understand fishers’ perceptions of and willingness to adopt aquaculture and drivers of and barriers to scallop aquaculture development in Maine (USA). Through a mail survey, lobster fishers’ perceptions of Maine’s aquaculture industry and their willingness to adopt aquaculture were assessed (Chapter 2). Individuals who were more satisfied with government management of aquaculture held more positive …

Regional Scale Generalizations Of Firn Thickness And Snow Accumulation In Southeast Alaska: An Applied Deep Learning Framework, Jonathan Maurer

Electronic Theses and Dissertations

High elevation mountain glaciers are referred to as the “water towers of the world” due to their ability to store water internally and release it later through melt and runoff. Much of the work to understand these complex environments has focused on cold based polar glaciers in high latitude regions, neglecting temperate glaciers and associated snowpack which are more responsive than polar systems to minor climatic changes. Advancements in the availability of open source data, deep learning theory, and computational efficiency has opened up new methods of “data hungry” modeling that may be well suited to the type of complex …

Holocene And Last Glacial Period Atmospheric Dynamics And Biogeochemistry Based On South Pole Ice Core Microparticle And Trace Element Records, Aaron Chesler

Electronic Theses and Dissertations

I develop and interpret a record of dust deposition from the South Pole ice core (SPC14) to identify changes in atmospheric variability. The SPC14 core was drilled during 2014 – 2016 and provides a high accumulation (~7 cm w.e.q. per year) record in central Antarctica that reaches a depth of 1751 m (~54 ka). My analysis combines microparticle (dust) concentration, size, and shape metrics using continuous and discrete methodologies and high- and low-resolution multifractional Fe analyses that span the past 54 ka.

Results from my dust shape analysis suggest the common assumption of spherical dust particle shape in incorrect and …

Anthropogenic Effects On Tidal Distortion In A Tidal River, Matthew D. Fischer

Electronic Theses and Dissertations

Tidal rivers are landward portions of estuarine systems constituting the union between coastal, tidally controlled settings and rivers, where fluvial processes dominate. In these reaches, river discharge (mean flow) and tides are the two most important mechanisms in controlling geophysical flows. The processes governing water levels and current amplitudes in tidal rivers are highly nonlinear and modulated by external forcings- thus requiring sophisticated techniques for accurate prediction and forecasting. Physical oceanographers and estuarine physicists tend to limit their study area to the maximum extent of the horizontal tide (salinity intrusion), not the most landward point influenced by tidal water levels. …

Plasma-Assisted Growth And Characterization Of Piezoelectric Aln And Sc(X)Al(1-X)N Films For Microwave Acoustic Sensor Applications, Morton Greenslit

Electronic Theses and Dissertations

The use of surface acoustic wave (SAW) sensors in high temperature harsh environments such as those found in power plants, industrial manufacturing, or aerospace applications allows for monitoring of internal conditions at locations where traditional sensors do not operate or are unreliable. Surface acoustic wave resonator (SAWR) sensors are based on piezoelectric materials and feature a small passive low-profile self-powered design that can operate and wirelessly transmit data to monitor parameters such as temperature, pressure, or strain. SAWR sensors typically consist of a series of metal electrodes fabricated onto a bulk crystal piezoelectric such as langasite (La3Ga5SiO14). However, there are …

First-Row Transition Element Distribution Across The Blueschist-Eclogite Transition: A Case Study From New Caledonia, Natalie M. Harmon

Electronic Theses and Dissertations

The first-row transition elements (FRTE), namely Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn, are potential redox tracers in the solid Earth due to their general compatibility during crustal processes, and the redox-sensitive nature of certain elements. Despite widespread interest in the FRTEs, their distribution and behavior in subduction zones, particularly across the blueschist-eclogite transition, are still poorly constrained. New Caledonia preserves a prograde subduction zone with largely coherent continuous progression in metamorphic grade. Although the metamorphic sequence has been disrupted to some extent, this is the closest natural example of blueschist and eclogite that was sourced …

Understanding The Impacts Of Anthropogenic Effects An Habitat Variability Interactions On Maine's Rocky Intertidal Ecosystem, Laura Braun

Electronic Theses and Dissertations

The rocky intertidal ecosystem is an important ecological and cultural aspect of the picturesque Maine coast, playing a vital role in not only Maine’s coastal ecosystem, but also to Maine’s economy. It’s distinct community structure along the sharp elevational gradient and the presence of daily stressors (wave action, heat, and desiccation), make the rocky intertidal ecosystem an important model ecosystem to monitor for effects from anthropogenic impacts. In this thesis, I describe attempts to monitor and understand the impacts of two of these anthropogenic impacts on this system: climate change and industrial harvesting of Ascophyllum nodosum along Maine’s coast. For …

Carbon Dioxide Emissions From Deadwood In Forests Of The Northeastern United States, Zoe Read

Electronic Theses and Dissertations

As the climate changes, understanding the sources and sinks of greenhouse gases such as carbon dioxide (CO₂) is increasingly important. However, several components of the carbon cycle within forests remain poorly understood. For example, knowledge gaps exist in our understanding of CO₂ emissions from coarse woody material (CWM; logs and stumps), including how emissions change over time, how they are influenced by environmental variables, and how they compare to soil and ecosystem-level CO₂ emissions.

To fill these knowledge gaps, we examined CO₂ emissions from CWM at three sites. We sampled 18 red spruce (Picea …

Weak Gravitational Lensing Analysis In Two Superclusters Of Galaxies, Sarah B. Rice

Electronic Theses and Dissertations

Observations of the Universe on very large scales have shown it to be filled with galaxy clusters and superclusters connected by walls and filaments of galaxies, with vast areas mostly devoid of luminous matter separating them. It is widely accepted that the amount of luminous matter does not provide the mass needed to hold galaxies and galaxy clusters together, and the nature of the missing "dark matter" is one of the most prominent astrophysical mysteries today. Since dark matter interacts with luminous matter gravitationally, it stands to reason that dark matter might organize itself in a similar manner to luminous …

Performance Enhancement Of Hyperspectral Semantic Segmentation Leveraging Ensemble Networks, Nicholas Soucy

Electronic Theses and Dissertations

Hyperspectral image (HSI) semantic segmentation is a growing field within computer vision, machine learning, and forestry. Due to the separate nature of these communities, research applying deep learning techniques to ground-type semantic segmentation needs improvement, along with working to bring the research and expectations of these three communities together. Semantic segmentation consists of classifying individual pixels within the image based on the features present. Many issues need to be resolved in HSI semantic segmentation including data preprocessing, feature reduction, semantic segmentation techniques, and adversarial training. In this thesis, we tackle these challenges by employing ensemble methods for HSI semantic segmentation. …

S7e8: What Is The Legacy And Future Of The Climate Change Institute?, Ron Lisnet, Paul A. Mayewski, Daniel Sandweiss, Cynthia Isenhour

The Maine Question

The nation’s first multi- and inter-disciplinary research institute to study Earth’s recent and long-term climate variability was founded in 1972 at the University of Maine. That institute, now known as the Climate Change Institute, is celebrating its 50th anniversary this year, a milestone that honors the many groundbreaking discoveries its scientists have made in the field of climate science.

CCI have scientists first mapped the difference between climate during the Ice Age and today in the 1970s; discovered the importance of marine-based ice sheets in the 1980s; connected acid rain to human causes in the mid-1980s; uncovered the concept of …

Arcmap Basics: Wpes, How Do I...? Quick Guide, Bea E. Van Dam

Non-Thesis Student Work

This document is a quick guide to performing common geospatial tasks in ArcMap 10.x (ArcGIS Desktop) for new users. Covered are basic navigation of the ArcMap window; importing, opening, querying, editing, and exporting data; and map preparation. In many cases, there are multiple ways to accomplish different tasks; presented here are the methods the author finds easiest or most straightforward. Mouse click sequences and menu/tool layout may differ if using previous versions of ArcMap.

S7e4: How Can We Eliminate Pfas?, Ron Lisnet, Onur Apul

The Maine Question

In recent years, communities across Maine and the U.S. have discovered the presence of toxic chemicals called per- and polyfluoroalkyl substances, or PFAS, in their land and water. Also known as forever chemicals because they are difficult to destroy, PFAS have been incorporated in various products, including food containers, clothing, rugs, teflon pans, fabrics and dental floss, for decades. Emerging research, however, has linked PFAS to several health issues, including weakened immune systems, increased risk of obesity and multiple cancers, developmental problems in children and harm to negative effects on reproduction.

Onur Apul, assistant professor of environmental engineering at the …

3d Computer Modeling Offers New Insights Into Diatom Ecology, Joseph Mohan

Electronic Theses and Dissertations

Algae supply over half of the Earth’s global primary production and form the base of almost all aquatic food networks. Thus, changes in algal productivity or composition will induce profound shifts in many ecosystems. This research is guided by two questions. Herein I ask if 3D models of algae can be created accurately enough to use for research applications? If they can be accurately created, then how can these models be used to advance our understanding of functional trait evolution and paleoecology? Herein, I develop 3D computer models for estimating the volume of individual algae and their parts. I also …

Using Soil Testing Data To Examine Organic Carbon Changes During The Past 27 Years In Maine Agricultural Soils, Andrew Chase

Electronic Theses and Dissertations

Agricultural soils may act as a source or a sink for carbon (C) in the global C cycle. With rising atmospheric CO2 levels, C sequestration in soils may play an important role in climate change mitigation. Soil organic carbon (SOC) also contributes to key aspects of soil health and fertility, such as aggregation, water-holding capacity, microbial biomass, and nutrient mineralization. Although SOC may be calculated from estimates of soil organic matter (SOM) obtained by loss-on-ignition (LOI), factors such as sample clay concentration and combustion temperature introduce error into estimates of SOM. We explored the potential for an extensive collection of …

Simulations Of Coastal Currents, Transport And Population Connectivity Of Blue Mussel (Mytilus Edulis) In The Gulf Of Maine, Denghui Li

Electronic Theses and Dissertations

Sections of the coastal Gulf of Maine (GoME) differ in circulation, temperature, salinity, and primary production. These regional differences as well as their temporal changes, together with biological factors, such as the vertical migration, pelagic larval duration, etc., determine marine larval transports, and further affect the population connectivity, and community assembly in the intertidal GoME. To investigate the variations of coastal currents in the GoME, we built a high-resolution circulation model covering the shelf seas from Long Island Sound to the Gulf of St. Lawrence, This model was quantitatively validated with observed sea surface height (SSH), time series of temperature, …

Stereoselective Synthesis Of Pseudosaccharide Derivative And Bisphosphoramidate Core Of Em2487, Saad Z. Mohammed Ali

Electronic Theses and Dissertations

HIV is among the leading causes of death worldwide resulting in over 1 million deaths annually according to the World Health Organization. Despite advances in the treatment of HIV, eradicating this pathogen remains a top priority in the medical and scientific communities. EM2487 is a natural product produced by Streptomyces sp. Mer-2487 that possesses promising activity against HIV. Specifically, EM2487 is a potent and selective inhibitor of HIV replication in both acutely and chronically infected cells. The observed HIV activity is hypothesized to be the result of targeting the Tat-TAR (trans-activation response) element which activates RNA polymerase II at the …

Archaeological Bivalves As El Niño-Southern Oscillation (Enso) Proxies, Frankie St. Amand

Electronic Theses and Dissertations

El Niño-Southern Oscillation (ENSO) is a climate phenomenon with periodic events that impact humans in the study area along the North Coast of Peru. In this region, Eastern Pacific and Coastal El Niño events are associated with anomalously high sea surface temperature (SST), reduced upwelling, and heavy precipitation (Grados et al., 2018; Sandweiss et al., 2020). Major changes in ENSO occurred during the Mid- to Late-Holocene, ca. 5.8 and 2.9 ka, resulting in rapid increases in event frequency to modern conditions. To better identify human adaption to changing climate during the Holocene, we must improve our understanding of ENSO. Though …

Microstructural Analysis For Dynamic Pulverization And Asymmetric Damage At The Base Of Seismogenic Strike-Slip Faults, Bo Ra Song

Electronic Theses and Dissertations

Although the mechanics of continental, seismogenic strike-slip faults have been primarily studied around active faults near Earth’s surface, large earthquakes on these faults commonly extend to depths between 10 and 20 km. At the base of seismogenic strike-slip faults, interaction and feedback between coseismic brittle fracturing and post- and interseismic viscous flow affect transient and long-term changes in stress cycling, fluid and heat transport, fault strength, and associated strain localization and deformation mechanisms. A primary goal of my dissertation is to explore the deeper structures of damage zones near the base of the seismogenic zone and to better understand the …

Quantifying Spatial Heterogeneity Of Wild Blueberries And Crop Water Stress Monitoring Using Remote Sensing Technologies, Kallol Barai

Electronic Theses and Dissertations

The wild blueberry is one of the major crops of Maine, with significant economic value and potential health benefits. Due to global climate change, drought impacts have been increasing significantly in recent years in the northeast region of the USA, causing significant economic losses in the agricultural sectors. It has been predicted to increase further in the future. Changing patterns of the elevated atmospheric temperatures, increased rainfall variabilities, and more frequent drought events have made the wild blueberry industry of Maine vulnerable, suggesting the adoption of novel approaches to mitigate the negative impacts of global climate changes. Also, wild blueberry …

Social Capital, Indigenous Storytelling, And Fish Diversity: Learning Together Through Community-University Partnerships In Downeast Maine, Michelle De Leon

Electronic Theses and Dissertations

Not only can community-university partnerships be vehicles for mobilizing community resources and affecting change, they also have high potential to produce useful, nuanced research and enable renewed visions of trust. I explore partnerships rooted in trust in the context of a community-university partnership between the Passamaquoddy Tribe at Sipayik and the University of Maine and its work through the Passamaquoddy-led StoryMaps Team. To accomplish this, I take a transdisciplinary approach to incorporate diverse perspectives on understanding critical and ethical approaches to engagement with Indigenous communities. The central focus among all three chapters is the need for Indigenous communities and institutions …

Remotely Sensed Assessment Of The Preferred Habitat Of Alexandrium Catenella In The Gulf Of Maine And The Bay Of Fundy, Andre F. Bucci

Electronic Theses and Dissertations

Harmful Algal Blooms (HABs) of the toxic dinoflagellate Alexandrium catenella are an annually recurring problem in the Gulf of Maine (GoM), resulting in risks to human health and substantial economic losses due to shellfish harvesting closures. The monitoring approaches in the region are restricted to real-time identification of the HABs events, when they are clearly underway and already causing deleterious effects to the environment. To fully function as an early warning system rather than an immediate response, monitoring strategies need to be focused on environmental conditions preceding A. catenella HABs. However, the current understanding of the preferred habitat for A. …

Intersections Of Environmentalism, Chemistry, And Racism: An Experimental Study Of Halobenzene Hydrogenolysis And Critical Communication Studies Of Equitable Learning Practices Rooted In Black Feminism, Lauren O. Babb

Electronic Theses and Dissertations

Increasing concentrations of fluorinated aromatic compounds in surface water, groundwater, and soil pose threats to the environment. Fundamental studies that elucidate mechanisms of dehalogenation for C-X compounds (where X represents a halide) are required to develop effective remediation strategies. For halogenated benzenes, previously published research has suggested that the strength of the C-X bond is not rate-determining in the overall rate of dehalogenation. Instead, the rate-determining step has been hypothesized to be adsorption of the C-X compound onto the surface of a catalyst. Building on this hypothesis, in this work, we examine the reaction kinetics of fluorobenzene conversion to benzene, …

Glaciochemical Investigations In Three Southern Hemisphere Mountain Sites, Mariusz Potocki

Electronic Theses and Dissertations

The research presented in this dissertation focuses on glaciochemical records of trace elements, major ions, and stable water isotopes from three mountain regions: the Antarctic Peninsula, the Central Chilean Andes, and South Georgia Island.

The first section reports a significant increase in U concentration over 27 years on Detroit Plateau, Antarctic Peninsula. U concentrations in the ice core increase by as much as 102 between the 1980s and 2000s, accompanied by increased variability in recent years. The U concentration increase coincides with expanded open pit mining in the Southern Hemisphere, most notably Australia. Since other land-source dust elements do not …

The Effects Of Rising Ambient Temperatures On Thermoregulation And Range Shifts Of Northern Flying Squirrels, Elise K. Gudde

Electronic Theses and Dissertations

Climate change may potentially alter a species’ range distribution and thus the relationship between environmental temperatures and animal performance as a response to climate warming has become an important area of research. Two species of flying squirrel in North America, the southern flying squirrel (Glaucomys volans) and the northern flying squirrel (Glaucomys sabrinus) have undergone northward range shifts, with climate warming being the suspected driver. Because they are nocturnal and tree nesting, flying squirrels may be particularly susceptible to warmer temperatures, as they will experience the highest daily ambient temperatures during their resting phase. I used G. sabrinus as a …

Synthesis And Evaluation Of Water-Dispersed Aryl-Gold Nanoparticles And Applications In Catalysis, Ahmad Al Ahmad

Electronic Theses and Dissertations

Gold nanoparticles have been used in environmental remediation as catalysts through biological and chemical redox reactions of many types of industrial waste including nitroarenes, organic dyes, carbon monoxide, and others. These reactions occur in harsh environmental conditions (e.g. changing temperature, presence of salts, extreme pH solutions) which require robust nanoparticles that can keep their activity and resist aggregation. This thesis describes the synthesis, characterization, and investigation of the catalytic activity of gold-aryl nanoparticles. Gold–aryl nanoparticles (AuNPs-COOH) fabricated using a mild reduction process of a molecular aryldiazonium gold(III) salt [HOOC-4-C6H4N≡N]AuCl4 showed high stability in the presence of high ionic strength salt, …

Measurement Of Airborne Radionuclides And Their Relation To Weather Patterns At Orono, Me, James W. Deaton

Electronic Theses and Dissertations

7Be and 210Pb activities were measured in air sampling filters collected at The University of Maine campus from 2014 to 2019. The activities of 7Be were in the range of 1.178-98.8 Bq, with an average value of 32.13 Bq. The activities of 210Pb were in the range of 0.091 to 13.64 Bq, and an average value of 3.029 Bq. The distributions of activity for both radionuclides are lognormal. Both 7Be and 210Pb show seasonal variation with maximum values in the summer and minimum values in the fall, and the 7Be/210Pb ratio shows a clear seasonal variation with maxima in the …

Assessment Of Historical Climate Variability In Maine With Implications For Future Agricultural Productivity And Adaptation, Carly Frank

Electronic Theses and Dissertations

Climate change is a wicked problem with global impacts, one of which being the sustainability of the existing global food system. As temperatures and variability in precipitation are projected to increase, the challenges to agriculture are expected to intensify. This thesis examines the Maine historical climate record over the growing season, in combination with future projections, to assess how conditions have changed and will change with agricultural implications. In this analysis, relevant climatic variables are analyzed, and agriculture-significant measures are derived for Maine’s three climate divisions using four decades of daily and monthly gridded datasets. In addition, this thesis explores …