Physical Sciences and Mathematics Commons^™

A Novel Route To Organonitrites By Pd-Catalyzed Cross-Coupling Of Sodium Nitrite And Potassium Organotrifluoroborates, Mohammad Al-Masum, Nabil Saleh, Tasfia Islam

Chemistry Faculty Research

Microwave irradiated palladium-catalyzed cross-coupling reaction of potassium styryltrifluoroborates and sodium nitrite gives the corresponding styryl nitrites in high yields. Potassium aryltrifluoroborates also furnish aryl nitrites under same reaction condition. This unprecedented cross-coupling is an interesting development and has the potential to lead to new nitration protocols.

The Discovery Of Hd 37605c And A Dispositive Null Detection Of Transits Of Hd 37605b, Sharon Xuesong Wang, Jason T. Wright, William D. Cochran, Stephen R. Kane, Gregory W. Henry, Matthew J. Payne, Michael Endl, Phillip J. Macqueen, Jeff A. Valenti, Victoria Antoci, Diana Dragomir, Jaymie M. Matthews, Andrew W. Howard, Geoffrey W. Marcy, Howard Isaacson, Eric B. Ford, Suvrath Mahadevan, Kaspar Von Braun

Information Systems and Engineering Management Research Publications

We report the radial velocity discovery of a second planetary mass companion to the K0 V star HD 37605, which was already known to host an eccentric, P ∼ 55 days Jovian planet, HD 37605b. This second planet, HD 37605c, has a period of ∼7.5 years with a low eccentricity and an Msin i of ∼3.4 MJup. Our discovery was made with the nearly 8 years of radial velocity follow-up at the Hobby–Eberly Telescope and Keck Observatory, including observations made as part of the Transit Ephemeris Refinement and Monitoring Survey effort to provide precise ephemerides to long-period planets for transit …

Rotational And Cyclical Variability In Γ Cassiopeiae. Ii. Fifteen Seasons, Gregory W. Henry, Myron A. Smith

Information Systems and Engineering Management Research Publications

The B0.5 IVe star γ Cas is of great interest because it is the prototype of a small group of classical Be stars having hard X-ray emission of unknown origin. We discuss results from ongoing B and V observations of the γ Cas star–disk system acquired with an Automated Photometric Telescope during the observing seasons 1997–2011. In an earlier study, Smith, Henry, & Vishniac showed that light variations in γ Cas are dominated by a series of comparatively prominent cycles with amplitudes of 0.02–0.03 mag and lengths of 2–3 months, superimposed on a 1.21 day periodic signal some five times …

Non-Detection Of Previously Reported Transits Of Hd 97658b With Most* Photometry, Diana Dragomir, Jaymie M. Matthews, Andrew W. Howard, Victoria Antoci, Gregory W. Henry, David B. Guenther, John A. Johnson, Rainer Kuschnig, Geoffrey W. Marcy, Anthony F. J. Moffat, Jason F. Rowe, Slavek M. Rucinski, Dimitar Sasselov, Werner W. Weiss

Information Systems and Engineering Management Research Publications

The radial velocity-discovered exoplanet HD 97658b was recently announced to transit, with a derived planetary radius of 2.93 ± 0.28 R⊕. As a transiting super-Earth orbiting a bright star, this planet would make an attractive candidate for additional observations, including studies of its atmospheric properties. We present and analyze follow-up photometric observations of the HD 97658 system acquired with the Microvariability and Oscillations of STars space telescope. Our results show no transit with the depth and ephemeris reported in the announcement paper. For the same ephemeris, we rule out transits for a planet with radius larger than 2.09 R⊕, corresponding …

Host–Guest Complex Of Β-Cyclodextrin And Disulfide Form Of 4-Aminothiophenol, Taylor A. Cappadona, Lee M. Daniels, Tasneem A. Siddiquee

Chemistry Faculty Research

An inclusion complex of β-cyclodextrin and 4-aminothiophenol was assembled by hydrophobic interaction of the host (β-cyclodextrin) and guest (4-aminothiophenol). The complex was isolated as crystalline solid and studied by single crystal X-ray diffraction method along with NMR and IR spectroscopy. Two cyclodextrin rings each containing one disulfide form of 4-aminothiophenol were found to pair up by hydrogen bonding of the outer rim -OH groups. The phenyl disulfide moiety of 4-aminophenyl disulfide molecule was found in the core of β-cyclodextrin, while the amino functional groups were positioned to the exterior of the cyclodextrin ring. Phenyl rings of the guest molecule from …

The Relationship Between Γ Cassiopeiae’S X-Ray Emission And Its Circumstellar Environment Ii. Geometry And Kinematics Of The Disk From Mirc And Vega Instruments On The Chara Array, Philippe Stee, O. Delaa, John D. Monnier, Anthony Meilland, Karine Perraut, Denis Mourard, Xiao Che, Gail H. Schaefer, Ettore Pedretti, Myron A. Smith, Raimundo Lopes De Oliveira, Christian Motch, Gregory W. Henry, Noel D. Richardson, Karen S. Bjorkman, R. Bücke, E. Pollmann, Juan Zorec, Douglas R. Gies, Theo A. Ten Brummelaar, Harold A. Mcalister, Nils H. Turner, Judit Sturmann, Laszlo Sturmann, Stephen T. Ridgway

Information Systems and Engineering Management Research Publications

Context.γ Cas is thought to be the prototype of classical Be stars and is the most studied object among this group. However, as for all Be stars, the origin and the physics of its circumstellar disk responsible for the observed near IR-excess, emission lines, and peculiar X-ray emission is still being debated.

Aims. We constrain the geometry and kinematics of its circumstellar disk from the highest spatial resolution ever achieved on this star. This investigation is a part of a large multi-technique observing campaign to obtain the most complete picture of γ Cas which emphasizes the relation of the …

The Lick–Carnegie Survey: A New Two-Planet System Around The Star Hd 207832, Nader Haghighipour, R. Paul Butler, Eugenio J. Rivera, Gregory W. Henry, Steve Vogt

Information Systems and Engineering Management Research Publications

Keck/HIRES precision radial velocities of HD 207832 indicate the presence of two Jovian-type planetary companions in Keplerian orbits around this G star. The planets have minimum masses of Msin i = 0.56 MJup and 0.73 MJup, with orbital periods of ∼162 and ∼1156 days, and eccentricities of 0.13 and 0.27, respectively. Strömgren b and y photometry reveals a clear stellar rotation signature of the host star with a period of 17.8 days, well separated from the period of the radial velocity variations, reinforcing their Keplerian origin. The values of the semimajor axes of the planets suggest that these objects have …

Nearness To Local Subspace Algorithm For Subspace And Motion Segmentation, Akram Aldroubi, Ali Safak Sekmen

Computer Science Faculty Research

This letter presents a clustering algorithm for high dimensional data that comes from a union of lower dimensional subspaces of equal and known dimensions. The algorithm estimates a local subspace for each data point, and computes the distances between the local subspaces and the points to convert the problem to a one-dimensional data clustering problem. The algorithm is reliable in the presence of noise, and applied to the Hopkins 155 Dataset, it generates the best results to date for motion segmentation. The two motion, three motion, and overall segmentation rates for the video sequences are 99.43%, 98.69%, and 99.24%, respectively.

Spectro-Interferometric Observations Of Classical Nova V458 Vul 2007, Samira Rajabi, Matthew W. Muterspaugh, Benjamin F. Lane, Martin M. Sirk, Stanley Browne, Askari Ghasempour, Samuel P. Halverson, John G. Kelly, Michael Williamson

Information Systems and Engineering Management Research Publications

We used the Palomar Testbed Interferometer (PTI) to resolve 2.2 μm emission from the classical nova V458 Vul 2007 over the course of several days following its discovery on 2007 August 8.54 UT. We also obtained K-band photometric data and spectra of the nova during the early days of the outburst. We also used photometric measurements from the AAVSO database. This is a unique data set offering a three-technique approach: high-resolution imaging, spectroscopy, and photometry. Our analysis shows that the nova ejecta can be modeled as an inclined disk at low inclination, i.e., low ellipticity which is consistent with the …

Confronting A Solar Irradiance Reconstruction With Solar And Stellar Data, Philip G. Judge, G. Wesley Lockwood, Richard R. Radick, Gregory W. Henry, Alexander I. Shapiro, Werner Schmutz, Charles Lindsey

Information Systems and Engineering Management Research Publications

Context. A recent paper by Shapiro and colleagues (2011, A&A, 529, A67) reconstructs spectral and total irradiance variations of the Sun during the holocene.

Aims. In this note, we comment on why their methodology leads to large (0.5%) variations in the solar TSI on century-long time scales, in stark contrast to other reconstructions which have ≲ 0.1% variations.

Methods. We examine the amplitude of the irradiance variations from the point of view of both solar and stellar data.

Results. Shapiro et al.’s large amplitudes arise from differences between the irradiances computed from models A and C of Fontenla and colleagues, …

Soil Biochemical Changes Induced By Poultry Litter Application And Conservation Tillage Under Cotton Production Systems, Regine Mankolo, Chandra Reddy, Zachary Senwo, Ermson Nyakatawa, Seshadri Sajjala

Agricultural and Environmental Sciences Faculty Research

Problems arising from conventional tillage (CT) systems (such as soil erosion, decrease of organic matter, environmental damage etc.) have led many farmers to the adoption of no-till (NT) systems that are more effective in improving soil physical, chemical and microbial properties. Results from this study clearly indicated that NT, mulch tillage (MT), and winter rye cover cropping systems increased the activity of phosphatase, β-glucosidase and arylsulfatase at a 0–10 cm soil depth but decreased the activity of these enzymes at 10–20 cm. The increase in enzyme activity was a good indicator of intensive soil microbial activity in different soil management …

Effects Of Precipitation Increase On Soil Respiration: A Three-Year Field Experiment In Subtropical Forests In China, Qi Deng, Dafeng Hui, Deqiang Zhang, Guoyi Zhou, Juxiu Liu, Shizhong Liu, Guowei Chu, Jiong Li

Biology Faculty Research

Background

The aim of this study was to determine response patterns and mechanisms of soil respiration to precipitation increases in subtropical regions.

Methodology/Principal Findings

Field plots in three typical forests [i.e. pine forest (PF), broadleaf forest (BF), and pine and broadleaf mixed forest (MF)] in subtropical China were exposed under either Double Precipitation (DP) treatment or Ambient Precipitation (AP). Soil respiration, soil temperature, soil moisture, soil microbial biomass and fine root biomass were measured over three years. We tested whether precipitation treatments influenced the relationship of soil respiration rate (R) with soil temperature (T) and soil …

Absolute Properties Of The Eclipsing Binary Star V335 Serpentis, Claud H. Sandberg Lacy, Francis C. Fekel, Antonio Claret

Information Systems and Engineering Management Research Publications

V335 Ser is now known to be an eccentric double-lined A1+A3 binary star with fairly deep (0.5 mag) partial eclipses. Previous studies of the system are improved with 7456 differential photometric observations from the URSA WebScope and 5666 from the NFO WebScope, and 67 high-resolution spectroscopic observations from the Tennessee State University 2 m automatic spectroscopic telescope. From dates of minima, the apsidal period is about 880 years. Accurate (better than 2%) masses and radii are determined from analysis of the two new light curves and the radial velocity curve. Theoretical models match the absolute properties of the stars at …

The Hd 192263 System: Planetary Orbital Period And Stellar Variability Disentangled, Diana Dragomir, Stephen R. Kane, Gregory W. Henry, David R. Ciardi, Debra A. Fischer, Andrew W. Howard, Eric L. N. Jensen, Gregory Laughlin, Suvrath Mahadevan, Jaymie M. Matthews, Genady Pilyavsky, Kaspar Von Braun, Sharon X. Wang, Jason T. Wright

Information Systems and Engineering Management Research Publications

As part of the Transit Ephemeris Refinement and Monitoring Survey, we present new radial velocities and photometry of the HD 192263 system. Our analysis of the already available Keck-HIRES and CORALIE radial velocity measurements together with the five new Keck measurements we report in this paper results in improved orbital parameters for the system. We derive constraints on the size and phase location of the transit window for HD 192263b, a Jupiter-mass planet with a period of 24.3587 ± 0.0022 days. We use 10 years of Automated Photoelectric Telescope photometry to analyze the stellar variability and search for planetary transits. …

3.6 And 4.5 Μm Phase Curves And Evidence For Non-Equilibrium Chemistry In The Atmosphere Of Extrasolar Planet Hd 189733b, Heather A. Knutson, Nikole K. Lewis, Jonathan J. Fortney, Adam Burrows, Adam P. Showman, Nicolas B. Cowan, Eric Agol, Suzanne Aigrain, David Charbonneau, Drake Deming, Jean-Michel Désert, Gregory W. Henry, Jonathan Langton, Gregory Laughlin

Information Systems and Engineering Management Research Publications

We present new, full-orbit observations of the infrared phase variations of the canonical hot Jupiter HD 189733b obtained in the 3.6 and 4.5 μm bands using the Spitzer Space Telescope. When combined with previous phase curve observations at 8.0 and 24 μm, these data allow us to characterize the exoplanet's emission spectrum as a function of planetary longitude and to search for local variations in its vertical thermal profile and atmospheric composition. We utilize an improved method for removing the effects of intrapixel sensitivity variations and robustly extracting phase curve signals from these data, and we calculate our best-fit parameters …

Spot Activity Of Lq Hydra From Photometry Between 1988 And 2011, Jyri J. Lehtinen, Lauri Jetsu, Thomas Hackman, Perttu Kajatkari, Gregory W. Henry

Information Systems and Engineering Management Research Publications

Aims. We investigate the spot activity of the young magnetically active main sequence star LQ Hya. Our aims are to identify possible active longitudes, estimate the differential rotation, and study long and short term changes in the activity.

Methods. Our analysis is based on 24 years of Johnson V-band photometry of LQ Hya obtained with the T3 0.4 m Automated Telescope at the Fairborn Observatory. We use the previously published continuous period search (CPS) method to model the evolution of the light curve of LQ Hya. The CPS fits a Fourier series model to short overlapping subsets …

Lipid Peroxides And Glutathione Status In Human Progenitor Mononuclear (U937) Cells Following Exposure To Low Doses Of Nickel And Copper, William Y. Boadi, Shalandus Harris, Justin B. Anderson, Samuel E. Adunyah

Chemistry Faculty Research

Effects of Cu2+, Ni2+ or Cu2+ + Ni2+ on lipid peroxide and glutathione (GSH) levels in U937 cells were investigated. Cells were treated with 0, 5, 10, and 20 µM of Cu2+ and/or Ni2+ and H2O2 (0.01 mM) and incubated for 24 hours at 37°C. Lipid peroxides were measured by the thiobarbituric acid assay (TBA). GSH intracellular levels were assayed by the GSH assay kit from EMD/Calbiochem (San Diego, California, USA). Cu2+ or Ni2+ significantly (P < 0.01) increased lipid peroxides in a dose-dependent manner, compared to controls. The effect was more pronounced for Cu2+, compared to the Ni2+-treated samples. Cu2+ + Ni2+ increased lipid peroxides in a significant (P < 0.001), dose-dependent manner, compared to Cu2+ or Ni2+ alone (i.e., ratio of 2.5:1-fold for combined versus single treatments, respectively). Cu2+ or Ni2+ significantly decreased GSH levels in U937 cells, with the effect being pronounced for Cu2+. Cu2+ + Ni2+ metal ions significantly (P < 0.001) depleted cells of GSH in a dose-dependent manner. Ethylene diamine tetraacetic acid (EDTA) at 50 or 100 µM moderately reduced the Cu2+- or Ni2+-induced effects on GSH levels. Interestingly, GSH levels generally decreased to half (except for the combined metal dose of 20 µM at 100 µM EDTA) of its level at the highest metal concentration tested for both the single or combined treatments. In conclusion, multiple exposures of cells to metal ions may be lethal to cells, compared to their single treatments.

Absolute Properties Of The Eclipsing Binary Star Bf Draconis, Claud H. Sandberg Lacy, Guillermo Torres, Francis C. Fekel, Jeffrey A. Sabby, Antonio Claret

Information Systems and Engineering Management Research Publications

BF Dra is now known to be an eccentric double-lined F6+F6 binary star with relatively deep (0.7 mag) partial eclipses. Previous studies of the system are improved with 7494 differential photometric observations from the URSA WebScope and 9700 from the NFO WebScope, 106 high-resolution spectroscopic observations from the Tennessee State University 2 m automatic spectroscopic telescope and the 1 m coudé-feed spectrometer at Kitt Peak National Observatory, and 31 accurate radial velocities from the CfA. Very accurate (better than 0.6%) masses and radii are determined from analysis of the two new light curves and four radial velocity curves. Theoretical models …

Synthesis Of Some New Fluorinated Hexahydroquinoline And Acridinedione Derivatives In Trifluoroethanol, Cosmas O. Okoro, Mumiye A. Ogunwale, Tasneem Siddiquee

Chemistry Faculty Research

This article describes one-pot synthesis of new fluorinated hexahydroquinoline derivatives via unsymmetric Hantzsch reaction involving 5-trifluoromethyl-1,3-cyclohexanedione, aldehydes, acetoacetate ester, and ammonium acetate in trifluoroethanol (TFE). The reaction is simple and rapid with high yield.

Probing The Haze In The Atmosphere Of Hd 189733b With Hubble Space Telescope/Wfc3 Transmission Spectroscopy, Neale P. Gibson, Suzanne Aigrain, Frederic Pont, David K. Sing, Jean-Michel Désert, Thomas M. Evans, Gregory W. Henry, Nawal Husnoo, Heather Knutson

Information Systems and Engineering Management Research Publications

We present Hubble Space Telescope near-infrared transmission spectroscopy of the transiting exoplanet HD 189733b, using the Wide Field Camera 3 (WFC3). This consists of time series spectra of two transits, used to measure the wavelength dependence of the planetary radius. These observations aim to test whether the Rayleigh scattering haze detected at optical wavelengths extends into the near-infrared, or if it becomes transparent leaving molecular features to dominate the transmission spectrum. Due to saturation and non-linearity affecting the brightest (central) pixels of the spectrum, light curves were extracted from the blue and red ends of the spectra only, corresponding to …

Copyright Page

The Journal of Tennessee State University

No abstract provided.

Table Of Contents

The Journal of Tennessee State University

No abstract provided.

Forward

The Journal of Tennessee State University

No abstract provided.

The Economic Impact Of Tennessee State University On The State Of Tennessee 2010-2011, Soumendra Ghosh, Anis Mnif, Sabeen Fahim

The Journal of Tennessee State University

No abstract provided.

Editorial Board Page

The Journal of Tennessee State University

No abstract provided.

Some Notable Writers, Editors, And Publishers Affiliated With Tsu Over Its First 100 Years

The Journal of Tennessee State University

No abstract provided.

Living Our Lives As Elders: A Convocation Address, Celeste C. Williams

The Journal of Tennessee State University

No abstract provided.

Dr. Thomas E. Poag: The Life And Works Of A Tsu Legend, Helen R. Houston

The Journal of Tennessee State University

No abstract provided.

Service-Learning And Civic Engagement: A Return To Our Roots, Deena Sue Fuller

The Journal of Tennessee State University

No abstract provided.

Coach Ed Temple And The Tigerbelles, Yildiz B. Binkley, Reavis Mitchell, Tara Mitchell Mielnik

The Journal of Tennessee State University

No abstract provided.