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Full-Text Articles in Physical Sciences and Mathematics
Self-Condensation Reactions Of Acyl Phosphonates: Synthesis Of Tertiary O-Protected \Alpha-Hydroxyphosphonates, Serkan Eymur, Mehmet Göllü, Ayhan Sitki Demi̇r
Self-Condensation Reactions Of Acyl Phosphonates: Synthesis Of Tertiary O-Protected \Alpha-Hydroxyphosphonates, Serkan Eymur, Mehmet Göllü, Ayhan Sitki Demi̇r
Turkish Journal of Chemistry
The self-condensation reaction of benzoyl dialkyl phosphonates was developed using cyanide ion as catalyst, affording versatile tertiary O-protected \alpha-hydroxy phosphonates in moderate yield.
Synthesis Of Tertiary Propargylic Phosphonates By Addition Of Trialkynylaluminum Reagents To Acyl Phosphonates And Investigation Of Their Antimicrobial Activities, Muhammed Shakhawoat Hossain, Sidika Polat Çakir, Ayşe Betül Karaduman, Mustafa Yamaç, Ayhan Sitki Demi̇r
Synthesis Of Tertiary Propargylic Phosphonates By Addition Of Trialkynylaluminum Reagents To Acyl Phosphonates And Investigation Of Their Antimicrobial Activities, Muhammed Shakhawoat Hossain, Sidika Polat Çakir, Ayşe Betül Karaduman, Mustafa Yamaç, Ayhan Sitki Demi̇r
Turkish Journal of Chemistry
A series of propargylic alcohols containing phosphonates was synthesized by addition reactions of tris-(propynyl) and tris-(phenylethynyl)aluminum reagents to acyl phosphonates in good yields. Aromatic moieties of the acyl phosphonates with electron-withdrawing groups generally resulted in better isolated chemical yield. Selected propargylic phosphonates were tested for antimicrobial activities. Compounds 3a and 3h showed noticeable antifungal activity, especially against molds.