Physical Sciences and Mathematics Commons^™

The Crystal Chemistry Of Holtite, L. A. Groat, Edward S. Grew, R. J. Evans, A. Pieczka, T. S. Ercit

Earth Science Faculty Scholarship

Holtite, approximately (Al,Ta,square)Al(6)(BO(3))(Si,Sb(3+),As(3+))(Sigma 3)O(12)(O,OH,square)(Sigma 3), is a member of the dumortierite group that has been found in pegmatite, or alluvial deposits derived from pegmatite, at three localities: Greenbushes, Western Australia; Voron'i Tundry, Kola Peninsula, Russia; and Szklary, Lower Silesia, Poland. Holtite can contain >30 wt.% Sb(2)O(3), As(2)O(3), Ta(2)O(5), Nb(2)O(5), and TiO(2) (taken together), but none of these constituents is dominant at a crystallographic site, which raises the question whether this mineral is distinct from dumortierite. The crystal structures of four samples from the three localities have been refined to R(1) = 0.02-0.05. The results show dominantly: Al, Ta, and vacancies …

Antarctic Climate Change And The Environment, Peter Convey, R. Bindschadler, G. Di Prisco, E. Fahrbach, J. Gutt, D. A. Hodgson, Paul Andrew Mayewski, C. P. Summerhayes, J. Turner, Acce Consortium

Earth Science Faculty Scholarship

The Antarctic climate system varies on timescales from orbital, through millennial to sub-annual, and is closely coupled to other parts of the global climate system. We review these variations from the perspective of the geological and glaciological records and the recent historical period from which we have instrumental data (similar to the last 50 years). We consider their consequences for the biosphere, and show how the latest numerical models project changes into the future, taking into account human actions in the form of the release of greenhouse gases and chlorofluorocarbons into the atmosphere. In doing so, we provide an essential …

Atmospheric Soluble Dust Records From A Tibetan Ice Core: Possible Climate Proxies And Teleconnection With The Pacific Decadal Oscillation, B. Grigholm, Paul Andrew Mayewski, Shichang Kang, Y. Zhang, S. Kaspari, Sharon B. Sneed, Q. Zhang

Earth Science Faculty Scholarship

In autumn 2005, a joint expedition between the University of Maine and the Institute of Tibetan Plateau Research recovered three ice cores from Guoqu Glacier (33 degrees 34'37.80 '' N, 91 degrees 10'35.3 '' E, 5720 m above sea level) on the northern side of Mt. Geladaindong, central Tibetan Plateau. Isotopes ( delta(18)O), major soluble ions (Na(+), K(+), Mg(2+), Ca(2+), Cl(-), NO(3)(-), SO(4)(2-)), and radionuclide (beta-activity) measurements from one of the cores revealed a 70-year record (1935-2005). Statistical analysis of major ion time series suggests that atmospheric soluble dust species dominate the chemical signature and that background dust levels conceal …

Magma Extraction From The Mantle Wedge At Convergent Margins Through Dikes: A Parametric Sensitivity Analysis, Scott E. Johnson, Z.-H. Jin

Earth Science Faculty Scholarship

We address under what conditions a magma generated by partial melting at 100 km depth in the mantle wedge above a subduction zone can reach the crust in dikes before stalling. We also address under what conditions primitive basaltic magma (Mg # >60) can be delivered from this depth to the crust. We employ linear elastic fracture mechanics with magma solidification theory and perform a parametric sensitivity analysis. All dikes are initiated at a depth of 100 km in the thermal core of the wedge, and the Moho is fixed at 35 km depth. We consider a range of melt …

A High-Resolution Record Of Atmospheric Dust Composition And Variability Since Ad 1650 From A Mount Everest Ice Core, S. Kaspari, Paul Andrew Mayewski, M. Handley, Shichang Kang, S. Hou, Sharon B. Sneed, Kirk A. Maasch, D. Qin

Earth Science Faculty Scholarship

A Mount Everest ice core analyzed at high resolution for major and trace elements (Sr, Cs, Ba, La, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb, Lu, Bi, U, Tl, Al, S, Ca, Ti, V, Cr, Mn, Fe, Co) and spanning the period A. D. 1650- 2002 is used to investigate the sources of and variations in atmospheric dust through time. The chemical composition of dust varies seasonally, and peak dust concentrations occur during the winter-spring months. Significant correlations between the Everest dust record and dust observations at stations suggest that the Everest record is representative of …

Maine's Climate Future: An Initial Assessment, George L. Jacobson, Ivan J. Fernandez, Paul Andrew Mayewski, Catherine V. Schmitt

Earth Science Faculty Scholarship

Earth’s atmosphere is experiencing unprecedented changes that are modifying global climate. Discussions continue around the world, the nation, and in Maine on how to reduce and eventually eliminate emissions of carbon dioxide (CO2), other greenhouse gases, and other pollutants to the atmosphere, land, and oceans. These efforts are vitally important and urgent. However, even if a coordinated response succeeds in eliminating excess greenhouse gas emissions by the end of the century, something that appears highly unlikely today, climate change will continue, because the elevated levels of CO2 can persist in the atmosphere for thousands of years to come.

In late …

Along-Strike Differences In The Southern Alps Of New Zealand: Consequences Of Inherited Variation In Rheology, Phaedra Upton, Peter O. Koons, Dave Craw, C. Mark Henderson, Ray Enlow

Earth Science Faculty Scholarship

Long- and short-term strain variations along the Australian-Pacific plate boundary through the South Island of New Zealand, including a 300% increase in orogen width, coexistence of oblique thrusting on orthogonal structures, and variability in the locus of orogenic gold deposits, coincide with rheologically relevant geological variation. Our model investigates the consequences of thin, strong lower crust in the north and thick, weak lower crust in the south. Solution of the full 3-D mechanical equations reproduces the larger wavelength strain patterns of the orogen. A 3-D perturbation-based analytical solution leads to the identification of the sensitivity of displacement type to minor …

Recent Increases In Atmospheric Concentrations Of Bi, U, Cs, S And Ca From A 350-Year Mount Everest Ice Core Record, Susan D. Kaspari, Paul Andrew Mayewski, Michael Handley, Erich Osterberg, Shichang Kang, Sharon B. Sneed, Shugui Hou, Dahe Qin

Earth Science Faculty Scholarship

High-resolution major and trace elements (Sr, Cs, Ba, La, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb, Lu, Bi, U, Tl, Al, S, Ca, Ti, V, Cr, Mn, Fe, and Co) quantified in a Mount Everest ice core ( 6518 m above sea level) spanning the period 1650-2002 AD provides the first Asian record of trace element concentrations from the pre-industrial era, and the first continuous high-resolution Asian record from which natural baseline concentrations and subsequent changes due to anthropogenic activities can be examined. Modern concentrations of most elements remain within the pre-industrial range; however, Bi, U, …

Chevkinite-Group Minerals From Granulite-Facies Metamorphic Rocks And Associated Pegmatites Of East Antarctica And South India, H. E. Belkin, R. Macdonald, Edward S. Grew

Earth Science Faculty Scholarship

Electron microprobe data are presented for chevkinite-group minerals from granulite-facies rocks and associated pegmatities of the Napier Complex and Mawson Station charnockite in East Antarctica and from the Eastern Ghats, South India. Their compositions conform to the general formula for this group, viz. A(4)BC(2)D(2)Si(4)O(22) where, in the analysed specimens A = (rare-earth elements (REE), Ca, Y, Th), B = Fe(2+) Mg, C = (Al, Mg, Ti, Fe(2+), Fe(3+), Zr) and D = Ti and plot within the perrierite field oftlic total Fe (as FeO) (wt.%) vs. CaO (wt.%) discriminator diagram of Macdonald and Belkin (2002). In contrast to most chevkinite-group …

Variations Of Ice Bed Coupling Beneath And Beyond Ice Streams: The Force Balance, Terence J. Hughes

Earth Science Faculty Scholarship

A geometrical force balance that links stresses to ice bed coupling along a flow band of an ice sheet was developed in 1988 for longitudinal tension in ice streams and published 4 years later. It remains a work in progress. Now gravitational forces balanced by forces producing tensile, compressive, basal shear, and side shear stresses are all linked to ice bed coupling by the floating fraction phi of ice that produces the concave surface of ice streams. These lead inexorably to a simple formula showing how phi varies along these flow bands where surface and bed topography are known: phi …

State Of The Antarctic And Southern Ocean Climate System, Paul Andrew Mayewski, M. P. Meredith, C. P. Summerhayes, J. Turner, A. Worby, P. J. Barrett, G. Casassa, Nancy A.N. Bertler, T. Bracegirdle, A. C. Naveira Garabato, D. Bromwich, H. Campbell, Gordon S. Hamilton, W. B. Lyons, Kirk A. Maasch, S. Aoki, C. Xiao, Tas Van Ommen

Earth Science Faculty Scholarship

This paper reviews developments in our understanding of the state of the Antarctic and Southern Ocean climate and its relation to the global climate system over the last few millennia. Climate over this and earlier periods has not been stable, as evidenced by the occurrence of abrupt changes in atmospheric circulation and temperature recorded in Antarctic ice core proxies for past climate. Two of the most prominent abrupt climate change events are characterized by intensification of the circumpolar westerlies (also known as the Southern Annular Mode) between similar to 6000 and 5000 years ago and since 1200-1000 years ago. Following …

Design, Optimization And Calibration Of An Automated Density Gauge For Firn And Ice Cores, Daniel J. Breton, Gordon S. Hamilton, C. T. Hess

Earth Science Faculty Scholarship

A gamma-ray density gauge can provide high-resolution and high-precision density measurements of firn and ice cores. This study describes the design, gamma-ray energy optimization and mass attenuation coefficient calibration of the Maine Automated Density Gauge Experiment (MADGE), a portable, field-operable gamma-ray density gauge used on overland traverses in East Antarctica. The MADGE instrument uses a (241)Am gamma-ray source, a pulse-mode counting system and electronic core diameter calipers to collect high-precision (+/- 0.004 g cm(-3)) density data from 3-8 cm diameter firn and ice cores. The data are collected at a 3.3 mm spatial resolution and an average throughput of 1.5 …

Chemical Composition Of Fresh Snow From Glaciar Marinelli, Tierra Del Fuego, Chile, B. Grigholm, Paul Andrew Mayewski, Andrei V. Kurbatov, Gino Casassa, A. Contreras Staeding, M. Handley, Sharon B. Sneed, D. S. Introne

Earth Science Faculty Scholarship

A fresh-snow sampling campaign was conducted during the late austral summer of 2006 in the accumulation zone of Glaciar Marinelli, located in the Cordillera Darwin, Tierra del Fuego, Chile. Snow samples were analyzed for stable isotopes (delta(18)O, major soluble ions (Na', K', Ca, Mg, a NO(3)(-), SO(4)(2-), MS(-)) and major and trace elements (Na, Mg, Al, Fe, Ca, Sr, Cd, Cs, Ba, La, Ce, Pr, Dy, Ho, Er, Bi, U, As, Ti, V, Cr, Mn). The dominance of marine chemistry resembles that in studies from Patagonian glaciers. Snow chemistry was dominantly loaded by marine species (Cl(-), Na(+) and ssSO(4)(2-)), while …

Gpr Reflection Profiles Of Clark And Commonwealth Glaciers, Dry Valleys, Antarctica, Steven A. Arcone, Karl J. Kreutz

Earth Science Faculty Scholarship

Englacial horizons deeper than 100 m are absent within 100 MHz ground-penetrating radar (GPR) surface profiles we recorded on Clark and Commonwealth Glaciers in the Antarctic Dry Valleys region. Both glaciers show continuous bottom horizons to 280 m, with bottom signal-to-noise ratios near 30 dB. Density horizons should fade below 50 m depth because impermeable ice occurred by 36 m. Folding within Commonwealth Glacier could preclude radar strata beneath about 80 m depth, but there is no significant folding within Clark Glacier. Strong sulfate concentrations and contrasts exist in our shallow ice core. However, it appears that high background concentration …

Stable-Isotope And Trace Element Time Series From Fedchenko Glacier (Pamirs) Snow/Firn Cores, Vladimir B. Aizen, Paul Andrew Mayewski, Elena M. Aizen, Daniel R. Joswiak, Arzhan B. Surazakov, Susan Kaspari, Bijorn Grigholm, Michael Krachler, Michael Handley, Alexander Finaev

Earth Science Faculty Scholarship

In summer 2005, two pilot snow/firn cores were obtained at 5365 and 5206 m a.s.l. on Fedchenko glacier, Pamirs, Tajikistan, the world's longest and deepest alpine glacier. The well-defined seasonal layering appearing in stable-isotope and trace element distribution identified the physical links controlling the climate and aerosol concentration signals. Air temperature and humidity/precipitation were the primary determinants of stable-isotope ratios. Most precipitation over the Pamirs originated in the Atlantic. In summer, water vapor was re-evaporated from semi-arid regions in central Eurasia. The semi-arid regions contribute to non-soluble aerosol loading in snow accumulated on Fedchenko glacier. In the Pamir core, concentrations …

Thermal Convection And The Origin Of Ice Streams, Terence J. Hughes

Earth Science Faculty Scholarship

Ice streams are a fact of ice-sheet dynamics, draining up to 90% of the ice. Thermal convection in ice below the density inversion is a speculation. An attempt is made to meld the two in such a way that the speculation becomes an explanation for the fact.

Correction To Variations Of Ice Bed Coupling Beneath And Beyond Ice Streams: The Force Balance, Terence J. Hughes

Earth Science Faculty Scholarship

A geometrical force balance that links stresses to ice bed coupling along a flow band of an ice sheet was developed in 1988 for longitudinal tension in ice streams and published 4 years later. It remains a work in progress. Now gravitational forces balanced by forces producing tensile, compressive, basal shear, and side shear stresses are all linked to ice bed coupling by the floating fraction phi of ice that produces the concave surface of ice streams. These lead inexorably to a simple formula showing how phi varies along these flow bands where surface and bed topography are known: phi …

Records Of Volcanic Events Since Ad 1800 In The East Rongbuk Ice Core From Mt. Qomolangma, Jian Zhong Xu, S. Kaspari, Shu Gui Hou, Shi Chang Kang, Da He Qin, Jia Wen Ren, Paul Andrew Mayewski

Earth Science Faculty Scholarship

Continuous Bi profile of the East Rongbuk (ER) ice core near Mt. Qomolangma reveals nine major volcanic events since AD 1800. Compared with Volcanic Explosivity Index (VEI), it shows that the concentrations of Bi in the ER ice core can reflect the major volcanic events within the key areas. This provides a good horizon layer for ice core dating, as well as a basis for reconstructing a long sequence of volcanic records from the Qinghai-Xizang (Tibet) Plateau ice cores.

State Of The Antarctic And Southern Ocean Climate System, Paul Andrew Mayewski, M. P. Meredith, C. P. Summerhayes, J. Turner, A. Worby, P. J. Barrett, G. Casassa, Nancy Bertler, T. Bracegirdle, A. C. Naveira Garabato, D. Bromwich, H. Campbell, Gordon S. Hamilton, W. B. Lyons, Kirk A. Maasch, S. Aoki, C. Xiao, Tas Van Ommen

Earth Science Faculty Scholarship

This paper reviews developments in our understanding of the state of the Antarctic and Southern Ocean climate and its relation to the global climate system over the last few millennia. Climate over this and earlier periods has not been stable, as evidenced by the occurrence of abrupt changes in atmospheric circulation and temperature recorded in Antarctic ice core proxies for past climate. Two of the most prominent abrupt climate change events are characterized by intensification of the circumpolar westerlies (also known as the Southern Annular Mode) between ∼6000 and 5000 years ago and since 1200–1000 years ago. Following the last …